236
Views
5
CrossRef citations to date
0
Altmetric
Original Articles

Nanocatalysts in Direct Methanol Fuel Cell Applications

, , &
Pages 394-399 | Received 12 Aug 2007, Accepted 20 Jan 2008, Published online: 12 Jun 2008

References

  • Thomas , C. E. , James , B. D. , Lomax , F. D. and Kuhn , I. F. 1998 . Fuel Options, for the Fuel Cell Vehicle: Hydrogen Methanol or Gasoline? . Int. J. Hydrogen Energy , 26 ( 6 ) : 551 – 67 .
  • Giorgi , R. , Ascarerlli , P. , Turtu , S. and Contini , V. 2001 . Nano‐sized Metal Catalysts in Electrodes for Solid Polymeric Electrolyte Fuel Cells: An XPS and XRD Study . Appl. Surf. Sci. , 178 ( 1–4 ) : 149 – 155 .
  • Farrauto , R. J. 2003 . From the Internal Combustion Engine to the Fuel Cell: Moving Towards the Hydrogen Economy . Stud. Surf. Sci. Catal. , 145 : 21 – 29 .
  • Pettersson , L. J. and Westerholm , R. 2001 . State of the Art of Multi‐fuel Reformers for Fuel Cell Vehicles: Problem Identification and Research Need . Int. J. Hydrogen Energy , 26 ( 3 ) : 243 – 264 .
  • Lindstrom , O. 1988 . That Incredible Fuel Cell . Chem. Tech. , 18 ( 8 ) : 490 – 497 .
  • Thomas , S. and Zalbowitz , M. 1999 . Fuel cells—Green Power . Los Alamos National Laboratory, New Mexico, Report No. LA‐UR‐99‐3231
  • Schimt , V. M. and Stimmning , U. 1996 . “ Fuel Cell Systems for Vehicle Applications ” . In New Promising Electrochemical Systems for Rechargeable batteries Edited by: Barsukov , V. and Beck , F. 233 – 246 . Deventer, , The Netherlands : Kluwer Academic Publihsers .
  • Ahmed , S. , Doshi , R. , Lee , S. H.D. , Kumar , R. and Krumpelt , M. Partial oxidation reformer development for fuel cell vehicles, Proceedings of 32nd Intersociety Energy Conversion Engineering Conference , pp. 843 – 846 .
  • Amphlett , J. C. , Klassen , R. D. , Mann , R. F. and Peppley , B. A. Methanol, Diesel Oil and Ethanol as Liquid Sources of Hydrogen for PEM Fuel Cells, Proceedings of 28th Intersociety Energy Conversion Engineering Conference , Vol. 1 , pp. 1221 – 26 .
  • Prater , K. B. 1994 . Polymer Electrolyte Fuel Cells: A Review of Recent Developments . J. Power Sources , 51 ( 1–2 ) : 129 – 144 .
  • Ascarelli , P. , Cini , M. , Missoni , G. and Nistico , N. 1977 . XPS Line Broadening in Small Metal Particles . J. de Physique , 2 : 125 – 128 .
  • Ascarelli , P. and Cini , M. 1989 . Emission and Scattering Techniques Edited by: Day , P. 353 – 354 . Dordrecht : Reidel .
  • Miyao , K. , Onodera , H. and Takezawa , N. 1994 . Highly Active Copper Catalysts for Steam Reforming of Methanol . React. Kinet. Catal. Lett. , 53 ( 2 ) : 379 – 83 .
  • Snytnikov , P. V. , Sobyanin , V. A. , Belyaev , V. D. , Tsyrulnikov , P. G. , Shitova , N. B. and Shlyapin , D. A. 2003 . Selective Oxidation of Carbon Monoxide in Excess Hydrogen Over Pt‐, Ru‐ and Pd‐supported Catalysts . Appl. Catal. A , 239 ( 1–2 ) : 149 – 156 .
  • Zhou , W. J. , Zhou , B. , Zhou , Z. H. , Li , W. Z. , Song , S. Q. , Wei , Z. , Sun , G. Q. and Xin , Q. 2004 . A Novel Route to Prepare Pt‐based Electro-Catalysts for Direct Methanol (ethanol) Fuel Cells, Nanotechnology in Catalysis Edited by: Zhou , B. , Hermans , S. and Somorjai , G. A. Vol. 1 , 183 – 200 . New York, NY : Springer Science+Business Media Inc. .
