Rubber-Toughened Epoxies: A Critical Review

References

• May , C. A. 1988 . Introduction to Epoxy Resins, Epoxy Resins, Chemistry, and Technology , New York : Marcel Dekker .
   Google Scholar
• Lemay , J. D. and Kelly , F. N. 1986 . Structure and ultimate properties of epoxy resins . Advances in Polymer Science: Epoxy Resins and Composites III , 78 : 115 – 148 .
   Web of Science ®Google Scholar
• Garg , A. C. and Mai , Y. W. 1988 . Failure mechanism in toughened epoxy resins- A review . Comp. Sci. Tech. , 31 : 179 – 223 .
   Web of Science ®Google Scholar
• Bucknall , C. B. 1977 . Toughened Plastics , London : Applied Science .
   Google Scholar
• Sultan , J. N. , Liable , R. C. and McGarry , F. J. 1971 . Microstructure of two-phase polymers . Polym. Symp. , 16 : 127 – 136 .
   Google Scholar
• Manzione , L. T. , Gillham , J. K. and McPherson , C. A. 1981 . Rubber-modified epoxies: I. Transition and morphology . J. Appl. Polym. Sci. , 26 : 889 – 905 .
   Web of Science ®Google Scholar
• Riew , C. K. , Siebert , A. R. , Smith , R. W. , Fernando , M. and Kinloch , A. J. 1994 . Toughened epoxy resins: Performed particles as toughener . Proc. ACS, Polym. Mater. Sci. Eng. , 70 : 5 – 6 .
   Google Scholar
• Lovell , P. A. , McDonald , J. , Saunders , D. E. J. and Young , R. J. 1993 . Studies of rubber-toughened poly(methyl methacrylate): I. Preparation and thermal properties of blends poly(methyl methacrylate) with multiple-layer toughening particles . Polymer , 34 : 61 – 69 .
   Web of Science ®Google Scholar
• Dean , J. M. , Lipic , P. M. , Grubbs , R. B. , Cook , R. F. and Bates , F. S. 2001 . Micellar structure and mechanical properties of block copolymer-modified epoxies . J. Polym. Sci.: Part B: Polym. Phys. , 39 : 2996 – 3010 .
   Web of Science ®Google Scholar
• Dean , J. M. , Grubbs , R. B. , Saad , W. , Cook , R. F. and Bates , F. S. 2003 . Mechanical properties of block copolymer vesicle and micelle modified epoxies . J. Polym. Sci.: Part B: Polym. Phys. , 41 : 2444 – 2456 .
   Web of Science ®Google Scholar
• Ritzenthaler , S. , Court , F. , David , L. , Girard-Reydet , E. , Leibler , L. and Pascault , J. P. 2002 . ABC triblock copolymers/epoxy-diamine blends: Keys to achieve to nanostructured thermosets . Macromolecules , 35 : 6245 – 6254 .
   Web of Science ®Google Scholar
• Rebizant , V. , Abetz , V. , Tournilhac , F. , Court , F. and Leibler , L. 2003 . Reactive tetrablock copolymers containing glycidyl methacrylate: Synthesis and morphology control in epoxy-amine networks . Macromolecules , 36 : 9889 – 9896 .
   Web of Science ®Google Scholar
• Rebizant , V. , Venet , A. S. , Tournilhac , F. , Girard-Reydet , E. , Navarro , C. , Pascault , J. P. and Leibler , L. 2004 . Chemistry and mechanical properties of epoxy-based thermosets reinforced by reactive and non-reactive SBMX block copolymers . Macromolecules , 37 : 8017 – 8027 .
   Web of Science ®Google Scholar
• Ruzette , A. V. and Leibler , L. 2005 . Block copolymers in tomorrow's plastics . Nat. Mater. , 4 : 19 – 31 .
   PubMed Web of Science ®Google Scholar
• Kozii , V. V. and Rozenberg , B. A. 1992 . Mechanisms of energy dissipation in elastomer-modified thermosetting polymer matrics and composites based on such polymers . Polym. Sci. , 34 : 919 – 951 .
   Google Scholar
• Pearson , R. A. and Yee , A. F. 1991 . Influence of particle size and particle size distribution on toughening mechanisms in rubber-modified epoxies . J. Mater. Sci. , 26 : 3828 – 3844 .
