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On the Critical Role of RAFT Agent Design in Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization

Pages 163-187 | Received 19 Jan 2011, Accepted 22 Feb 2011, Published online: 29 Apr 2011

References

  • Georges , M. K. , Veregin , R. P. N. , Kazmaier , P. M. and Hamer , G. K. 1993 . “Narrow molecular weight resins by a free-radical polymerization process,” . Macromolecules , 26 : 2987 – 2988 .
  • Jenkins , D. , Jones , R. G. and Moad , G. 2010 . “Terminology for reversible-deactivation radical polymerization previously called “controlled” or “living” radical polymerization,” . Pure Appl. Chem. , 82 : 483 – 491 .
  • Tatemoto , M. and Morita , S. 1982 . Liquid fluorine-containing polymer and its production with iodinated compound . US Patent 4,361,678
  • Otsu , T. and Yoshida , M. 1982 . “Role of initiator-transfer agent-terminator (iniferter) in radical polymerizations: Polymer design by organic disulfides as iniferters,” . Makromol Chem. Rapid Commun. , 3 : 127 – 135 .
  • Chiefari , J. , Chong , Y. K. , Ercole , F. , Krstina , J. , Jeffery , J. , Le , T. P. , Tam , P. T. , Mayadunne , Roshan , T. A. , Meijs , G. F. , Moad , C. L. , Moad , G. , Rizzardo , E. and Thang , S. H. 1998 . “Living free-radical polymerization by reversible addition-fragmentation chain transfer: the RAFT process,” . Macromolecules , 31 : 5559 – 5562 .
  • Le , T. P. , Moad , G. , Rizzardo , E. and Thang , S. H. 1998 . “Polymerization with living characteristics” . Int. Pat. , : 9801478
  • Corpart , P. , Charmot , D. , Biadatti , T. , Zard , S. Z. and Michelet , D. Method for block copolymer synthesis by controlled radical polymerization . WO 9858974 1998
  • Lowe , A. B. and McCormick , C. L. 2007 . “Reversible addition–fragmentation chain transfer (RAFT) radical polymerization and the synthesis of water-soluble (co)polymers under homogeneous conditions in organic and aqueous media” . Prog. Polym. Sci. , 32 : 283 – 351 .
  • Stenzel , M. H. 2008 . “Complex architecture design via the RAFT process: scope, strengths and limitations” . In Handbook of RAFT Polymerization , Edited by: Barner-Kowollik , C . 315 – 372 . Weinheim : Wiley-VCH . chap. 9
  • Boyer , C. , Stenzel , M. H. and Davis , T. P. 2011 . “Building nanostructures using RAFT polymerization” . J. Polym. Sci., Part A: Polym. Chem. , 49 : 551 – 595 .
  • Monteiro , M. , Adamy , M. , Leeuwen , B. J. , Van Herk , A. M. and Destarac , M. 2005 . “A “living” radical ab initio emulsion polymerization of styrene using a fluorinated transfer agent” . Macromolecules , 38 : 1538 – 1541 .
  • Ferguson , C. J. , Hughes , R. J. , Pham , B. T. T. , Hawkett , B. S. , Gilbert , R. G. , Serelis , A. K. and Such , C. H. 2002 . “Effective ab Initio Emulsion polymerization under RAFT control” . Macromolecules , 35 : 9243 – 9245 .
  • Inglis , A. J. , Sinnwell , S. , Stenzel , M. H. and Barner-Kowollik , C. 2009 . “Ultrafast click conjugation of macromolecular building blocks at ambient temperature” . Angew. Chem. Int. Ed. , 48 : 2411 – 2414 .
  • Koo , S. P. S. , Stamenović , M. M. , Prasath , R. A. , Inglis , A. J. , Du Prez , F. E. , Barner-Kowollik , C. , Van Camp , W. and Junkers , T. 2010 . “Limitations of radical thiol-ene reactions for polymer-polymer conjugation” . J. Polym. Sci., Part A: Polym. Chem. , 48 : 1699 – 1713 .
  • Perrier , S. and Takolpuckdee , P. 2005 . “Macromolecular design via reversible addition fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization” . J. Polym. Sci., Part A: Polym. Chem. , 43 : 5347 – 5393 .
  • Moad , G. , Rizzardo , E. and Thang , S. H. 2005 . “Living radical polymerization by the RAFT process” . Aust. J. Chem. , 58 : 379 – 410 .
