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Research Article

Laboratory study of H2SO4/H2O nucleation using a new technique – a laminar co-flow tube

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Pages 1-11 | Received 26 Jul 2017, Accepted 26 Feb 2018, Published online: 19 Mar 2018

References

  • Almeida, J., Schobesberger, S., Kürten, A., Ortega, I. K., Kupiainen-Määttä, O. and co-authors. 2013. Molecular understanding of sulphuric acid-amine particle nucleation in the atmosphere. Nature 502, 359–363.10.1038/nature12663
  • Ayers, G. P., Gillett, R. W. and Gras, J. L. 1980. On the vapor pressure of sulfuric acid. Geophys. Res. Lett. 7, 433–436.10.1029/GL007i006p00433
  • Ball, S. M., Hanson, D. R., Eisele, F. L. and McMurry, P. H. 1999. Laboratory studies of particle nucleation: Initial results for H2SO4, H2O, and NH3 vapors. J. Geophys. Res. Atmos. 104, 23709–23718.10.1029/1999JD900411
  • Benson, D. R., Erupe, M. E. and Lee, S. H. 2009. Laboratory-measured H2SO4–H2O–NH3 ternary homogeneous nucleation rates: initial observations. Geophys. Res. Lett. 36, 1–6.
  • Benson, D. R., Young, L.-H., Kameel, F. R. and Lee, S.-H. 2008. Laboratory-measured nucleation rates of sulfuric acid and water binary homogeneous nucleation from the SO2 + OH reaction. Geophys. Res. Lett. 35, 1–6.
  • Benson, D. R., Yu, J. H., Markovich, A. and Lee, S. H. 2011. Ternary homogeneous nucleation of H2SO4, NH3, and H2O under conditions relevant to the lower troposphere. Atmos. Chem. Phys. 11, 4755–4766.10.5194/acp-11-4755-2011
  • Berndt, T., Sipilä, M., Stratmann, F., Petäjä, T., Vanhanen, J. and co-authors. 2014. Enhancement of atmospheric H2SO4/H2O nucleation: organic oxidation products versus amines. Atmos. Chem. Phys. 14, 751–764.10.5194/acp-14-751-2014
  • Berndt, T., Stratmann, F., Sipilä, M., Vanhanen, J., Petäjä, T. and co-authors. 2010. Laboratory study on new particle formation from the reaction OH + SO2: influence of experimental conditions, H2O vapour, NH3 and the amine tert-butylamine on the overall process. Atmos. Chem. Phys. 10, 7101–7116.10.5194/acp-10-7101-2010
  • Brus, D., Hyvärinen, A. P., Viisanen, Y., Kulmala, M. and Lihavainen, H. 2010. Homogeneous nucleation of sulfuric acid and water mixture: experimental setup and first results. Atmos. Chem. Phys. 10, 2631–2641.10.5194/acp-10-2631-2010
  • Brus, D., Hyvarinen, A. P., Zdimal, V. and Lihavainen, H. 2005. Homogeneous nucleation rate measurements of 1-butanol in helium: a comparative study of a thermal diffusion cloud chamber and a laminar flow diffusion chamber. J. Chem. Phys 122, 1–14.
  • Brus, D., Neitola, K., Hyvärinen, A. P., Petäjä, T., Vanhanen, J. and co-authors. 2011. Homogenous nucleation of sulfuric acid and water at close to atmospherically relevant conditions. Atmos. Chem. Phys. 11, 5277–5287.10.5194/acp-11-5277-2011
  • Brus, D., Škrabalová, L., Herrmann, E., Olenius, T., Trávničková, T. and co-authors. 2017. Temperature-dependent diffusion of H2SO4 in air at atmospherically relevant conditions: laboratory measurements using laminar flow technique. Atmosphere 8, 1–15.
