A Trinuclear Cu(II) Complex from the Use of Phenyl 2-Pyridyl Ketoxime: Structure and Magnetic Behavior

REFERENCES

• Afrati , T. , Zaleski , C. M. , Dendrinou-Samara , C. , Mezei , G. , Kampf , J. M. , Pecoraro , V. L. and Kessissoglou , D. P. 2007 . Di-2-pyridyl ketone oxime in copper chemistry: di-, tri-, penta- and hexanuclear complexes . Dalton Trans. , : 2658 – 2668 .
   PubMed Web of Science ®Google Scholar
• Winpenny , R. E. P. 2001 . High-nuclearity paramagnetic 3d-metal complexes with oxygen- and nitrogen-donor ligands . Adv. Inorg. Chem. , 52 : 1 – 111 .
   Web of Science ®Google Scholar
• Bodwin , J. J. , Cutland , A. D. , Malkani , R. G. and Pecoraro , V. L. 2001 . The development of chiral metallacrowns into anion recognition agents and porous materials . Coord. Chem. Rev. , 216 : 489 – 512 .
   Web of Science ®Google Scholar
• Pecoraro , V. L. 1989 . Structural characterization of [VO(salicylhydroximate)(CH3OH)]3: applications to the biological chemistry of vanadium(V) . Inorg. Chem. Acta , 155 : 171 – 173 .
   Web of Science ®Google Scholar
• Dendrinou-Samara , C. , Alexiou , M. , Zaleski , C. M. , Kampf , J. W. , Kirk , M. L. , Kessissoglou , D. P. and Pecoraro , V. L. 2003 . Synthesis and magnetic properties of a metallacryptate that behaves as a single-molecule magnet . Angew. Chem. Int. Ed. , 42 : 3763 – 3766 .
   PubMed Web of Science ®Google Scholar
• Zaleski , C. M. , Depperman , E. C. , Kampf , J. W. , Kirk , M. L. and Pecoraro , V. L. 2004 . Synthesis, structure, and magnetic properties of a large lanthanide-transition-metal single-molecule magnet . Angew. Chem. Int. Ed. , 43 : 3912 – 3914 .
   PubMed Web of Science ®Google Scholar
• Zaleski , C. M. , Depperman , E. C. , Dendrinou-Samara , C. , Alexiou , M. , Kampf , J. W. , Kessissoglou , D. P. , Kirk , M. L. and Pecoraro , V. L. 2005 . Metallacryptate single-molecule magnets: Effect of lower molecular symmetry on blocking temperature . J. Am. Chem. Soc. , 127 : 12862 – 12872 .
   PubMed Web of Science ®Google Scholar
• Zaleski , C. M. , Depperman , E. , Kampf , J. W. , Kirk , M. L. and Pecoraro , V. L. 2006 . Using Ln(III)[15-MCCu II(N)(S)-(pheHA)-5]3 + complexes to construct chiral single-molecule magnets and chains of single-molecule magnets . Inorg. Chem. , 45 : 10022 – 10024 .
   PubMed Web of Science ®Google Scholar
• Milios , C. J. , Kefalloniti , E. , Raptopoulou , C. P. , Terzis , A. , Escuer , A. , Vicente , R. and Perlepes , S. P. 2004 . 2-Pyridinealdoxime [(py)CHNOH] in manganese(II) carboxylate chemistry: mononuclear, dinuclear, tetranuclear and polymeric complexes, and partial transformation of (py)CHNOH to picolinate(-1) . Polyhedron , 23 : 83 – 95 .
   Web of Science ®Google Scholar
• Chaudhuri , P. 2003 . Homo- and hetero-polymetallic exchange coupled metal-oximates . Coord. Chem. Rev. , 243 : 143 – 190 .
   Web of Science ®Google Scholar
• Goldcamp , M. J. , Robison , S. E. , Krause , J. A. and Baldwin , M. J. 2002 . Oxygen reactivity of a nickel(II)-polyoximate complex . Inorg. Chem. , 41 : 2307 – 2309 .
   PubMed Web of Science ®Google Scholar
• Alexiou , M. , Katsoulakou , E. , Dendrinou-Samara , C. , Raptopoulou , C. P. , Psycharis , V. , Manessi-Zoupa , E. , Perlepes , S. P. and Kessissoglou , D. P. 2005 . Di-2-pyridyl ketone oxime in zinc chemistry: Inverse 12-metallacrown-4 complexes and cationic pentanuclear clusters . Eur. J. Inorg. Chem. , : 1964 – 1978 .