  • Moad , G. , Rizzardo , E. and Thang , S. H. 2006 . “Living radical polymerization by the RAFT process—A first update” . Aust. J. Chem. , 59 : 669 – 692 .
  • Moad , G. , Rizzardo , E. and Thang , S. H. 2009 . “Living radical polymerization by the RAFT process—A second update” . Aust. J. Chem. , 62 : 1402 – 1472 .
  • Barner-Kowolik , C. 2008 . “ Handbook of RAFT Polymerization ” . Edited by: Barner-Kowollik , C. Weinheim, Germany : Wiley-VCH . ISBN 978-3-527-31924-4
  • Barner-Kowollik , C. and Perrier , S. 2008 . “The future of reversible addition fragmentation chain transfer polymerization” . J. Polym. Sci., Part A: Polym. Chem. , 46 : 5715 – 5723 .
  • Zard , S. Z. 2006 . “The genesis of the reversible radical addition-fragmentation-transfer of thiocarbonylthio derivatives from the Barton—McCombie deoxygenation: a brief account and some mechanistic observations” . Aust. J. Chem. , 59 : 663 – 668 . and references cited therein
  • Colombani , D. and Chaumont , P. 1996 . “Addition-fragmentation processes in free radical polymerization” . Prog. Polym. Sci. , 21 : 439 – 503 .
  • Krstina , J. , Moad , G. , Rizzardo , E. , Winzor , C. L. , Berge , C. T. and Fryd , M. 1995 . “Narrow polydispersity block copolymers by free-radical polymerization in the presence of macromonomers” . Macromolecules , 28 : 5381 – 5385 .
  • Geagea , R. , Stefak , R. , Mazières , S. and Destarac , M. 2008 . “RAFT polymerization mediated by an organometallic thiocarbony thio transfer agent” . Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) , 49 ( 2 ) : 250 – 251 .
  • Geagea , R. , Ladeira , S. , Mazières , M. and Destarac , M. 2011 . “Chromium and molybdenum pentacarbonyl complexes of phosphinocarbodithioates: synthesis, molecular structure and behaviour in RAFT polymerisation” . Chem. Eur. J. , 17, 3718–3725.
  • Feldermann , A. , Coote , M. L. , Stenzel , M. H. , Davis , T. P. and Barner-Kowollik , C. 2004 . “Consistent experimental and theoretical evidence for long-lived intermediate radicals in living free radical polymerization” . J. Am. Chem. Soc. , 126 : 15915 – 15923 .
  • Pound , G. , McLeary , J. B. , McKenzie , J. M. , Lange , R. F. M. and Klumperman , B. 2006 . “In-situ NMR spectroscopy for probing the efficiency of RAFT/MADIX agents” . Macromolecules , 39 : 7796 – 7797 .
  • Coote , M. L. , Izgorodina , E. I. , Krenske , E. H. , Busch , M. and Barner-Kowollik , C. 2006 . “Quantum chemical mapping of initialization processes in RAFT polymerization” . Macromol. Rapid Commun. , 27 : 1015 – 1022 .
  • Barner-Kowollik , C. , Buback , M. , Charleux , B. , Coote , M. L. , Drache , M. , Fukuda , T. , Goto , A. , Klumperman , B. , Lowe , A. B. , McLeary , J. B. , Moad , G. , Monteiro , M. J. , Sanderson , R. D. , Tonge , M. P. and Vana , P. 2006 . “Mechanism and kinetics of dithiobenzoate-mediated RAFT polymerization. I. The current situation” . J. Polym. Sci.-Part A: Polym. Chem. , : 5809 – 5831 .
  • Chernikova , E. , Golubev , V. , Filippov , A. , Lin , C. Y. and Coote , M. L. 2010 . “Use of spin traps to measure the addition and fragmentation rate coefficients of small molecule RAFT-adduct radicals” . Polym. Chem. , 1 : 1437 – 1440 .
  • Geleen , P. and Klumperman , B. 2007 . “Intermediate radical termination in reversible addition-fragmentation chain transfer-mediated polymerization: Identification of termination products” . Macromolecules , 40 : 3914 – 3920 .
  • Ah Toy , A. , Vana , P. , Davis , T. P. and Barner-Kowollik , C. 2004 . “Reversible addition fragmentation chain transfer (RAFT) polymerization of methyl acrylate: detailed structural investigation via coupled size exclusion chromatography−electrospray ionization mass spectrometry (SEC−ESI-MS)” . Macromolecules , 37 : 744 – 751 .