  • Japanese Patent JP 11138007 . 1999 . Honda Motor Co. Ltd.
  • Cameron , D. , Holliday , R. and Thompson , D. 2003 . Gold's Future Role in Fuel Cell System . J. Power Sources , 118 ( 1–2 ) : 298 – 303 .
  • Thompson , D. T. 2004 . Catalysis by Gold/platinum Group Metals. Mixed Metal Systems Displaying Increased Activity . Platinum Met. Rev. , 48 ( 4 ) : 169 – 172 .
  • Corti , C. W. , Holliday , R. J. and Thompson , D. T. 2002 . Developing New Industrial Applications for Gold: Gold Nanotechnology . Gold Bull. , 35 ( 4 ) : 111 – 117 .
  • King , W. D. , Corn , J. D. , Murphy , O. J. , Boxall , D. L. , Kenik , E. A. , Kwiatkowkski , K. C. , Stocks , S. R. and Lukehart , C. M. 2003 . Pt‐Ru and Pt‐Ru‐P/carbon Nanocomposites Synthesis, Characterization, and Unexpected Performance as Direct Methanol Fuel Cell (DMFC) Anode Catalysts . J. Phys. Chem. B , 107 ( 23 ) : 5467 – 5474 .
  • Hogarth , M. P. and Ralph , T. R. 2002 . Catalysis for Low Temperature Fuel Cells: Part III: Challenges for the Direct Fuel Cells . Platinum Met. Rev. , 46 ( 4 ) : 146
  • Tremiliosi‐Filho , G. , Kim , H. , Chrzanowski , W. , Wieckowski , A. , Grzybowska , B. and Kulesza , P. 1999 . Reactivity Activation Parameters in Methanol Oxidation on Platinum Single Crystal Electrodes ‘Decorated’ by Ruthenium Adlayers . J. Electroanal. Chem. , 467 ( 1–2 ) : 143 – 156 .
  • Frelink , T. , Visscher , W. and van Veen , J. A. R. 1996 . Measurement of the Ru Surface Content of Electrocodeposited PtRu Electrodes with the Electrochemical Quartz Crystal Microbalance: Implications for Methanol and CO Electrooxidation . Langmuir , 12 ( 15 ) : 3702 – 3708 .
  • Watanabe , M. , Uchina , M. and Motoo , S. 1987 . Preparation of Highly Dispersed Platinum+Ruthenium Alloy Clusters and the Activity for the Electooxidation of Methanol . J. Electroanal. Chem. , 229 ( 1—2 ) : 395 – 406 .
  • Boxall , D. L. , Deluga , G. A. , Kenik , E. A. , King , W. D. and Lukahart , C. M. 2001 . Rapid Synthesis of a Pt1Ru1/Carbon Nanocomposite Using Microwave Irradiation: A DMFC Anode Catalyst of High Relative Performance . Chem. Mater. , 13 ( 3 ) : 891 – 900 .
  • Steigerwalt , E. S. , Deluga , G. A. , Cliffel , D. E. and Lukehart , C. M. 2001 . A Pt‐Ru/graphitic Carbon Nanofiber Nanocomposite Exhibiting High Relative Performance as a Direct‐methanol Fuel Cell Anode Catalyst . J. Phys. Chem. B , 105 ( 34 ) : 8097 – 8101 .
  • Nallas , G. N.A. , Jones , S. W. and Brewer , K. 1996 . Bipyrimidine‐bridged mixed‐metal Trimetallic Complexes of Ruthenium(II) with Rhodium (III) or Iridium (III), {[(bpy)2Ru(bpm)]2MCl2}5+ . J. Inorg. Chem. , 35 ( 24 ) : 6974 – 6980 .
  • Lukehart , C. M. , Boxall , D. L. , Corn , J. D. , Hariharasarma , M. , King , W. D. , Kwitakowski , K. C. , Steigerwalt , E. S. and Kenik , E. A. 1999 . Prepr. Symp. Am. Chem. Soc., Div. Fuel Chem. , 44 ( 4 ) : 982 – 986 .