  • Duplissy, J., Merikanto, J., Franchin, A., Tsagkogeorgas, G., Kangasluoma, J. and co-authors. 2016. Effect of ions on sulfuric acid-water binary particle formation: 2. Experimental data and comparison with QC-normalized classical nucleation theory. J. Geophys. Res. Atmos. 121, 1752–1775.10.1002/2015JD023539
  • Gore, R. A. and Crowe, C. T. 1989. Effect of particle size on modulating turbulent intensity. Int. J. Multiph. Flow 15, 279–285.10.1016/0301-9322(89)90076-1
  • Herrmann, E., Brus, D., Hyvärinen, A. P., Stratmann, F., Wilck, M. and co-authors. 2010. A computational fluid dynamics approach to nucleation in the water-sulfuric acid system. J. Phys. Chem. A 114, 8033–8042.10.1021/jp103499q
  • Hinds, W. C. 1998. Aerosol technology: properties, behavior and measurement of airbone particles. John Wiley & sons, Inc., New York, NY.
  • Katz, J. L. and Ostermier, B. J. 1967. Diffusion cloud-chamber investigation of homogeneous nucleation. J. Chem. Phys. 47, 478.10.1063/1.1711920
  • Kerminen, V. M., Petäjä, T., Manninen, H. E., Paasonen, P., Nieminen, T. and co-authors. 2010. Atmospheric nucleation: highlights of the EUCAARI project and future directions. Atmos. Chem. Phys. 10, 10829–10848.10.5194/acp-10-10829-2010
  • Kirkby, J., Curtius, J., Almeida, J., Dunne, E., Duplissy, J. and co-authors. 2011. Role of sulphuric acid, ammonia and galactic cosmic rays in atmospheric aerosol nucleation. Nature 476, 429–433.10.1038/nature10343
  • Krejčí, P. 2010. Experimental study of homogeneous nucleation in the mixture of water and sulphuric acid vapours. Ph.D. doctoral thesis. Department, Czech Technical University in Prague, Prague.
  • Kulmala, M. 2003. How particles nucleate and grow. Science 302, 1000–1001.10.1126/science.1090848
  • Kulmala, M. and Laaksonen, A. 1990. Binary nucleation of water sulfuric-acid system – comparison of classical-theories with different H2SO4 saturation vapor-pressures. J. Chem. Phys. 93, 696–701.10.1063/1.459519
  • Lisle, E. S. and Sensenbaugh, J. D. 1965. The determination of sulfur trioxide and acid dew point in flue gases. Combustion 36, 12–16.
  • Merikanto, J., Napari, I., Vehkamaki, H., Anttila, T. and Kulmala, M. 2007. New parameterization of sulfuric acid-ammonia-water ternary nucleation rates at tropospheric conditions. J. Geophys. Res. Atmos. 112, 1–9.
  • Merikanto, J., Spracklen, D. V., Mann, G. W., Pickering, S. J. and Carslaw, K. S. 2009. Impact of nucleation on global CCN. Atmos. Chem. Phys. 9, 8601–8616.10.5194/acp-9-8601-2009
  • Neitola, K., Brus, D., Makkonen, U., Sipilä, M., Mauldin III, R. L. and co-authors. 2015. Total sulfate vs. sulfuric acid monomer concenterations in nucleation studies. Atmos. Chem. Phys. 15, 3429–3443.10.5194/acp-15-3429-2015
  • O’Connell J. P., Gillespie, M. D., Krostek, W. D. and Prausnitz, J. M.. 1969. Diffusivities of water in nonpolar gases. J. Phys. Chem. 73, 2000.10.1021/j100726a059
  • Peters, F. 1982. Homogeneous nucleation of ethanol and normal-propanol in a shock-tube. J. Chem. Phys. 77, 4788–4790.10.1063/1.444389
  • Riipinen, I., Sihto, S. L., Kulmala, M., Arnold, F., Dal Maso, M. and co-authors. 2007. Connections between atmospheric sulphuric acid and new particle formation during QUEST III-IV campaigns in Heidelberg and Hyyti. Atmos. Chem. Phys. 7, 1899–1914.10.5194/acp-7-1899-2007
  • Rondo, L., Ehrhart, S., Kürten, A., Adamov, A., Bianchi, F. and co-authors. 2016. Effect of dimethylamine on the gas phase sulfuric acid concentration measured by chemical ionization mass spectrometry. J. Geophys. Res. Atmos. 121, 3036–3049.10.1002/2015JD023868
  • Seinfeld, J. H. and Pandis, S. N. 1998. From air pollution to climate change. John Wiley, New York.
