Field Comparison of Air Sampling Methods for Monomeric and Polymeric 1,6-Hexamethylene Diisocyanate

References

• Criteria for a Recommended Standard: Occupational Exposure to Diisocyanates . (Pub. No. 78–215). [Online] Available at http://www.cdc.gov/niosh/78-215.html (Accessed July 28, 2010)
   Google Scholar
• Pocket Guide to Chemical Hazards . (Pub. No. 2005–149, 2007) [Online] Available at http://www.cdc.gov/niosh/npg/default.html (Accessed July 28, 2010)
   Google Scholar
• NORA Priority Areas: Asthma and Chronic Obstructive Pulmonary Disease . [Online] Available at http://www.cdc.gov/niosh/docs/96-115/diseas.html (Accessed July 28, 2010)
   Google Scholar
• Adams , W. G. 1975 . Long-term effects on the health of men engaged in the manufacture of toluene di-isocyanate . Br. J. Ind. Med. , 32 ( 1 ) : 72 – 78 .
   Google Scholar
• Butcher , B. T. , Mapp , C. E. and Fabbri , L. M. 1993 . Polyisocyanates and Their Prepolymers , New York : Marcel Dekker, Inc. .
   Google Scholar
• Diem , J. E. , Jones , R. N. Hendrick , D. J. 1982 . Five-year longitudinal study of workers employed in a new toluene diisocyanate manufacturing plant . Am. Rev. Respir. Dis. , 126 ( 3 ) : 420 – 428 .
   PubMed Web of Science ®Google Scholar
• Porter , C. V. , Higgins , R. L. and Scheel , L. D. 1975 . A retrospective study of clinical, physiologic and immunologic changes in workers exposed to toluene diisocyanate . Am. Ind. Hyg. Assoc. J. , 36 : 159 – 168 .
   PubMed Web of Science ®Google Scholar
• Weill , H. 1979 . Epidemiologic and medical-legal aspects of occupational asthma . J. Allergy Clin. Immunol. , 64 : 662 – 664 .
   Web of Science ®Google Scholar
• White , W. G. , Sugden , E. Morris , M. J. 1988 . Isocyanate-induced asthma in a car factory . Lancet , 1 : 756 – 760 .
   Google Scholar
• 1996 . Preventing Asthma and Death from Diisocyanate Exposure . Pub. 96-111 ([Online] Available at http://www.cdc.gov/niosh/asthma.html Accessed July 28, 2010
   Google Scholar
• Streicher , R. P. , Reh , C. M. Key-Schwartz , R. 2002 . Selecting isocyanate sampling and analytical methods . Appl. Occup. Environ. Hyg. , 17 : 157 – 162 .
   PubMedGoogle Scholar
• Streicher , R. P. , Kennedy , E. R. and Lorberau , C. D. 1994 . Strategies for the simultaneous collection of vapours and aerosols with emphasis on isocyanate sampling . Analyst 119 , : 89 – 97 .
   Google Scholar
• Janko , M. , McCarthy , K. Fajer , M. 1992 . Occupational exposure to 1,6-hexamethylene diisocyanate-based polyisocyanates in the state of Oregon, 1980–1990 . Am. Ind. Hyg. Assoc. J. , 53 : 331 – 338 .
   PubMed Web of Science ®Google Scholar
• Lesage , J. , Goyer , N. Desjardins , F. 1992 . Workers’ exposure to isocyanates . Am. Ind. Hyg. Assoc. J. , 53 : 146 – 153 .
   PubMed Web of Science ®Google Scholar
• Myer , H. E. , O’Block , S. T. and Dharmarajan , V. 1993 . A survey of airborne HDI, HDI-based polyisocyanate and solvent concentrations in the manufacture and application of polyurethane coatings . Am. Ind. Hyg. Assoc. J. , 54 : 663 – 670 .