  • Chin , D. T. and Howard , P. D. 1986 . Hydrogen Sulfide Poisoning of Platinum Anode in Phosphoric Acid Fuel Cell Electrolyte . J. Electrochem. Soc. , 133 ( 12 ) : 2447 – 2450 .
  • Nakagawa , K. , Nishitani‐Gamo , M. and Ando , T. 2005 . Hydrogen Production from Methane for Fuel Cell Using Oxidized Diamond‐supported Catalysts . Int. J. Hydrogen Technology , 30 ( 2 ) : 201 – 207 .
  • King , W. D. , Steigerwalt , E. S. , Deluga , G. A. , Corn , J. D. , Boxall , D. L. , Moore , J. T. , Chu , D. , Jiang , R. , Kenik , E. A. and Lukehart , C. M. 2004 . Pt‐Ru/Carbon Nanocomposites, Nanotechnology in Catalysis Edited by: Zhou , B. , Hermans , S. and Somorjai , G. A. Vol. 1 , 201 – 220 . New York, NY : Springer Science+Business Media Inc. .
  • Liu , Z. , Gan , L M. , Hong , L. , Chen , W. and Lee , J. Y. 2005 . Carbon‐supported Pt Nanoparticles as Catalysts for Proton Exchange Membrane Fuel Cells . J. Power Sources , 139 ( 1–2 ) : 73 – 78 .
  • Okitsu , K. , Yue , A. , Tanabe , S. and Matsumoto , H. 2000 . Sonochemical Preparation and Catalytic Behavior of Highly Dispersed Palladium Nanoparticles on Alumina . Chem. Mater. , 12 ( 10 ) : 3006 – 3011 .
  • Fujimoto , T. , Teraushi , S. , Umehara , H. , Kjima , I. and Henderson , W. 2001 . Sonochemical Preparation of Single‐dispersion Metal Nanoparticles from Metal Salts . Chem. Mater. , 13 ( 3 ) : 1057 – 1060 .
  • Ocampo , A. L. , Miranda‐Hernandez , M. , Morgado , J. , Montoya , J. A. and Sebastian , P. J. 2006 . Characterization and Evaluation of Pt‐Ru Catalyst Supported on Multi‐walled Carbon Nanotubes by Electrochemical Impedance . J. Power Sources , 160 ( 2 ) : 915 – 924 .
  • Komarneni , S. , Li , D. S. , Newalkar , B. , Hatsuki , H. and Bhalla , A. S. 2002 . Microwave‐polyol Process for Pt and Ag Nanoparticles . Langmuir , 18 ( 15 ) : 5959 – 5962 .
  • Chen , W. X. , Lee , J. Y. and Liu , Z. L. 2002 . Microwave‐assisted Synthesis of Carbon Supported Pt Nanoparticles for Fuel Cell Applications . Chem. Commun. , 21 : 588 – 2589 .
  • Le Gratiet , B. , Remita , H. , Picq , G. and Delcourt , M. O. 1996 . CO‐stabilized Supported Pt Catalysts for Fuel Cells: Radiolytic Synthesis . J. Catal. , 164 ( 1 ) : 36 – 43 .
  • Yu , W. , Tu , W. and Liu , H. 1999 . Synthesis of Nanoscale Platinum Colloids by Microwave Dielectric Heating . Langmuir , 15 ( 1 ) : 6 – 9 .
  • Li , W. , Zhou , W. , Li , H. , Zhou , Z. , Zhou , B. , Sun , G. and Xin , Q. 2004 . Nano‐stuctured Pt–FeC as Cathode Catalyst in Direct Methanol Fuel Cell . Electrochimica Acta , 49 ( 7 ) : 1045 – 1055 .
  • Aksoylu , A. E. , Freitas , M. and Figueiredo , J. L. 2000 . Bimetallic Pt‐Sn Catalysts Supported on Activated Carbon. I. The Effect of Support Medication and Impregnation Strategy . Appl. Catal. A , 192 ( 1 ) : 29 – 42 .
  • Watanabe , M. and Sakairi , K. US Patent 5728485 . 1998 .
  • Haruta , M. 2002 . Catalysis of Gold Nanoparticles Deposited on Metal Oxides . CatTech. , 6 ( 3 ) : 102 – 115 .
