1,345
Views
20
CrossRef citations to date
0
Altmetric
Articles

An enzyme-catalysed access to amphiphilic triblock copolymer of PCL-b-PEG-b-PCL: synthesis, characterization and self-assembly properties

, &
Pages 799-806 | Received 15 Jun 2015, Accepted 28 Jul 2015, Published online: 21 Aug 2015

References

  • Woodruff MA, Hutmacher DW. The return of a forgotten polymer – polycaprolactone in the 21st century. Prog. Polym. Sci. 2010;35:1217–1256.10.1016/j.progpolymsci.2010.04.002
  • Dash TK, Konkimalla VB. Poly-є-caprolactone based formulations for drug delivery and tissue engineering: a review. J. Control Release 2012;158:15–33.10.1016/j.jconrel.2011.09.064
  • Tian H, Tang ZH, Zhuang XL, Chen XS, Jing XB. Biodegradable synthetic polymers: preparation, functionalization and biomedical application. Prog. Polym. Sci. 2012;37:237–280.10.1016/j.progpolymsci.2011.06.004
  • Du ZX, Xu JT, Fan ZQ. Micellar morphologies of poly(є-caprolactone)-b-poly(ethylene oxide) block copolymers in water with a crystalline core. Macromolecules. 2007;40:7633–7637.10.1021/ma070977p
  • Fairley N, Hoang B, Allen C. Morphological control of poly(ethylene glycol)-block-poly(ε-caprolactone) copolymer aggregates in aqueous solution. Biomacromolecules. 2008;9:2283–2291.10.1021/bm800572p
  • Yang JX, He WN, Xu JT, Du Fan ZQ. Influence of different inorganic salts on crystallization-driven morphological transformation of PCL-b-PEO micelles in aqueous solutions. Chin. J. Polym. Sci. 2014;32:1128–1138.10.1007/s10118-014-1512-z
  • Kukut M, Yilmaz OK, Yagcia Y. Synthesis, characterization, and hydrolytic degradation of graft copolymers of polystyrene and aliphatic polyesters. Des. Monomers Polym. 2013;16:233–240.10.1080/15685551.2012.725214
  • Ruan JM, Xiao AG, Wu HW, Yang HL. Review-recent development of ring-opening polymerization of cyclic esters using aluminum complexes. Des. Monomers Polym. 2014;17:345–355.
  • Zaks A, Klibanov AM. Enzymatic catalysis in organic media at 100 °C. Science. 1984;224:1249–1251.10.1126/science.6729453
  • Klibanov AM. Improving enzymes by using them in organic solvents. Nature. 2001;409:241–246.10.1038/35051719
  • Kobayshi S. Enzymatic polymerization: a new method of polymer synthesis. J. Polym. Sci. Part A: Polym. Chem. 1999;37:3041–3056.10.1002/(ISSN)1099-0518
  • Zhang JX, Shi H, Wu D, et al. Recent developments in lipase-catalyzed synthesis of polymeric materials. Process Biochem. 2014;49:797–806.10.1016/j.procbio.2014.02.006
  • Kalyanasundaram K, Thomas JK. Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems. J. Am. Chem. Soc. 1977;99:2039–2044.10.1021/ja00449a004
  • He CL, Sun JR, Zhao T, et al. Formation of a unique crystal morphology for the poly(ethylene glycol)-poly (ε-caprolactone) diblock copolymer. Biomacromolecules. 2006;7:252–258.10.1021/bm050627f
  • Zhu ZX, Xiong CD, Zhang LL, Deng XM. Synthesis and characterization of poly (e-caprolactone) poly(ethylene glycol) block copolymer. J. Polym. Sci. Part A: Polym. Chem. 1997;35:709–714.10.1002/(ISSN)1099-0518
  • Smith BER. Polymers: a property database. New York (NY): CRS Press; 2009.
  • He CL, Sun JR, Deng C, et al. Study of the synthesis, crystallization, and morphology of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers. Biomacromolecules. 2004;5:2042–2047.10.1021/bm049720e
  • Tang WT, Hadziioannou G, Smith BA, Frank CW. Facile method for labelling polystyrene with various fluorescent dyes. Polymer. 1988;29:1313–1317.10.1016/0032-3861(88)90062-6
  • Wilhelm M, Zhao CL, Wang YC, et al. Poly(styrene-ethylene oxide) block copolymer micelle formation in water: a fluorescence probe study. Macromolecules. 1991;24:1033–1040.10.1021/ma00005a010

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.