   Web of Science ®Google Scholar
• Sue , H. J. 1991 . Study of rubber-modified brittle epoxy systems: Part II: Toughening mechanisms under mode-I fracture . Polym. Eng. Sci. , 31 : 275 – 288 .
   Web of Science ®Google Scholar
• Huang , Y. and Kinloch , A. J. 1992 . The role of plastic void growth in the fracture of rubber-toughened epoxy polymers . J. Mater. Sci. Lett. , 11 : 484 – 488 .
   Google Scholar
• Meeks , A. C. 1974 . Fracture and mechanical properties of epoxy resisn and rubber-modified epoxies Polymer . 15 : 675 – 681 .
   Google Scholar
• Huang , Y. and Kinloch , A. J. 1992 . Modelling of the toughening mechanisms in rubber-modified epoxy polymers . J. Mater. Sci. , 27 : 2753 – 2762 .
   Web of Science ®Google Scholar
• Kinloch , A. J. , Finch , C. A. and Hashemi , S. 1987 . Effect of segmental molecular mass between crosslinks of the matrix phase on the toughness of rubber-modified epoxies . Polym. Commun. , 28 : 322 – 325 .
   Web of Science ®Google Scholar
• Pearson , R. A. and Yee , A. F. 1989 . Toughening mechanisms in elastomer-modified epoxies: Part 3: The effect of crosslink density . J. Mater. Sci. , 24 : 2571 – 2580 .
   Web of Science ®Google Scholar
• Shaw , S. J. and Tod , D. A. 1989 . The effects of cure conditions on a rubber-modified epoxy adhesive . J. Adhesion , 28 : 231 – 246 .
   Web of Science ®Google Scholar
• Levita , G. , Petris , S. D. , Marchetti , A. and Lazzeri , A. 1991 . Crosslink density and fracture toughness of epoxy resisn . J. Mater. Sci. , 26 : 2348 – 2352 .
   Web of Science ®Google Scholar
• Liu , S. H. and Nauman , E. B. 1991 . Effects of crosslinking density on the toughening mechanisms of rubber-modified thermosets . 26 : 6581 – 6590 .
   Google Scholar
• Bradley , W. L. , Schultz , W. , Corelto , C. and Komatsu , S. 1993 . “The synergistic effect of crosslink density and rubber additions on the fracture toughness of polymers,” . In Toughened Plastics, Advances in Chemistry Series 233 , Edited by: Riew , C. K. and Kinloch , A. J. 317 – 333 . Washington : ACS .
   Google Scholar
• Chen , T. K. and Jan , Y. H. 1995 . Fracture behavior of rubber mounted high temperature epoxies . Polym. Eng. Sci. , 35 : 778 – 785 .
   Google Scholar
• Kishi , H. , Shi , Y. B. , Huang , J. and Yee , A. F. 1998 . Shear ductility and toughenability study of highly cross-linked epoxy/polyethersulphone . J. Mater. Sci. , 33 : 3479 – 3488 .
   Web of Science ®Google Scholar
• Franco , M. , Mondragon , I. and Bucknall , C. B. 1999 . Blends of epoxy resin with amine-terminated polyoxypropylene elastomer: Morphology and properties . J. Appl. Polym. Sci. , 72 : 427 – 434 .
   Web of Science ®Google Scholar
• Aizpurua , B. , Franco , M. , Corcuera , M. A. , Riccardi , C. C. and Mondragon , I. 2000 . Chemorheology and ultimate behavior of epoxy-amine mixtures modified with a liquid oligomer . J. Appl. Polym. Sci. , 76 : 1269 – 1279 .
   Web of Science ®Google Scholar
• Arias , M. L. , Frontini , P. M. and Williams , R. J. J. 2003 . Analysis of the damage zone around the crack tip for two rubber-modified epoxy matrices exhibiting different toughenability . Polymer , 44 : 1537 – 1546 .
   Web of Science ®Google Scholar
• Kang , B. U. , Jho , J. Y. , Kim , J. , Lee , S. S. , Park Lim , S. and Choe , C. R. 2001 . Effect of molecular weight between crosslinks on the fracture behavior of rubber-toughened epoxy adhesives . J. Appl. Polym. Sci. , 79 : 38 – 48 .
