A new mononuclear Cd(II) complex CdL₂I₂ (L = 6-nitro-imidazo(1,2-a)pyridine) made up by a novel in situ reaction

References

• Wang, M.-S.; Guo, S.-P.; Li, Y.; Cai, L.-Z.; Zou, J.-P.; Xu, G.; Zhou, W.-W.; Zheng, F.-K.; Guo, G.-C. A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light. J. Am. Chem. Soc. 2009, 131, 13572–13573.
   PubMed Web of Science ®Google Scholar
• Liu, Z.-F.; Wu, M.-F.; Wang, S.-H.; Zheng, F.-K.; Wang, G.-E.; Chen, J.; Xiao, Y.; Wu, A-Q.; Guo, G.-C.; Huang, J.-S. Eu3+-doped Tb3+ metal–organic frameworks emitting tunable three primary colors towards white light. J. Mater. Chem. C 2013, 1, 4634–4639.
   Web of Science ®Google Scholar
• Ouellette, W. A.; Prosvirin, V.; Valeich, J.; Dunbar, K. R.; Zubieta, J. Hydrothermal synthesis, structural chemistry, and magnetic properties of materials of the MII/triazolate/anion family, where MII = Mn, Fe, and Ni. Inorg. Chem. 2007, 46, 9067–9082.
   PubMed Web of Science ®Google Scholar
• Pan, L.; Sander, M. B.; Huang, X.; Li, J.; Smith, M.; Bittner, E.; Bockrath, B.; Johnson, J. K. Microporous metal organic materials: promising candidates as sorbents for hydrogen storage. J. Am. Chem. Soc. 2004, 126, 1308–1309.
   PubMed Web of Science ®Google Scholar
• Zhou, W.-W.; Chen, J.-T.; Xu, G.; Wang, M.-S.; Zou, J.-P.; Long, X.-F.; Wang, G.-J.; Guo, G.-C.; Huang, J.-S. Nonlinear optical and ferroelectric properties of a 3-D Cd(II) triazolate complex with a novel (63)2(610·85) topology. Chem. Commun. 2008, 2762–2764.
   PubMed Web of Science ®Google Scholar
• Zhou, W.-W.; Liu, B.; Chen, W-T.; Zheng, F.-K.; Chen, J.-T.; Guo, G.-C.; Huang, J.-S. A Zinc TTR complex with a novel 2-D structure (TTR = 3-amino-1H-1,2,4-triazole). Chinese J. Struct. Chem. 2007, 26, 703–706.
   Web of Science ®Google Scholar
• Amijs, C. H. M.; van Klink, G. P. M.; van Koten, G. Metallasupramolecular architectures, an overview of functional properties and applications. Dalton Trans. 2006, 308–327.
   PubMed Web of Science ®Google Scholar
• Janiak, C. Engineering coordination polymers towards applications. Dalton Trans. 2003, 2781–2804.
   Web of Science ®Google Scholar
• Furman, J. D.; Warner, A. Y.; Teat, S. J.; Mikhailovsky, A. A.; Cheetham, A. K. Tunable, ligand-based emission from inorganic-organic frameworks: a new approach to phosphors for solid state lighting and other applications. Chem. Mater. 2010, 22, 2255–2260.
   Web of Science ®Google Scholar
• Zhou, W.-W.; Zhao, W.; Wei, B.; Wang, F.-W.; Chen, Y.-H.; Fang, W.-Y.; Zhao, X. A new 1D Cd(II) pyridinate polymer: Structure, second-harmonic generation response, dielectric and potential ferroelectric properties. Inorg. Chim. Acta 2012, 386, 17–21.
   Web of Science ®Google Scholar
• Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M. Supramolecular isomerism within three-dimensional 3-connected nets: unusual synthesis and characterization of trimorphic copper(I) 3,5-dimethyl-1,2,4-triazolate. Dalton Trans. 2005, 3681–3685.
   PubMed Web of Science ®Google Scholar
• Hu, S.; Chen, J.-C.; Tong, M.-L.; Wang, B.; Yan, Y.-X.; Batten, S.-R. Cu2+-mediated dehydrogenative coupling and hydroxylation of an N-heterocyclic ligand: from generation of a new tetratopic ligand to the designed assembly of three-dimensional copper(I) coordination polymers, Angew. Chem., Int. Ed. 2005, 44, 5471–5475.
