296
Views
1
CrossRef citations to date
0
Altmetric
Research Article

The effect of Cr alloying with Pt/C as an electrocatalyst for low temperature PEM fuel cell

ORCID Icon, &
Pages 3239-3252 | Received 27 Dec 2021, Accepted 30 Mar 2022, Published online: 17 Apr 2022

References

  • Borbáth, I., K. Zelenka, Á. Vass, Z. Pászti, G. P. Szijjártó, Z. Sebestyén, G. Sáfrán, and A. Tompos. 2021. CO tolerant Pt electrocatalysts for PEM fuel cells with enhanced stability against electrocorrosion. International Journal of Hydrogen Energy 46 (25):13534–47. doi:10.1016/j.ijhydene.2020.08.002.
  • Chaisubanan, N., W. Maniwan, and M. Hunsom. 2017. Effect of heat-treatment on the performance of PtM/C (M= Cr, Pd, Co) catalysts towards the oxygen reduction reaction in PEM fuel cell. Energy 127:454–61. doi:10.1016/j.energy.2017.03.162.
  • Chinthala. M., Balakrishnan. A, Venkatraman. P, Manaswini Gowtham. V, Polagani. R. K. 2021. Synthesis and applications of nano-MgO and composites for medicine, energy, and environmental remediation: a review. Environmental Chemistry Letters 19:4415–4454. doi:10.1007/s10311-021-01299-4.
  • Cui, Z., H. Chen, W. Zhou, M. Zhao, and F. J. Disalvo. 2015. Structurally ordered Pt3Cr as oxygen reduction electrocatalyst: ordering control and origin of enhanced stability. Chemistry of Materials 27 (21):7538–45. doi:10.1021/acs.chemmater.5b03912.
  • Dong, H., and L. Dong. 2011. Electrocatalytic activity of carbon nanotube-supported Pt–Cr–Co tri-metallic nanoparticles for methanol and ethanol oxidations. Journal of Inorganic and Organometallic Polymers and Materials 21 (4):754–57. doi:10.1007/s10904-011-9526-2.
  • Gupta, G., P. Iqbal, F. Yin, J. Liu, R. E. Palmer, S. Sharma, K. C.-F. Leung, and P. M. Mendes. 2015. Pt diffusion dynamics for the formation Cr–Pt Core–shell nanoparticles. Langmuir 31 (24):6917–23. doi:10.1021/acs.langmuir.5b01410.
  • Gupta, G., S. Sharma, and P. M. Mendes. 2016. Nafion-stabilised bimetallic Pt–Cr nanoparticles as electrocatalysts for proton exchange membrane fuel cells (PEMFCs). RSC Advances 6 (86):82635–43. doi:10.1039/C6RA16025E.
  • Huang, H., X. Hu, J. Zhang, N. Su, and J. Cheng. 2017. Facile fabrication of platinum-cobalt alloy nanoparticles with enhanced electrocatalytic activity for a methanol oxidation reaction. Scientific Reports 7 (1):45555. doi:10.1038/srep45555.
  • Islam, J., S.-K. Kim, K.-H. Kim, E. Lee, and -G.-G. Park. 2021. Enhanced durability of Pt/C catalyst by coating carbon black with silica for oxygen reduction reaction. International Journal of Hydrogen Energy 46 (1):1133–43. doi:10.1016/j.ijhydene.2020.09.194.
  • Jeon, M. K., and P. J. McGinn. 2012. Co-alloying effect of Co and Cr with Pt for oxygen electro-reduction reaction. Electrochimica acta 64:147–53. doi:10.1016/j.electacta.2011.12.124.
  • Kaewsai, D., S. Yeamdee, S. Supajaroon, and M. Hunsom. 2018. ORR activity and stability of PtCr/C catalysts in a low temperature/pressure PEM fuel cell: effect of heat treatment temperature. International Journal of Hydrogen Energy 43 (10):5133–44. doi:10.1016/j.ijhydene.2018.01.101.
  • Khateeb, S., S. Guerreo, D. Su, R. M. Darling, L. V. Protsailo, and M. Shao. 2016. Fuel cell performance of palladium-platinum core-shell electrocatalysts synthesized in gram-scale batches. Journal of the Electrochemical Society 163 (7):F708–F713. doi:10.1149/2.1301607jes.
  • Kim, J. H., G. Kwon, H. Chun, and Y. T. Kim. 2014. Enhancement of activity and durability through Cr doping of TiO2 supports in Pt electrocatalysts for oxygen reduction reactions. ChemCatChem 6 (11):3239–45. doi:10.1002/cctc.201402466.
  • Kumar, P. R., P. L. Suryawanshi, S. P. Gumfekar, B. A. Bhanvase, and S. Sonawane. 2018. Sonochemical synthesis of Pt-Co/C electrocatalyst for PEM fuel cell applications. Surfaces and Interfaces 12:116–23. doi:10.1016/j.surfin.2018.04.002.
  • Kumar, P. R., P. L. Suryawanshi, S. P. Gumfekar, and S. H. Sonawane. 2017. Ultrasound-assisted synthesis of conducting polymer-based electrocatalysts for fuel cell applications. Chemical Engineering and Processing: Process Intensification 121:50–56. doi:10.1016/j.cep.2017.08.004.
  • Leong, T. S. H., G. J. O. Martin, and M. Ashokkumar. 2017. Ultrasonic encapsulation – A review. Ultrasonics Sonochemistry.