   Web of Science ®Google Scholar
• Yee , A. F. and Pearson , R. A. 1986 . Toughening mechanisms in elastomer-modified epoxies: Part 1: Mechanical properties . J. Mater. Sci. , 21 : 2462 – 2474 .
   Web of Science ®Google Scholar
• Broutman , L. J. and Panizza , G. 1971 . Micrmechnics studies of rubber reinforced glassy polymers . Int.J. Polym. Mater. , 1 : 95 – 109 .
   Google Scholar
• Guild , F. J. and Young , R. J. 1989 . A predictive model for particulate-filled composite materials: Part II: Hard particles . J. Mater. Sci. , 24 : 2454 – 2460 .
   Web of Science ®Google Scholar
• Bascom , W. D. , Cottington , R. L. , Jones , R. L. and Peyser , P. 1975 . The fracture of epoxy- and elastomer-modified epoxy polymers in bulk and as adhesives . J. Appl. Polym. Sci. , 19 : 2545 – 2562 .
   Web of Science ®Google Scholar
• Bucknall , C. B. and Yoshii , T. 1978 . Relationship between structure and mechanical properties in rubber-toughened epoxy reisns . Br. Polym. J. , 10 : 53 – 59 .
   Web of Science ®Google Scholar
• Ortiz , C. , McDonough , W. , Hunston , D. and Hoffman , D. 1994 . The effect of concentration and particle size on the fracture toughness of epoxies modified with dispersed acrylic elastomers . Proc. ACS: Polym. Mater. Sci. Eng. , 70 : 9
   Google Scholar
• Kim , H. S. and Ma , P. 1996 . Correlation between stress-whitening and fracture toughness in rubber-modified epoxies . J. Appl. Polym. Sci. , 61 : 659 – 662 .
   Web of Science ®Google Scholar
• Kim , H. S. and Ma , P. 1998 . Mode I and II fracture behavior of rubber-modified brittle epoxies . Key Eng. Mater. , 137 : 179 – 184 .
   Google Scholar
• Becu , L. , Maazouz , A. , Sautereau , H. and Gerard , J. F. 1997 . Fracture behavior of epoxy polymers modified with core-shell rubber particles . J. Appl. Polym. Sci. , 65 : 2419 – 2431 .
   Web of Science ®Google Scholar
• He , J. , Raghavan , D. , Hoffman , D. and Hunston , D. 1999 . The influence of elastomer concentration on toughness in dispersions containing preformed acrylic elastomeric particles in an epoxy matrix . Polymer , 40 : 1923 – 1933 .
   Web of Science ®Google Scholar
• Jansen , B. J. P. , Tamminga , K. Y. , Meijer , H. E. H. and Lemstra , P. J. 1999 . Preparation of thermoset rubbery epoxy particles as novel toughening modifiers for glassy epoxy resins . Polymer , 40 : 5601 – 5607 .
   Web of Science ®Google Scholar
• Chikhi , N. , Fellahi , S. and Bakar , M. 2002 . Modification of epoxy resin using reactive liquid (ATBN) rubber . Euro. Polym. J. , 38 : 251 – 264 .
   Web of Science ®Google Scholar
• Ramos , V. D. , Costa , H. M. , Soares , V. L. P. and Nascimento , S. V. 2005 . Modification of epoxy resin: A comparison of different types of elastomer . Polym. Testing , 24 : 387 – 394 .
   Web of Science ®Google Scholar
• Oldak , R. K. , Hydro , R. M. and Pearson , R. A. 2007 . “On the use of three block copolymers as toughening agents for epoxies,” . 30th Annual Meeting of the Adhesion Society . Feb. 18–21 2007 , Tampa, FL. pp. 153 – 155 .
   Google Scholar
• Pearson , R. A. , Bacigalupo , L. N. , Liang , Y. L. , Marouf , B. T. and Oldak , R. K. 2008 . “Plastic zone size- Fracture toughness correlations in rubber-modified epoxies,” . 31st Annual Meeting of the Adhesion Society . Feb. 17–20 2008 , Austin, Texas. pp. 27 – 29 .
   Google Scholar
• Sultan , J. N. and McGarry , F. J. 1973 . Effect of rubber particle size on deformation mechanisms in glassy epoxy . Polym. Eng. Sci. , 13 : 29 – 34 .