  • Feldermann , A. , Ah Toy , A. , Davis , T. P. , Stenzel , M. H. and Barner-Kowollik , C. 2005 . “An in-depth analytical approach to the mechanism of the RAFT process in acrylate free radical polymerizations via coupled size exclusion chromatography-electrospray ionization mass spectrometry (SEC-ESI-MS)” . Polymer , 46 : 8448 – 8457 .
  • Brown , S. L. , Konkolewicz , D. , Gray-Weale , A. , Motherwell , W. B. and Perrier , S. 2009 . “Searching for stars: selective desulfurization and fluorescence spectroscopy as new tools in the search for cross-termination side-products in reversible addition fragmentation chain transfer (RAFT)” . Aust. J. Chem. , 62 : 1533 – 1536 .
  • Konkolewicz , D. , Hawkett , B. S. , Gray-Weale , A. and Perrier , S. 2008 . “RAFT polymerization kinetics: combination of apparently conflicting models” . Macromolecules , 41 : 6400 – 6412 .
  • Konkolewicz , D. , Hawkett , B. S. , Gray-Weale , A. and Perrier , S. 2009 . “RAFT polymerization kinetics: how long are the cross-terminating oligomers?” . J. Polym. Sci., Part A: Polym. Chem. , 47 : 3455 – 3466 .
  • Chong , Y. K. , Krstina , J. , Le , T. P. T. , Moad , G. , Postma , A. , Rizzardo , E. and Thang , S. H. 2003 . “Thiocarbonylthio compounds [S:C(Ph)S-R] in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization). role of the free-radical leaving group (R)” . Macromolecules , 36 : 2256 – 2272 .
  • Müller , A. H. E. and Litvinenko , G. 1997 . “General kinetic analysis and comparison of molecular weight distributions for various mechanisms of activity exchange in living polymerizations” . Macromolecules , 30 : 1253 – 1266 .
  • Müller , A. H. E. , Yan , D. , Litvinenko , G. , Zhuang , R. and Dong , H. 1995 . “Kinetic analysis of living polymerization processes exhibiting slow equilibria. II: Molecular weight distribution for degenerative transfer (direct activity exchange between active and dormant species) at constant monomer concentration” . Macromolecules , 28 : 7335 – 7338 .
  • Goto , A. and Fukuda , T. 1997 . “Mechanism and kinetics of activation processes in a nitroxyl-mediated polymerization of styrene” . Macromolecules , 30 : 5183 – 5186 .
  • Kubo , K. , Goto , A. , Sato , K. , Kwak , Y. and Fukuda , T. 2005 . “Kinetic study on reversible addition-fragmentation chain transfer (RAFT) process for block and random copolymerizations of styrene and methyl methacrylate” . Polymer , 46 : 9762 – 9768 .
  • Gao , J. , Luo , Y. , Wang , R. , Zhang , X. , Li , B.-G. and Zhu , S. 2009 . “Effect of monomer composition on apparent chain transfer coefficient in reversible addition fragmentation transfer (RAFT) copolymerization” . Polymer , 50 : 802 – 809 .
  • Chernikova , E. V. , Tarasenko , A. V. , Garina , E. S. and Golubev , V. B. 2008 . “Free-radical polymerization of methyl methacrylate in the presence of dithiobenzoates as reversible addition-fragmentation chain transfer agents” . Vysokomol. Soedin., Ser. A Ser. B , 50 : 565 – 578 .
  • Chiefari , J. , Mayadunne , R. T. A. , Moad , C. L. , Moad , G. , Rizzardo , E. , Postma , A. , Skidmore , M. A. and Thang , S. H. 2003 . “Thiocarbonylthio compounds (S:C(Z)S-R) in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization). effect of the activating group Z” . Macromolecules , 36 : 2273 – 2283 .
  • Chiefari , J. , Mayadunne , R. , Moad , G. , Rizzardo , E. and Thang , S. Polymerization process with living characteristics and polymers made therefrom . US Patent 6747111, 2004
  • Chernikova , E. , Morozov , A. , Leonova , E. , Garina , E. , Golubev , V. , Bui , C. and Charleux , B. 2004 . “Controlled free-radical polymerization of n-butyl acrylate by reversible addition-fragmentation chain transfer in the presence of tert-butyl dithiobenzoate. A kinetic study” . Macromolecules , 37 : 6329 – 6339 .