  • Arico , A. S. , Shukla , A. K. , Kim , H. , Park , S. , Min , M. and Antonucci , V. 2001 . An XPS Study on Oxidation States of Pt and its Alloys with Co and Cr and its Relevance to Electroreduction of Oxygen . Appl. Surf. Sci. , 172 ( 1–2 ) : 33 – 40 .
  • Neergat , M. , Shukla , A. K. and Gandhi , K. S. 2001 . Platinum Based Alloys as Oxygen‐reduction Catalysts for Solid‐polymer‐electrolyte Direct Methanol Fuel Cells . J. Appl. Electrochem. , 31 ( 4 ) : 373 – 378 .
  • Haruta , M. 1997 . Size‐ and Support‐dependency in the Catalysis of Gold . Catal. Today , 36 ( 1 ) : 153 – 166 .
  • Hutchings , G. J. 1996 . Catalysis: A Golden Future . Gold Bull. , 29 ( 4 ) : 123 – 130 .
  • Thompson , D. 1998 . New Advances in Gold Catalysis Part I . Gold Bull. , 31 ( 4 ) : 111 – 118 .
  • Thompson , D. 1999 . New Advances in Gold Catalysis Part II . Gold Bull. , 32 ( 1 ) : 12 – 19 .
  • Bond , G. C. and Thompson , D. T. 1999 . Catalysis by Gold . Catal. Rev. Sci. Eng. , 41 ( 3–4 ) : 319 – 388 .
  • Bond , G. C. and Thompson , D. T. 2000 . Gold‐catalysed Oxidation of Carbon Monoxide . Gold Bull. , 33 ( 2 ) : 41 – 51 .
  • Mann , J. 2001 . Killer Nanotubes . Chem. Britain , 37 ( 11 ) : 22
  • Japanese Patent JP 10216518 . 1998 . Toyota Jidosha KK
  • Kahlich , M. J. , Gasteiger , H. A. and Behn , R. J. 1999 . Kinetics of the Selective Low‐temperature Oxidation of CO in H2‐rich Gas Over Au/α‐Fe2O3 . J. Catal. , 182 ( 2 ) : 430 – 440 .
  • Schubert , M. M. , Plzak , V. , Garche , J. and Behm R , J. 2001 . Activity, Selectivity, and Long‐term Stability of Different Metal Oxide Supported Gold Catalysts for the Preferential CO Oxidation in H2 Rich Gas . Catal. Lett. , 76 ( 3–41 ) : 143 – 150 .
  • Grisel , R. , Westrate , K. J. , Gluhoi , A. and Nieuwenhuys , B. E. 2002 . Catalysis by Gold Nanoparticles . Gold Bull. , 35 ( 2 ) : 39 – 45 .
  • Gardner , S. D. , Hoflund , G. B. , Schryer , D. R. , Upchurch , B. T. and Kielin , E. J. 1991 . Catalytic Behavior of Noble Metal/reducible Oxide Materials for Low‐temperature Carbon Monoxide Oxidation. 1. Comparison of Catalyst Performance . Langmuir , 7 ( 10 ) : 2135 – 2139 .
  • Andreeva , D. , Idakiev , V. , Tabakova , T. , Illieva , L. , Falaras , P. , Bourlinos , A. and Travlos , A. 2002 . Low‐temperature Water‐gas Shift Reaction over Au/CeO2 Catalysts . Catal. Today , 72 ( 1–2 ) : 51 – 57 .
  • Panzera , G. , Modafferi , V. , Candamano , S. , Donato , A. , Frusteri , F. and Antonucci , P. L. 2004 . CO Selective Oxidation on Ceria‐supported Au Catalysts for Fuel Cell Application . J. Power Sources , 135 ( 1–2 ) : 177 – 183 .
  • Burke , L. D. and Nugent , F. 1998 . The Electrochemistry of Gold. II The Electrocatalytic Behavior of the Metal in Aqueous Media . Gold Bull. , 31 ( 2 ) : 39 – 50 .
  • Nieuwenhuys , B. E. , Gluhoi , A. C. , Rienks , E. D. L. , Weststrate , C. J. and Vinod , C. P. 2005 . Chaos, Oscillations and the Golden Future of Catalysis . Catalysis Today , 100 ( 1–2 ) : 49 – 54 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.