   Web of Science ®Google Scholar
• Day , R. J. , Lovell , P. A. and Pierre , D. 1997 . Toughening of epoxy resins using particles prepared by emulsion polymerization: effects of particle surface functionality, size and morphology on impact fracture properties . Polym. Inter. , 44 : 288 – 299 .
   Web of Science ®Google Scholar
• Kim , J. W. , Kim , J. Y. and Suh , K. D. 1997 . Preparation and physical properties of rubber-modified epoxy resin using poly(urethane acrylate)/poly(glycidyl methacrylate-co-acrylonitrile) core-shell composite particles . J. Appl. Polym. Sci. , 63 : 1589 – 1600 .
   Web of Science ®Google Scholar
• Becu-Longuet , L. , Bonnet , A. , Pichot , C. , Sautereau , H. and Maazouz , A. 1999 . Epoxy networks toughened by core-Shell particles: Influence of the particle structure and size on the rheological and mechanical properties . J. Appl. Polym. Sci. , 72 : 849 – 858 .
   Web of Science ®Google Scholar
• Bagheri , R. and Pearson , R. A. 1996 . Role of particle cavitation in rubber-toughened epoxies: I. Microvoid toughening . Polymer , 37 : 4529 – 4538 .
   Web of Science ®Google Scholar
• Hillmyer , M. A. , Lipic , P. M. , Hajduk , D. , Almmdal , K. and Bates , F. S. 1997 . Self-assembly and polymerization of epoxy resin-amphiphilic block copolymer nanocomposites . J. Am. Chem. Soc. , 119 : 2749 – 2750 .
   Web of Science ®Google Scholar
• Lipic , P. M. , Bates , F. S. and Hilmyer , M. A. 1998 . Nanostructured thermosets from self-assembled amphiphilic block copolymer/epoxy resin mixtures . J. Am. Chem. Soc. , 120 : 8963 – 8970 .
   Web of Science ®Google Scholar
• Grubbs , R. B. , Broz , M. E. , Dean , J. M. and Bates , F. S. 2000 . Selectively epoxidized polyisoprene-polybutadiene block copolymers . Macromolecules , 33 : 2308 – 2310 .
   Web of Science ®Google Scholar
• Grubbs , R. B. , Broz , M. E. , Dean , J. M. and Bates , F. S. 2000 . Reactive block copolymers for modification of thermosetting epoxy . Macromolecules , 33 : 9522 – 9534 .
   Web of Science ®Google Scholar
• Grubbs , R. B. , Dean , J. M. , Dean , J. M. and Bates , F. S. 2001 . Methacrylic block copolymers through metal-mediated living free radical polymerization for modification of thermosetting epoxy . Macromolecules , 34 : 8593 – 8595 .
   Web of Science ®Google Scholar
• Guo , Q. , Dean , J. M. , Grubbs , R. B. and Bates , F. S. 2003 . Block copolymer modified novalec epoxy resin . J. Polym. Sci.: Part B: Polym. Phys. , 41 : 1994 – 2003 .
   Web of Science ®Google Scholar
• Sumeet , J. and Bates , F. S. 2003 . On the origins of morphological complexity in block copolymer surfactant . Science , 300 : 460 – 464 .
   PubMed Web of Science ®Google Scholar
• Fröhlich , J. , Kautz , H. , Thomann , R. , Frey , H. and Mülhaupt , R. 2004 . Reactive core/shell type hyperbranched block copolyethers as new liquid rubbers for epoxy toughening . Polymer , 45 : 2155 – 2164 .
   Web of Science ®Google Scholar
• Liu , J. , Sue , H. J. , Thompson , Z. J. , Bates , F. S. , Dettloff , M. , Jacob , G. , Verghese , N. and Pham , H. 2008 . Nanocavitation in self-assembled amphiphilic block copolymer-modified epoxy . Macromolecules , 41 : 7616 – 7624 .
   Web of Science ®Google Scholar
• Wu , J. , Thio , Y. S. and Bates , F. S. 2005 . Structure and properties of PBO-PEO diblock copolymer modified epoxy . J. Polym. Sci.: Part B: Polym. Phys. , 43 : 1950 – 1965 .
   Web of Science ®Google Scholar
• Hydro , R. and Pearson , R. A. 2007 . Epoxies toughened with triblock copolymers . J. Polym. Sci., Part B: Polym. Phys. , 45 : 1470 – 1481 .