  • Konkolewicz , D. , Siauw , M. , Gray-Weale , A. , Hawkett , B. S. and Perrier , S. 2009 . “Obtaining Kinetic Information from the Chain-Length Distribution of Polymers Produced by RAFT” . J. Phys. Chem. B , 113 : 7086 – 7094 .
  • Chernikova , E. V. , Terpugova , P. S. , Garina , E. S. and Golubev , V. B. 2007 . “Controlled radical polymerization of styrene and n-butyl acrylate mediated by trithiocarbonates” . Vysokomol. Soedin., Ser. A Ser. B , 49 : 208 – 221 .
  • Junkers , T. , Theis , A. , Buback , M. , Davis , T. P. , Stenzel , M. H. , Vana , P. and Barner-Kowollik , C. 2005 . “Chain length dependentt in butyl acrylate free–radical polymerization studied via stationary and pulsed laser initiated RAFT polymerization” . Macromolecules , 38 : 9497 – 9508 .
  • Buback , M. , Hesse , P. , Junkers , T. and Vana , P. 2006 . “Determination of addition and fragmentation rate coefficients in RAFT polymerization via timeresolved ESR spectroscopy after laser pulse initiation” . Macromol. Rapid Commun. , 27 : 182 – 187 .
  • Smulders , W. W. 2002 . Macromolecular architecture in aqueous dispersions. ‘Living’ free-radical polymerization in emulsion, PhD Dissertation , Eindhoven, Netherlands : Technische Universiteit Eindhoven .
  • Jacquin , M. , Muller , P. , Lizarraga , G. , Bauer , C. , Cottet , H. and Theodoly , O. 2007 . “Characterization of amphiphilic diblock copolymers synthesized by MADIX polymerization process” . Macromolecules , 40 : 2672 – 2682 .
  • Chernikova , E. V. , Tarasenko , A. V. , Garina , E. S. and Golubev , V. B. 2006 . “Controlled radical polymerization of styrene mediated by dithiobenzoates as reversible addition -fragmentation chain-transfer agents” . Vysokomol. Soedin., Ser. A Ser. B , 48 : 1787 – 1800 .
  • Barner-Kowollik , C. , Quinn , J. F. , Morsley , D. R. and Davis , T. P. 2001 . “Modelling the reversible addition fragmentation chain transfer (RAFT) process in cumyl dithiobenzoate mediated styrene homopolymerizations: assessing rate coefficients for the addition fragmentation equilibrium” . J. Polym. Sci., Part A: Polym. Chem. , 39 : 1353 – 1365 .
  • Bicciocchi , E. , Chong , Y. K. , Giorgini , L. , Moad , G. , Rizzardo , E. and Thang , S. H. 2010 . “Substituent effects on RAFT polymerization with benzyl aryl trithiocarbonates” . Macromol. Chem. Phys. , 211 : 529 – 538 .
  • Ran , R. , Chen , Z. and Wang , X. L. 2009 . “Substituent effects on trithiocarbonates-mediated polymerization of styrene” . J. Appl. Polym. Sci. , 111 : 2011 – 2017 .
  • Postma , A. , Davis , T. P. , Evans , R. A. , Li , G. , Moad , G. and O’Shea , M. S. 2006 . “Synthesis of well-defined polystyrene with primary amine end groups through the use of phthalimido-functional RAFT agents” . Macromolecules , 39 : 5293 – 5306 .
  • Postma , A. , Davis , T. P. , Li , G. , Moad , G. and O’Shea , M. S. 2006 . “RAFT polymerization with phthalimidomethyl trithiocarbonates or xanthates. On the origin of bimodal molecular weight distributions in living radical polymerization” . Macromolecules , 39 : 5307 – 5318 .
  • Altarawneh , I. S. , Gomes , V. G. and Srour , M. S. 2008 . “The influence of xanthate-based transfer agents on styrene emulsion polymerization : mathematical modeling and model validation” . Macromol. React. Eng. , 2 : 58 – 79 .
  • Adamy , M. , van Herk , A. M. , Destarac , M. and Monteiro , M. J. 2003 . “Influence of the chemical structure of MADIX agents on the RAFT polymerization of styrene” . Macromolecules , 36 : 2293 – 2301 .