   PubMed Web of Science ®Google Scholar
• Pisaniello , D. L. and Muriale , L. 1989 . The use of isocyanate paints in auto refinishing—A survey of isocyanate exposures and related work practices in South Australia . Ann. Occup. Hyg. , 33 ( 4 ) : 563 – 572 .
   Web of Science ®Google Scholar
• Goyer , N. 1995 . Performance of painting booths equipped with down-draft ventilation . Am. Ind. Hyg. Assoc. J. , 56 : 258 – 265 .
   Web of Science ®Google Scholar
• Rudzinski , W. E. , Dahlquist , B. Svejda , S. A. 1995 . Sampling and analysis of isocyanates in spray-painting operations . Am. Ind. Hyg. Assoc. J. , 56 : 284 – 289 .
   Web of Science ®Google Scholar
• England , E. , Key-Schwartz , R. Lesage , J. 2000 . Comparison of sampling methods for monomer and polyisocyanates of 1,6-hexamethylene diisocyanate during spray finishing operations . Appl. Occup. Environ. Hyg. , 15 : 472 – 478 .
   PubMedGoogle Scholar
• Fent , K. W. , Gaines , L. G. Thomasen , J. M. 2009 . Quantification and statistical modeling—Part I: Breathing-zone concentrations of monomeric and polymeric 1,6-hexamethylene diisocyanate . Ann. Occup. Hyg. , 53 ( 7 ) : 677 – 689 .
   PubMed Web of Science ®Google Scholar
• 1983 . OSHA Sampling & Analytical Methods: Diisocyanates: Method 42 . [Online] Available at http://www.osha.gov/dts/sltc/methods/organic/org042/org042.html (Accessed July 28, 2010)
   Google Scholar
• Bello , D. , Streicher , R. P. Liu , Y. C. 2002 . Field comparison of impingers and treated filters for sampling of total aliphatic isocyanates with the MAP reagent . Am. Ind. Hyg. Assoc. J. , 63 ( 6 ) : 790 – 796 .
   Google Scholar
• Bello , D. , Streicher , R. P. and Woskie , S. R. 2002 . Evaluation of the NIOSH draft method 5525 for determination of the total reactive isocyanate group (TRIG) for aliphatic isocyanates in autobody repair shops . J. Environ. Monit. , 4 ( 3 ) : 351 – 360 .
   PubMed Web of Science ®Google Scholar
• Ekman , J. , Levin , J. O. Lindahl , R. 2002 . Comparison of sampling methods for 1,6-hexamethylene diisocyanate (HDI) in a commercial spray box . Analyst 127 , : 169 – 173 .
   Google Scholar
• Levine , S. P. 2002 . Critical review of methods for sampling, analysis, and monitoring of vapor-phase toluene diisocyanate . Appl. Occup. Environ. Hyg. , 17 : 878 – 890 .
   PubMedGoogle Scholar
• Podolak , G. E. , Cassidy , R. A. Esposito , G. G. 1987 . “ Collection and analysis of airborne hexamethylene diisocyanate by a modified OSHA method ” . In Sampling and Calibration for Atmospheric Measurements (ASTM STP 957) , 203 – 214 . West Conshohocken , PA : American Society for Testing and Materials .
   Google Scholar
• Sennbro , C. J. , Ekman , J. Lindh , C. H. 2004 . Determination of isocyanates in air using 1-(2-methoxyphenyl)piperazine-impregnated filters: Long-term sampling performance and field comparison with impingers with dibutylamine . Ann. Occup. Hyg. , 48 ( 5 ) : 415 – 424 .
   PubMed Web of Science ®Google Scholar
• Streicher , R. P. , Reh , C. M. Key-Schwartz , R. J. 2000 . Determination of airborne isocyanate exposure: Considerations in method selection . Am. Ind. Hyg. Assoc. J. , 61 ( 4 ) : 544 – 556 .
   Web of Science ®Google Scholar
• Huynh , C. K. , Vu-Duc , T. and Savolainen , H. 1992 . Design and evaluation of a solid sampler for the monitoring of airborne 1,6-hexamethylene diisocyanate (HDI) and its prepolymers in two-component spray painting . Am. Ind. Hyg. Assoc. J. , 53 : 157 – 162 .