  • Sipila, M., Berndt, T., Petaja, T., Brus, D., Vanhanen, J. and co-authors. 2010. The role of sulfuric acid in atmospheric nucleation. Science 327, 1243–1246.10.1126/science.1180315
  • Smith, J. N., Dunn, M. J., VanReken, T. M., Iida, K., Stolzenburg, M. R. and co-authors. 2008. Chemical composition of atmospheric nanoparticles formed from nucleation in Tecamac, Mexico: evidence for an important role for organic species in nanoparticle growth. Geophys. Res. Lett. 35, 5.
  • Spracklen, D. V., Carslaw, K. S., Kulmala, M., Kerminen, V. M., Mann, G. W. and co-authors. 2006. The contribution of boundary layer nucleation events to total particle concentrations on regional and global scales. Atmos. Chem. Phys. 6, 5631–5648.10.5194/acp-6-5631-2006
  • Travnickova, T., Havlica, J. and Zdimal, V. 2013. Description of fluid dynamics and coupled transports in models of a laminar flow diffusion chamber. J. Chem. Phys. 139, 14.
  • Trávníček, Z., Hrubý, J. and Vogel, J. 2004. Visualization and numerical study of confined coaxial jets. In: Proceedings of the Engineering Mechanics, Czech Republic, 2004.
  • Trávníček, Z., Hrubý, J. and Vogel, J. 2005. Coaxial jets stability and control possibility. Dev. Mach. Des. Control 4, 121–130.
  • Vanhanen, J., Mikkilä, J., Lehtipalo, K., Sipilä, M., Manninen, H. E. and co-authors. 2011. Particle size magnifier for nano-CN detection. Aerosol Sci. Technol. 45, 533–542.10.1080/02786826.2010.547889
  • Viisanen, Y., Kulmala, M. and Laaksonen, A. 1997. Experiments on gas–liquid nucleation of sulfuric acid and wafer. J. Chem. Phys. 107, 920–926.10.1063/1.474445
  • Viisanen, Y. and Strey, R. 1994. Homogeneous nucleation rates for n ‐butanol. J. Chem. Phys. 101, 7835–7843.10.1063/1.468208
  • Wagner, P. E. and Anisimov, M. P. 1993. Evaluation of nucleation rates from gas flow diffusion chamber experiments. J. Aerosol Sci. 24, S103–S104.10.1016/0021-8502(93)90144-X
  • Wagner, W. and Pruß, A. 2002. The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use. J. Phys. Chem. Ref. Data 31, 387–535.10.1063/1.1461829
  • Wagner, P. E. and Strey, R. 1981. Homogeneous nucleation rates of water-vapor measured in a 2-piston expansion chamber. J. Phys. Chem. 85, 2694–2698.10.1021/j150618a026
  • Wyslouzil, B. E., Seinfeld, J. H., Flagan, R. C. and Okuyama, K. 1991a. Binary nucleation in acid–water systems. II. Sulfuric acid–water and a comparison with methanesulfonic acid–water. J. Chem. Phys. 94, 6842–6850.10.1063/1.460262
  • Wyslouzil, B. E., Seinfeld, J. H., Flagan, R. C. and Okuyama, K. 1991b. Binary nucleation in acid water-systems. 1. Methanesulfonic-acid water. J. Chem. Phys. 94, 6827–6841.
  • Wyslouzil, B. E. and Wölk, J. 2016. Overview: homogeneous nucleation from the vapor phase—the experimental science. J. Chem. Phys. 145, 211702.10.1063/1.4962283
  • Young, L. H., Benson, D. R., Kameel, F. R., Pierce, J. R., Junninen, H. and co-authors. 2008. Laboratory studies of H2SO4/H2O binary homogeneous nucleation from the SO2 + OH reaction: evaluation of the experimental setup and preliminary results. Atmos. Chem. Phys. 8, 4997–5016.10.5194/acp-8-4997-2008
  • Zhang, R. Y. 2010. Getting to the critical nucleus of aerosol formation. Science 328, 1366–1367.10.1126/science.1189732
  • Zollner, J. H., Glasoe, W. A., Panta, B., Carlson, K. K., McMurry, P. H. and co-authors. 2012. Sulfuric acid nucleation: power dependencies, variation with relative humidity, and effect of bases. Atmos. Chem. Phys. 12, 4399–4411.10.5194/acp-12-4399-2012