  • Theis , A. , Davis , T. P. , Stenzel , M. H. and Barner-Kowollik , C. 2006 . “Probing the reaction kinetics of vinyl acetate free radical polymerization via living free radical polymerization (MADIX)” . Polymer , 47 : 999 – 1010 .
  • Altarawneh , I. S. , Srour , M. and Gomes , V. G. 2007 . “RAFT with bulk and solution polymerization : an approach to mathematical modelling and validation” . Polym.-Plast. Technol. Eng. , 46 : 1103 – 1115 .
  • Theis , A. , Feldermann , A. , Charton , N. , Stenzel , M. H. , Davis , T. P. and Barner-Kowollik , C. 2005 . “Access to chain length dependent termination rate coefficients of methyl acrylate via reversible addition fragmentation chain transfer (RAFT) polymerization” . Macromolecules , 38 : 2595 – 2605 .
  • Theis , A. , Feldermann , A. , Charton , N. , Davis , T. P. , Stenzel , M. H. and Barner-Kowollik , C. 2005 . “Living free radical polymerization (RAFT) of dodecyl acrylate: chain length dependent termination, mid-chain radicals and monomer reaction order” . Polymer , 46 : 6797 – 6809 .
  • Han , X. , Fan , J. , He , J. , Xu , J. , Fan , D. and Yang , Y. 2007 . “Direct observation of the RAFT polymerization process by chromatography” . Macromolecules , 40 : 5618 – 5624 .
  • Drache , M. and Schmidt-Naake , G. 2008 . “Initialization of RAFT agents with different leaving groups—determination of the transfer coefficients” . Macromol. Symp. , 271 : 129 – 136 .
  • Drache , M. and Schmidt-Naake , G. 2007 . Macromol. Symp. , 259 : 397 – 405 .
  • Goto , A. , Sato , K. , Tsujii , Y. , Fukuda , T. , Moad , G. , Rizzardo , E. and Thang , S. H. 2001 . “Mechanism and kinetics of RAFT-based living radical polymerizations of styrene and methyl methacrylate” . Macromolecules , 34 : 402 – 408 .
  • Destarac , M. , Charmot , D. , Franck , X. and Zard , S. Z. 2000 . “Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents” . Macromol. Rapid Commun. , 21 : 1035 – 1039 .
  • Destarac , M. , Brochon , C. , Catala , J.-M. , Wilczewska , A. and Zard , S. Z. 2002 . “Macromolecular Design via the Interchange of Xanthates (MADIX): Polymerization of Styrene with O-Ethyl Xanthates as Controlling Agents” . Macromol. Chem. Phys. , 203 : 2281 – 2289 .
  • Destarac , M. , Bzducha , W. , Taton , D. , Gauthier-Gillaizeau , I. and Zard , S. Z. 2002 . “Xanthates as chain-transfer agents in controlled radical polymerization (MADIX): Structural effect of the O-alkyl group” . Macromol. Rapid. Commun. , 23 : 1049 – 1054 .
  • Destarac , M. , Taton , D. , Zard , S. Z. , Saleh , T. and Six , Y. 2003 . “On the Importance of Xanthate Substituents in the MADIX Process,” Advances in Controlled / Living Radical Polymerization, Matyjaszewski, K., Ed., ACS Symposium Series, vol 854 ” . 536 – 550 . American Chemical Society .
  • Destarac , M. , Gauthier-Gillaizeau , I. , Vuong , C.-T. and Zard , S. Z. 2006 . “Vinylogous thionothio compounds for RAFT Polymerization” . Macromolecules , 39 : 912 – 914 .
  • Doi , T. , Matsumoto , A. and Otsu , T. 1994 . “Radical polymerization of methyl acrylate by use of benzyl N, N-diethyldithiocarbamate in combination with tetraethylthiuram disulfide as a two-component iniferter” . J. Polym. Sci A: Polym. Chem. , 32 : 2911 – 2918 .
  • Mayadunne , R. T. A. , Rizzardo , E. , Chiefari , J. , Chong , Y. K. , Moad , G. and Thang , S. H. 1999 . “Living radical polymerization with reversible addition−fragmentation chain transfer (RAFT polymerization) using dithiocarbamates as chain transfer agents” . Macromolecules , 32 : 6977–6980
  • Alberti , A. , Benaglia , A. , Laus , M. , Macciantelli , D. and Sparnacci , K. 2003 . “Direct ESR detection of free radicals in the RAFT polymerization of styrene” . Macromolecules , 36 : 736 – 740 .