  • LiBretto, N. J., C. Yang, Y. Ren, G. Zhang, and J. T. Miller. 2019. Identification of surface structures in Pt3Cr intermetallic nanocatalysts. Chemistry of Materials 31 (5):1597–609. doi:10.1021/acs.chemmater.8b04774.
  • Liu, Z., Y. Yin, D. Yang, C. Zhang, P. Ming, B. Li, and S. Yang. 2020. Efficient synthesis of Pt–Co nanowires as cathode catalysts for proton exchange membrane fuel cells. RSC Advances 10 (11):6287–96. doi:10.1039/D0RA00264J.
  • Maniwan, W., K. Poochinda, and M. Hunsom. 2016. Activity and stability of PtxCr/C catalyst for oxygen reduction reaction: effect of the Pt:Cr ratio and heat treatment atmosphere. International Journal of Hydrogen Energy 41 (46):21404–14. doi:10.1016/j.ijhydene.2016.07.264.
  • Min, M., and H. Kim. 2016. Performance and stability studies of PtCr/C alloy catalysts for oxygen reduction reaction in low temperature fuel cells. International Journal of Hydrogen Energy 41 (39):17557–66. doi:10.1016/j.ijhydene.2016.07.175.
  • Parkash, A. 2020. Incorporation of Pt–Cr nanoparticles into highly porous MOF-5 as efficient oxygen reduction electrocatalysts. Nanotechnology 31 (44):445403. doi:10.1088/1361-6528/aba8bd.
  • Polagani, R. K., P. L. Suryawanshi, S. P. Gumfekar, S. H. Sonawane, and M. Ashokkumar. 2018. Ultrasound-assisted synthesis of Pt-Co/C bimetallic alloys for oxygen reduction in PEM fuel cells. Sustainable Energy and Fuels 2 (7):1491–99. doi:10.1039/C8SE00100F.
  • Polagani, R. K., P. L. Suryawanshi, S. H. Sonawane, and M. Chinthala. 2021. Electrocatalytic performance of sonochemically synthesized Pt–Ni/C nanoparticles in fuel cell application. International Journal of Chemical Reactor Engineering. doi: 10.1515/ijcre-2021-0225.
  • Pollet, B. G. 2019. The use of power ultrasound for the production of PEMFC and PEMWE catalysts and low-Pt loading and high-performing electrodes. Catalysts 1-18. 9 (3):246. doi:10.3390/catal9030246.
  • Rao, C. V., A. L. M. Reddy, Y. Ishikawa, and P. M. Ajayan. 2011. Synthesis and electrocatalytic oxygen reduction activity of graphene-supported Pt3Co and Pt3Cr alloy nanoparticles. Carbon 49 (3):931–36. doi:10.1016/j.carbon.2010.10.056.
  • Sahin, N. E., T. W. Napporn, L. Dubau, F. Kadirgan, J.-M. Léger, and K. B. Kokoh. 2017. Temperature-dependence of oxygen reduction activity on Pt/C and PtCr/C electrocatalysts synthesized from microwave-heated diethylene glycol method. Applied Catalysis. B, Environmental 203:72–84. doi:10.1016/j.apcatb.2016.09.026.
  • Sakthivel, M., I. Radev, V. Peinecke, and J.-F. Drillet. 2014. Highly active and stable Pt 3 Cr/C alloy catalyst for oxygen reduction reaction. ECS Transactions 61 (31):15–24. doi:10.1149/06131.0015ecst.
  • Sakthivel, M., I. Radev, V. Peinecke, and J.-F. Drillet. 2015. Highly active and stable Pt3 Cr/C alloy catalyst in H 2 -PEMFC . Journal of the Electrochemical Society 162 (8):F901–F906. doi:10.1149/2.0761508jes.
  • Singh, R. N., R. Awasthi, C. S. Sharma . 2014. Review: an overview of recent development of platinum-based cathode materials for direct methanol fuel cells. International Journal of Electrochemical Science 9 :5607–5639.
  • Taufany, F., C.-J. Pan, H.-L. Chou, J. Rick, Y.-S. Chen, D.-G. Liu, J.-F. Lee, M.-T. Tang, and B.-J. Hwang. 2011. Relating structural aspects of bimetallic Pt3Cr1/C nanoparticles to their electrocatalytic activity, stability, and selectivity in the oxygen reduction reaction. Chemistry – A European Journal 17 (38):10724–35. doi:10.1002/chem.201100556.
  • Xu, H., B. W. Zeigera, and K. S. Suslick. 2013. Sonochemical synthesis of nanomaterials. Chemical Society Reviews 42 (7):2555–67. doi:10.1039/C2CS35282F.
  • Zhang, X., H. Li, J. Yang, Y. Lei, C. Wang, J. Wang, Y. Tang, and Z. Mao. 2021. Recent advances in Pt-based electrocatalysts for PEMFCs. RSC Advances 11 (22):13316–28. doi:10.1039/D0RA05468B.
  • Zhang, C., X. Shen, Y. Pan, Z. Peng, D. Fang, B. Yi, and Z. Shao. 2017. A review of Pt-based electrocatalysts for oxygen reduction reaction. Frontiers in Energy 11 (3):260–67. doi:10.1007/s11708-017-0499-x.
  • Zou, L., J. Li, T. Yuan, Y. Zhou, X. Li, and H. Yang. 2014. Structural transformation of carbon-supported Pt3Cr nanoparticles from a disordered to an ordered phase as a durable oxygen reduction electrocatalyst. Nanoscale 6 (18):10686–92. doi:10.1039/C4NR02799J.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.