   PubMed Web of Science ®Google Scholar
• Zhang, X.-M.; Fang, R.-Q.; Wu, H.-S. A twelve-connected Cu6S4 cluster-based coordination polymer. J. Am. Chem. Soc. 2005, 127, 7670–7671.
   PubMed Web of Science ®Google Scholar
• Li, D.; Wu, T. Transformation of inorganic sulfur into organic sulfur: a novel photoluminescent 3-D polymeric complex involving ligands in situ formation. Inorg. Chem. 2005, 44, 1175–1177.
   PubMed Web of Science ®Google Scholar
• Li, D.; Wu, T.; Zhou, X.-P.; Zhou, R.; Huang, X.-C. Twelve-connected net with face-centered cubic topology: a coordination polymer based on [Cu12(m4-SCH3)6]6+ clusters and CN− linkers. Angew. Chem., Int. Ed. 2005, 44, 4175–4178.
   PubMed Web of Science ®Google Scholar
• Cheng, L.; Zhang, W.-X.; Ye, B.-H.; Lin, J.-B.; Chen, X.-M. In situ solvothermal generation of 1,2,4-triazolates and related compounds from organonitrile and hydrazine hydrate: a mechanism study. Inorg. Chem. 2007, 46, 1135–1143.
   PubMed Web of Science ®Google Scholar
• Tian, H.; Fu, D.-W.; Ye, Q.; Xiong, R.-G. Two novel noncentrosymmetric zinc coordination compounds with second harmonic generation response, and potential piezoelectric and ferroelectric properties. Cryst. Growth Des. 2009, 9, 2026–2029.
   Web of Science ®Google Scholar
• Zhou, W.-W.; Zhao, W.; Wang, F.-W.; Fang, W.-Y.; Liu, D.-F.; Wei, Y.-J.; Xu, M.; Zhao, X.; Liang, X. A 3-D metal–organic framework with a rutile topology network, right- or left- handed helical chains and tunable UV-to-visible photoluminescence. RSC Adv. 2015, 5, 42616–42620.
   Web of Science ®Google Scholar
• Aromí, G.; Barrios, L. A.; Roubeau, O.; Gamez, P. Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials. Coord. Chem. Rev. 2011, 255, 485–546.
   Web of Science ®Google Scholar
• SHELXL-2014, Program for Refinement of Crystal Structures; University of Göttingen, Germany, 2014.
   Google Scholar
• Fu, D.-W.; Zhang, W.; Xiong, R.-G.. The first metal–organic framework (MOF) of Imazethapyr and its SHG, piezoelectric and ferroelectric properties. Dalton Trans. 2008, 3946–3948.
   PubMed Web of Science ®Google Scholar
• Zhai, Q.-G.; Lu, C.-Z.; Wu, X.-Y.; Batten, S. R. Coligand modulated six-, eight-, and ten-connected Zn/Cd-1,2,4-triazolate frameworks based on mono-, bi-, tri-, penta-, and heptanuclear cluster units. Cryst. Growth Des. 2007, 7, 2332–2342.
   Web of Science ®Google Scholar
• Zhai, Q.-G.; Wu, X.-Y.; Chen, S.-M.; Lu, C.-Z.; Yang, W.-B. Construction of Cd/Zn(II)-1,2,4-triazolate coordination complexes via changing substituents and anions. Cryst. Growth Des. 2006, 6, 2126–2135.
   Web of Science ®Google Scholar
• Li, B.-Z.; Liu, X.-G.; Peng, Y.-F.; Li, B.-L.; Zhang, Y. A novel three-dimensional cadmium(II) coordination polymer incorporating 1,4-bis(1,2,4-triazol-1-yl-methyl)benzene and thiocyanate. Acta Cryst. 2006, C62, m41–m44.
   Google Scholar
• Li, B.; Zhu, X.; Zhou, J.; Peng, Y.; Zhang, Y. Syntheses and structures of five cadmium(II) coordination polymers from 1,2-bis(1,2,4-triazol-1-yl)ethane. Polyhedron 2004, 23, 3133–3141.
   Web of Science ®Google Scholar