476
Views
1
CrossRef citations to date
0
Altmetric
Research Article

Effect of concentration and ionic strength on the lower critical solution temperature of poly(N-isopropylacrylamide) investigated by small-angle X-ray scattering

, &
Pages S10-S18 | Received 13 Aug 2021, Accepted 07 Sep 2021, Published online: 16 Sep 2021

References

  • Zhu, K.; Pamies, R.; Al-Manasir, N.; Cifre, J. G. H.; de la Torre, J. G.; Nyström, B.; Kjøniksen, A.-L. The Effect of Number of Arms on the Aggregation Behavior of Thermoresponsive Poly(N-Isopropylacrylamide) Star Polymers. ChemPhysChem. 2020, 21(12), 1258–1271. DOI: 10.1002/cphc.202000273.
  • Salehi, R.; Davaran, S.; Rashidi, M. R.; Entezami, A. A. Thermosensitive Nanoparticles Prepared from Poly(N-Isopropylacrylamide-Acrylamide-Vinilpyrrolidone) and Its Blend with Poly(Lactide-Co-Glycolide) for Efficient Drug Delivery System. J. Appl. Polym. Sci. 2009, 111(4), 1905–1910. DOI: 10.1002/app.29199.
  • Vihola, H.; Laukkanen, A.; Hirvonen, J.; Tenhu, H. Binding and Release of Drugs into and from Thermosensitive Poly(N-Vinyl Caprolactam) Nanoparticles. Eur. J. Pharm. Sci. 2002, 16(1), 69–74. DOI: 10.1016/S0928-0987(02)00076-3.
  • Kokuryo, D.; Nakashima, S.; Ozaki, F.; Yuba, E.; Chuang, K.-H.; Aoshima, S.; Ishizaka, Y.; Saga, T.; Kono, K.; Aoki, I. Evaluation of Thermo-Triggered Drug Release in Intramuscular-Transplanted Tumors Using Thermosensitive Polymer-Modified Liposomes and MRI. Nanomedi. Nanotechnol. Biol. Med. 2015, 11(1), 229–238. DOI:10.1016/j.nano.2014.09.001.
  • Chen, H.; Zhang, J.; Qian, Z.; Liu, F.; Chen, X.; Hu, Y. In Vivonon-Invasive Optical Imaging of Temperature-Sensitive Co-Polymeric Nanohydrogel. Nanotechnology. 2008, 19(18), 185707. DOI: 10.1088/0957-4484/19/18/185707.
  • Gui, R.; Wang, Y.; Sun, J. Encapsulating Magnetic and Fluorescent Mesoporous Silica into Thermosensitive Chitosan Microspheres for Cell Imaging and Controlled Drug Release in Vitro. Colloids Surf. B Biointerfaces. 2014, 113, 1–9. DOI: 10.1016/j.colsurfb.2013.08.015.
  • Ye, X.; Luo, Y.; Gao, X.; Zhu, S. Design and Evaluation of a Thermochromic Roof System for Energy Saving Based on Poly(N-Isopropylacrylamide) Aqueous Solution. Energy Build. 2012, 48, 175–179. DOI: 10.1016/j.enbuild.2012.01.024.
  • Rotzetter, A. C. C.; Schumacher, C. M.; Bubenhofer, S. B.; Grass, R. N.; Gerber, L. C.; Zeltner, M.; Stark, W. J. Thermoresponsive Polymer Induced Sweating Surfaces as an Efficient Way to Passively Cool Buildings. Adv. Mater. 2012, 24(39), 5352–5356. DOI: 10.1002/adma.201202574.
  • Schild, H. G. Poly(N-Isopropylacrylamide): Experiment, Theory and Application. Prog. Polym. Sci. 1992, 17(2), 163–249. DOI: 10.1016/0079-6700(92)90023-R.
  • Kujawa, P.; Winnik, F. M. Volumetric Studies of Aqueous Polymer Solutions Using Pressure Perturbation Calorimetry: A New Look at the Temperature-Induced Phase Transition of Poly(N-Isopropylacrylamide) in Water and D2O. Macromolecules. 2001, 34(12), 4130–4135. DOI: 10.1021/ma002082h.
  • Zhang, G.; Wu, C. Folding and Formation of Mesoglobules in Dilute Copolymer Solutions. In Conformation-Dependent Design of Sequences in Copolymers I; Khokhlov, A. R. Ed.; Springer: Berlin, Heidelberg, 2006; pp. 101–176.Advances in Polymer Science. DOI:10.1007/12_050.
  • Heskins, M.; Guillet, J. E. Solution Properties of Poly(N-Isopropylacrylamide). J. Macromol. Sci. Part Chem. 1968, 2(8), 1441–1455. DOI:10.1080/10601326808051910.