   Web of Science ®Google Scholar
• Wrotecki , C. , Heim , P. and Gaillard , P. 1991 . Rubber toughening of poly(methyl methacrylate): Part II: Effect of a twin population of particle size . Polym. Eng. Sci. , 31 : 218 – 222 .
   Web of Science ®Google Scholar
• Riew , C. K. , Rowe , E. H. and Siebert , A. R. 1976 . “Rubber toughened thermosets” . In Toughness and Brittleness of Plastics , Advances in Chemistry Series 154 Edited by: Deanin , R. D. and Crugnola , A. M. 326 Washington : ACS .
   Google Scholar
• Bascom , W. D. , Ting , R. Y. , Moulton , R. J. , Riew , C. K. and Siebert , A. R. 1981 . The fracture of an epoxy polymer containing elastomeric modifiers . J. Mater. Sci. , 16 : 2657 – 2664 .
   Web of Science ®Google Scholar
• Chen , T. K. and Jan , Y. H. 1992 . Fracture mechanism of toughened epoxy resin with bimodal rubber-particle size distribution . 27 : 111 – 121 .
   Google Scholar
• Evans , A. G. , Ahmad , Z. B. , Gilbert , D. G. and Beaumont , P. W. R. 1986 . Mechanisms of toughening in rubber toughened polymers . Acta Metall. , 34 : 79 – 87 .
   Google Scholar
• Azimi , H. R. , Pearson , R. A. and Hertzberg , R. W. 1996 . Fatigue of rubber-modified epoxies: effect of particle size and volume fraction . J. Mater. Sci. , 31 : 3777 – 3789 .
   Web of Science ®Google Scholar
• Bagheri , R. , Williams , M. A. and Pearson , R. A. 1997 . Use of surface modified recycled rubber particles for toughening of epoxy polymers . Polym. Eng. Sci. , 37 : 245 – 251 .
   Web of Science ®Google Scholar
• Margolina , A. and Wu , S. 1988 . Percolation model for brittle-tough transition in nylon-rubber blends . Polymer , 29 : 2170 – 2173 .
   Web of Science ®Google Scholar
• Sjoerdsma , S. D. 1989 . The tough-brittle transition in rubber-modified polymers . Polym. Commun. , 30 : 106 – 108 .
   Web of Science ®Google Scholar
• Verchere , D. , Pascault , J. P. , Sautereau , H. , Moschiar , S. M. , Riccardi , C. C. and Williams , R. J. J. 1991 . Rubber-modified epoxies: IV. Influence of morphology on mechanical properties . J. Appl. Polym. Sci. , 43 : 293 – 304 .
   Web of Science ®Google Scholar
• Van der Sanden , M. C. M. , Meijer , H. E. H. and Lemstra , P. J. 1993 . Deformation and toughness of polymeric systems: II. Influence of entanglement density . Polymer , 34 : 2148 – 2154 .
   Web of Science ®Google Scholar
• Michler , G. H. 1993 . Relations between molecular structure, morphology, and mechanical properties of heterogeneous polymer systems . Polym. Sci. , 35 : 1559 – 1568 .
   Google Scholar
• Van der Sanden , M. C. M. 1993 . PhD Dissertation University of Technology Eindhoven Netherlands .
   Google Scholar
• Bagheri , R. and Pearson , R. A. 2000 . Role of particle cavitation in rubber-toughened epoxies: 2. Inter-particle distance . Polymer , 41 : 269 – 276 .
   Web of Science ®Google Scholar
• Sue , H. J. , Garcia-Meitin , E. I. , Pickelman , D. M. and Yang , P. C. 1993 . “Optimization of mode-I fracture toughness of high-performance epoxies by using designed core-shell rubber particles,” . In Toughened Plastics , Advances in Chemistry Series 233 Edited by: Riew , C. K. and Kinloch , A. J. 259 – 292 . Washington : ACS .
   Google Scholar
• Yamanaka , K. , Takagi , Y. and Inoue , T. 1989 . Reaction-induce phase separation in rubber-modified epoxy resin . Polymer , 60 : 1839 – 1844 .
   Web of Science ®Google Scholar
• Huang , I. C. 1994 . “Effects of material properties and particle morphology on toughening of plastics,” , PhD Dissertation Ann Arbor, Michigan : University of Michigan .