   Web of Science ®Google Scholar
• Isele , K. , Franz , P. , Ambrus , C. , Bernardinelli , G. , Decurtins , S. and Williams , A. F. 2005 . Self-assembly and interconversion of tetranuclear copper(II) complexes . Inorg. Chem. , 44 : 3896 – 3906 .
   PubMed Web of Science ®Google Scholar
• Yoon , J. , Mirica , L. M. , Stack , T. D. P. and Solomon , E. I. 2005 . Variable-temperature, variable-field magnetic circular dichroism studies of tris-hydroxy- and μ3-oxo-bridged trinuclear Cu(II) complexes: Evaluation of proposed structures of the native intermediate of the multicopper oxidases . J. Am. Chem. Soc. , 127 : 13680 – 13693 .
   PubMed Web of Science ®Google Scholar
• Ferrer , S. , Haasnoot , J. G. , Reedijk , J. , Muller , E. , Biagini Cingi , M. , Lanfranchi , M. , Manotti Lanfredi , A. M. , Ribas , J. and Trinuclear , N . 2000 . N-bridged copper(II) complexes involving a Cu3OH core: [Cu3(μ3-OH)L3A(H2O)2]A· (H2O)x L = 3-Acetylamino-1,2,4-triazolate; A = CF3SO3, NO3, ClO4; x = 0, 2 synthesis, X-ray Structures, spectroscopy, and magnetic properties . Inorg. Chem. , 39 : 1859 – 1867 .
   PubMed Web of Science ®Google Scholar
• Dendrinou-Samara , C. , Katsamakas , S. , Raptopoulou , C. , Terzis , A. , Tangoulis , V. and Kessissoglou , D. P. 2007 . Interaction of Fe(III) with herbicide-carboxylato ligands: Di-, tri- and tetra-nuclear compounds: Structure and magnetic behavior . Polyhedron , 26 : 763 – 772 .
   Web of Science ®Google Scholar
• Kahn , O. 1993 . Molecular Magnetism , New York : VCH Publishers, Inc. .
   Google Scholar
• Bruker . 2002 . SAINT , Madison, W1 : Bruker AXS Inc. .
   Google Scholar
• Sheldrick , G. M. 1996 . SADABS, Program for Empirical Absorption Correction of Area Detector Data , Germany : University of Göttingen .
   Google Scholar
• Sheldrick , G. M. 1997 . SHELXS-97, Program for Crystal Structure Solution , Germany : University of Göttingen .
   Google Scholar
• Sheldrick , G. M. 1997 . SHELXL-97, Program for Crystal Structure Refinement , Germany : University of Göttingen .
   Google Scholar
• Afrati , T. , Dendrinou-Samara , C. , Raptopoulou , C. , Terzis , A. , Tangoulis , V. and Kessissoglou , D. P. 2007 . Copper inverse-9-metallacrown-3 compounds showing antisymmetric magnetic behaviour . Dalton Trans. , : 5156 – 5164 .
   PubMed Web of Science ®Google Scholar
• Stamatatos , T. C. , Vlahopoulou , J. C. , Sanakis , Y. , Raptopoulou , C. P. , Psycharis , V. , Boudalis , A. K. and Perlepes , S. P. 2006 . Formation of the Cu3(μ3-OH)5 + core in copper(II) carboxylate chemistry via use of di-2-pyridyl ketone oxime [(py)2CNOH]: [Cu3(OH)(O2CR)2(py)2CNO}3] (R = Me, Ph) . Inorg. Chem. Commun. , 9 : 814 – 818 .
   Web of Science ®Google Scholar
• Milios , C. J. , Piligkos , S. , Bell , A. R. , Laye , R. H. , Teat , S. J. , Vicente , R. , McInnes , E. , Escuer , A. , Perlepes , S. P. and Winpenny , R. E. P. 2006 . A rare mixed-valence state manganese(II/IV) tetranuclear cage formed using phenyl 2-pyridyl ketone oxime and azide as ligands . Inorg. Chem. Commun. , 9 : 638 – 641 .
   Web of Science ®Google Scholar
• Stamatatos , T. C. , Foguet-Albiol , D. , Stoumpos; , C. C. , Raptopoulou , C. P. , Terzis , A. , Wernsdorfer , W. , Perlepes , S. P. and Christou , G. 2007 . New Mn3 structural motifs in manganese single-molecule magnetism from the use of 2-pyridyloximate ligands . Polyhedron , 26 : 2165 – 2168 .
   Web of Science ®Google Scholar