  • Laus , M. , Papa , R. , Sparnacci , K. , Alberti , A. , Benaglia , M. and Macciantelli , D. 2001 . “Controlled radical polymerization of styrene with phosphoryl- and (thiophosphoryl)dithioformates as RAFT agents” . Macromolecules , 34 : 7269 – 7275 .
  • Chen , C.-L. , Lo , Y.-H. , Lee , C.-Y. , Fong , Y.-H. , Shih , K.-C. and Huang , C.-C. 2010 . “Novel W(II) complexes for reversible addition-fragmentation chain transfer (RAFT) polymerizations” . Inorg. Chem. Commun. , 13 : 603 – 605 .
  • Benaglia , M. , Chiefari , J. , Chong , Y. K. , Moad , G. , Rizzardo , E. and Thang , S. H. 2009 . “Universal (switchable) RAFT agents” . J. Am. Chem. Soc. , 131 : 6914 – 6915 .
  • Benaglia , M. , Chen , M. , Chong , Y. K. , Moad , G. , Rizzardo , E. and Thang , S. H. 2009 . “Polystyrene-block-poly(vinyl acetate) through the use of a switchable RAFT Agent” . Macromolecules , 42 : 9384 – 9386 .
  • Coote , M. L. and Henry , D. J. 2005 . “Computer-aided design of a destabilized RAFT adduct radical: Toward improved RAFT agents for styrene-block-vinyl acetate copolymers” . Macromolecules , 38 : 5774 – 5779 .
  • Coote , M. L. , Izgorodina , E. I. , Cavigliasso , G. E. , Roth , M. , Busch , M. and Barner-Kowollik , C. 2006 . “Addition-fragmentation kinetics of fluorodithioformates (F-RAFT) in styrene, vinyl acetate and ethylene polymerization - an ab initio investigation” . Macromolecules , 39 : 4584 – 4591 .
  • Theis , A. , Stenzel , M. H. , Davis , T. P. , Coote , M. L. and Barner-Kowollik , C. 2005 . “A synthetic approach to a novel class of fluorine bearing reversible addition fragmentation chain transfer (RAFT) agents: F-RAFT” . Aust. J. Chem. , 58 : 437 – 441 .
  • Busch , M. , Roth , M. , Davis , T. P. , Stenzel , M. H. and Barner-Kowollik , C. 2007 . “The use of novel F-RAFT agents in high temperature and high pressure ethene polymerization: can control be achieved?” . Aust. J. Chem. , 60 : 788 – 793 .
  • Lin , C. Y. and Coote , M. L. 2009 . “How well can theory predict addition-fragmentation equilibrium constants in RAFT polymerization?” . Aust. J. Chem. , 62 ( 11 ) : 1479 – 1483 .
  • Krenzke , E. H. , Izgorodina , E. I. and Coote , M. L. 2006 . “An ab initio guide to structure-reactivity trends in reversible addition fragmentation chain transfer polymerization” . ACS Symp. Ser. , 944 (Controlled/Living Radical Polymerization), 406–420
  • Barner-Kowollik , C. , Coote , M. L. , Davis , T. P. , Radom , L. and Vana , P. 2003 . “The reversible addition–fragmentation chain transfer process and the strength and limitations of modeling: Comment on “the magnitude of the fragmentation rate coefficient” . J. Polym. Sci. Part A: Polym. Chem. , 41 ( 18 ) : 2828 – 2832 .
  • Coote , M. L. and Radom , L. 2003 . “Ab initio evidence for slow fragmentation in RAFT polymerization” . J. Am. Chem. Soc. , 125 ( 6 ) : 1490 – 1491 .
  • Coote , M. L. , Krenske , E. H. and Izgorodina . 2006 . “Computational studies of RAFT polymerization-mechanistic insights and practical applications” . Macromol. Rapid Commun. , 27 : 473 – 497 .
  • Coote , M. L. , Krenzke , E. H. and Izgorodina , E. I. 2008 . “Quantum-chemical studies of RAFT polymerization: methodology, structure-reactivity correlations and kinetic implications” . In Handbook of RAFT Polymerization , Edited by: Barner-Kowollik , C. 5 – 49 . Weinheim, , Germany : Wiley-VCH .

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