   Google Scholar
• Bagheri , R. and Pearson , R. A. 1996 . Role of blend morphology in rubber-toughened polymers . J. Mater. Sci. , 31 : 3945 – 3954 .
   Web of Science ®Google Scholar
• Marouf , B. T. , Pearson , R. A. and Bagheri , R. 2009 . Anomalous fracture behavior in an epoxy-based hybrid composite . Mater. Sci. Eng. A , 515 : 49 – 58 .
   Web of Science ®Google Scholar
• Becu , L. , Taha , M. , Maazouz , A. and Merle , G. J. 2002 . Dispersion state and mechanical properties of core-shell particle modified epoxy network . Mater. Sci. , 37 : 41 – 49 .
   Google Scholar
• Marieta , C. , Remiro , P. M. , Garmendia , G. , Harismendy , I. and Mondragon , I. 2003 . AFM approach toward understanding morphologies in toughened thermosetting matrices,“ . Euro. Polym. J. , 39 : 1965 – 1973 .
   Web of Science ®Google Scholar
• Bucknall , C. B. , Heather , P. S. and Lazzari , A. 1989 . Rubber toughening of plastics . J. Mater. Sci. , 24 : 2255 – 2261 .
   Web of Science ®Google Scholar
• Yee , A. F. , Li , D. and Li , X. 1993 . The importance of constraint relief caused by rubber cavitation in the toughening of epoxy . 28 : 6392 – 6398 .
   Google Scholar
• Li , D. , Yee , A. F. , Chen , I. W. , Chang , S. C. and Takahashi , K. 1994 . Fracture behavior of unmodified and rubber-modified epoxies under hydrostatic pressure . 29 : 2205 – 2215 .
   Google Scholar
• Lazzeri , A. and Bucknall , C. B. 1993 . Dilatational bands in rubber-toughened polymers . ibid , 28 : 6799 – 6808 .
   Google Scholar
• Bucknall , C. B. , Karpondis , A. and Zhang , X. C. 1994 . A model for particle cavitation in rubber-tougheend plastics . 29 : 3377 – 3383 .
   Google Scholar
• Dijkstra , K. , Van der Wal , A. and Gaymans , R. J. 1994 . Nylon 6/rubber blends . 29 : 3489 – 3496 .
   Google Scholar
• Huang , Y. and Kinloch , A. J. 1992 . Modelling of the mechanisms in rubber-modified epoxy polymers” . J. Mater. Sci. , 27 : 2763 – 2769 .
   Web of Science ®Google Scholar
• Huang , Y. and Kinloch , A. J. 1992 . The sequence of initiation of the toughening micromechanisms in rubber-modified epoxy polymers . Polymer , 33 : 5338 – 5340 .
   Web of Science ®Google Scholar
• Argon , A. S. 1989 . “Sources of toughness in polymers,” . In Advances in Fracture Research , Edited by: Salama , K. , Ravi-Chandar , K. , Taplin , D. M. R. and Rama Rao , P. 2661 – 2881 . Oxford : Pergamon Press .
   Google Scholar
• Huang , Y. and Kinloch , A. J. 1992 . The toughness of the epoxy polymers containing microvoids . Polymer , 33 : 1330 – 1332 .
   Web of Science ®Google Scholar
• Guild , F. J. and Kinloch , A. J. 1995 . Predictive modeling of the mechanical properties of rubber-toughened epoxy . J. Mater. Sci. , 30 : 1689 – 1697 .
   Web of Science ®Google Scholar
• Sue , H. J. and Yee , A. F. 1996 . Micromechanical modeling of crack-tip rubber particle cavitational process in polymer toughening . Polym. Eng. Sci. , 36 : 2320 – 2326 .
   Web of Science ®Google Scholar
• Lu , F. , Cantwell , W. J. and Kausch , H. H. 1997 . The role of cavitation and debonding in the toughening of core-shell rubber modified epoxy systems . J. Mater. Sci. , 32 : 3055 – 3059 .
   Web of Science ®Google Scholar
• Du , J. , Thouless , M. D. and Yee , A. F. 1998 . Development of a process zone in rubber-modified epoxy polymers . Inter. J. Fracture , 92 : 271 – 286 .