   PubMed Web of Science ®Google Scholar
• Fent , K. W. , Jayaraj , K. Ball , L. M. 2008 . Quantitative monitoring of dermal and inhalation exposure to 1,6-hexamethylene diisocyanate monomer and oligomers . J. Environ. Monit. , 10 ( 4 ) : 500 – 507 .
   PubMed Web of Science ®Google Scholar
• 2005 . Washington State Division of Occupational Safety and Health: L&I Method 0050: HDI, IPDI, and MDI (Vapor) MAMA Derivatives . Available on request
   Google Scholar
• 2008 . Washington State Division of Occupational Safety and Health: “L&I Method 0067: HDI and IPDI Polyisocyanate Aerosol . Available on request from Washington State Department of Labor and Industry, Olympia, Wash
   Google Scholar
• Hornung , R. W. and Reed , R. L. 1990 . Estimation of average concentration in presence of nondetectable values . Appl. Occup. Environ. Hyg. , 5 : 46 – 51 .
   Google Scholar
• Pronk , A. , Tielemans , E. Skarping , G. 2006 . Inhalation exposure to isocyanates of car body repair shop workers and industrial spray painters . Ann. Occup. Hyg. , 50 ( 1 ) : 1 – 14 .
   PubMed Web of Science ®Google Scholar
• Nordqvist , Y. , Nilsson , U. Colmsjo , A. 2005 . A chemosorptive cylindrical denuder designed for personal exposure measurements of isocyanates-evaluation on generated aerosols of 4,4’-methylenediphenyl diisocyanate . J. Environ. Monit. , 7 ( 5 ) : 469 – 474 .
   PubMed Web of Science ®Google Scholar
• Spanne , M. , Grzybowski , P. and Bohgard , M. 1999 . Collection efficiency for submicron particles of a commonly used impinger . Am. Ind. Hyg. Assoc. J. , 60 : 540 – 544 .
   Web of Science ®Google Scholar
• Carlton , G. N. and Flynn , M. R. 1997 . The influence of spray painting parameters on breathing zone particle size distributions . Appl. Occup. Environ. Hyg. , 12 : 744 – 750 .
   Google Scholar
• Sabty-Daily , R. A. , Hinds , W. C. and Froines , J. R. 2005 . Size distribution of chromate paint aerosol generated in a bench-scale spray booth . Ann. Occup. Hyg. , 49 ( 1 ) : 33 – 45 .
   Web of Science ®Google Scholar
• Rando , R. J. , Poovey , H. G. and Mokadam , D. R. 2002 . “ Laboratory comparison of sampling methods for reactive isocyanate vapors and aerosols ” . In Isocyanates: Sampling, Analysis, and Health Effects (ASTM STP 1408) , West Conshohocken , PA : American Society for Testing and Materials .
   Google Scholar
• Liu , Y. , Stowe , M. H. Bello , D. 2009 . Skin exposure to aliphatic polyisocyanates in the auto body repair and refinishing industry: III. A personal exposure algorithm . Ann. Occup. Hyg. , 53 ( 1 ) : 33 – 40 .
   PubMed Web of Science ®Google Scholar
• Bello , D. , Sparer , J. Redlich , C. A. 2007 . Slow curing of aliphatic polyisocyanate paints in automotive refinishing: A potential source for skin exposure . J. Occup. Environ. Hyg. , 4 : 406 – 411 .
   PubMed Web of Science ®Google Scholar
• Dharmarajan , V. , Lingg , R. D. Booth , K. S. 1987 . “ Recent developments in the sampling and analysis of isocyanates in air ” . In Sampling and Calibration for Atmospheric Measurements , Edited by: Taylor , J. K. 190 – 202 . Philadelphia , PA : American Society for Testing and Materials .
   Google Scholar