  • Schild, H. G.; Tirrell, D. A. Microcalorimetric Detection of Lower Critical Solution Temperatures in Aqueous Polymer Solutions. J. Phys. Chem. 1990, 94(10), 4352–4356. DOI: 10.1021/j100373a088.
  • Acciaro, R.; Gilányi, T.; Varga, I. Preparation of Monodisperse Poly(N-Isopropylacrylamide) Microgel Particles with Homogenous Cross-Link Density Distribution. Langmuir. 2011, 27(12), 7917–7925. DOI: 10.1021/la2010387.
  • Pamies, R.; Zhu, K.; Kjøniksen, A.-L.; Nyström, B. Thermal Response of Low Molecular Weight Poly-(N-Isopropylacrylamide) Polymers in Aqueous Solution. Polym. Bull. 2009, 62(4), 487–502. DOI: 10.1007/s00289-008-0029-4.
  • Lyngsø, J.; Pedersen, J. S. A High-Flux Automated Laboratory Small-Angle X-Ray Scattering Instrument Optimized for Solution Scattering. J. Appl. Crystallogr. 2021, 54(1), 295–305. DOI: 10.1107/S1600576720016209.
  • Schwamberger, A.; De Roo, B.; Jacob, D.; Dillemans, L.; Bruegemann, L.; Seo, J. W.; Locquet, J. P. Combining SAXS and DLS for Simultaneous Measurements and Time-Resolved Monitoring of Nanoparticle Synthesis. Nucl. Instrum. Methods Phys. Res. Sect. B Beam Interact. Mater. At. 2015, 343, 116–122. DOI: 10.1016/j.nimb.2014.11.049.
  • Li, Y.; Beck, R.; Huang, T.; Choi, M. C.; Divinagracia, M. Scatterless Hybrid Metal–Single-Crystal Slit for Small-Angle X-Ray Scattering and High-Resolution X-Ray Diffraction. J. Appl. Crystallogr. 2008, 41(6), 1134–1139. DOI: 10.1107/S0021889808031129.
  • Pedersen, J. S.; Schurtenberger, P. Scattering Functions of Semiflexible Polymers with and without Excluded Volume Effects. Macromolecules. 1996, 29(23), 7602–7612. DOI: 10.1021/ma9607630.
  • Debye, P. Molecular-Weight Determination by Light Scattering. J. Phys. Chem. 1947, 51(1), 18–32. DOI: 10.1021/j150451a002.
  • Kaczmarek, D.; Diget, J. S.; Nyström, B.; Gyulai, G.; Mészáros, R.; Gilányi, T.; Varga, I. Response of Block Copolyelectrolyte Complexes to Addition of Ionic Surfactants. Colloids Surf. Physicochem. Eng. Asp. 2017, 532, 290–296. DOI: 10.1016/j.colsurfa.2017.04.078.
  • Lyngsø, J.; Al-Manasir, N.; Behrens, M. A.; Zhu, K.; Kjøniksen, A.-L.; Nyström, B.; Pedersen, J. S. Small-Angle X-Ray Scattering Studies of Thermoresponsive Poly(N-Isopropylacrylamide) Star Polymers in Water. Macromolecules. 2015, 48(7), 2235–2243. DOI: 10.1021/acs.macromol.5b00057.
  • Pedersen, J. S. Analysis of Small-Angle Scattering Data from Colloids and Polymer Solutions: Modeling and Least-Squares Fitting. Adv. Colloid Interface Sci. 1997, 70, 171–210. DOI: 10.1016/S0001-8686(97)00312-6.
  • Zhang, Y.; Furyk, S.; Bergbreiter, D. E.; Cremer, P. S. Specific Ion Effects on the Water Solubility of Macromolecules: PNIPAM and the Hofmeister Series. J. Am. Chem. Soc. 2005, 127(41), 14505–14510. DOI: 10.1021/ja0546424.
  • Bruce, E. E.; Okur, H. I.; Stegmaier, S.; Drexler, C. I.; Rogers, B. A.; Van Der Vegt, N. F. A.; Roke, S.; Cremer, P. S. Molecular Mechanism for the Interactions of Hofmeister Cations with Macromolecules in Aqueous Solution. J. Am. Chem. Soc. 2020, 142(45), 19094–19100. DOI: 10.1021/jacs.0c07214.
  • Fang, Y.; Furó, I. Weak Anion Binding to Poly(N‑isopropylacrylamide) Detected by Electrophoretic NMR. J. Phys. Chem. B. 2021, 125, 3710–3716. DOI: 10.1021/acs.jpcb.1c00642.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.