   Web of Science ®Google Scholar
• Chen , X. H. and Mai , Y. W. 1998 . The effects of triaxial constraint on toughening mechanisms of rubber-modified epoxy system . Key Eng. Mater. , 137 : 115 – 122 .
   Google Scholar
• Chen , X. H. and Mai , Y. W. 1998 . Micromechanics of rubber-toughened polymers . J. Mater. Sci. , 33 : 3529 – 3539 .
   Web of Science ®Google Scholar
• Jeong , H. Y. 2000 . Void nucleation models and their implications for the material behavior of rubber-modified epoxies . Key Eng. Mater. , 183–187 : 1195 – 1200 .
   Google Scholar
• Jeong , H. Y. and Pan , J. 1996 . Crack-tip fields for porous solids with pressure-sensitive matrices and for rubber-modified epoxies . Polym. Eng. Sci. , 36 : 2306 – 2319 .
   Web of Science ®Google Scholar
• Bagheri , R. and Pearson , R. A. 1995 . The use of microvoids to toughen polymers” . Polymer , 36 : 4883 – 4885 .
   Web of Science ®Google Scholar
• Mafi , E. R. and Ebrahimi , M. 2008 . Role of core-shell rubber particle cavitation resistance on toughenability of epoxy resins . Polym. Eng. Sci. , 48 : 1376 – 1380 .
   Web of Science ®Google Scholar
• Chan , L. , Gillham , J. K. , Kinloch , A. J. and Shaw , S. J. 1984 . “Rubber-modified epoxies: Morphology, transitions and mechanical properties,” . In Advances in Chemistry Series 208 Riew , Edited by: Gillham , C. K. and Gillham , J. K. 261 – 279 . Washington : ACS .
   Google Scholar
• Huang , Y. , Kinloch , A. J. , Bertsch , R. and Sibert , A. R. 1993 . “Particle-matrix interfacial bonding,” . In Toughened Plastics , Advances in Chemistry Series 233 Edited by: Riew , C. K. and Kinloch , A. J. 189 – 210 . Washington : ACS .
   Google Scholar
• Qian , J. Y. , Pearson , R. A. , Dimonie , V. L. , Shaffer , O. L. and El-Asser , M. S. 1997 . The role of dispersed phase morphology on toughening of epoxies . Polymer , 38 : 21 – 30 .
   Web of Science ®Google Scholar
• Qian , J. Y. , Pearson , R. A. , Dimonie , V. L. and El-Asser , M. S. 1995 . Synthesis and application of core-shell particles as toughening agents for epoxies . J. Appl. Polym. Sci. , 58 : 439 – 448 .
   Web of Science ®Google Scholar
• Shaffer , O. L. , Bagheri , R. , Qian , J. Y. , Dimonie , V. , Pearson , R. A. and El-Asser , M. S. 1995 . Characterization of the particle-matrix interface in rubber-modified epoxy by atomic force microscopy . J. Appl. Polym. Sci. , 58 : 465 – 484 .
   Web of Science ®Google Scholar
• Russell , B. and Chartoff , R. 2005 . The influence of cure conditions on the morphology and phase distribution in a rubber-modified epoxy resin using scanning electron microscopy and atomic force microscopy . Polymer , 46 : 785 – 798 .
   Web of Science ®Google Scholar
• Matonis , V. A. and Small , N. C. 1969 . A macroscopic analysis of composites containing layered spherical inclusions . Polym. Eng. Sci. , 9 : 90 – 99 .
   Web of Science ®Google Scholar
• Matonis , V. A. 1969 . The interfacial stresses in particulate composite systems . 9 : 100 – 104 .
   Google Scholar
• Chen , T. K. and Jan , T. H. 1991 . Effect of rubber/matrix interfacial modifications on the properties of a rubber-toughened epoxy resin . 31 : 577 – 588 .
   Google Scholar
• Chen , T. K. and Jan , T. H. 1991 . Toughening mechanism for a rubber-toughened epoxy resin with rubber/matrix interfacial modification . J. Mater. Sci. , 26 : 5848 – 5858 .
   Web of Science ®Google Scholar
• Bagheri , R. and Pearson , R. A. 1995 . Interfacial studies in CTBN-modified epoxies . J. Appl. Polym. Sci. , 58 : 427 – 437 .
   Web of Science ®Google Scholar