Catalysts used in biodiesel production: a review

References

• Chouhan AS, Sarma AK. Modern heterogeneous catalysts for biodiesel production: A comprehensive review. Renewable and Sustainable Energy Reviews. 2011;15:4378–4399.
   Web of Science ®Google Scholar
• Guan G, Kusakabe K, Sakurai N, et al. Transesterification of vegetable oil to biodiesel fuel using acid catalysts in the presence of dimethyl ether. Fuel. 2009;88:81–86.
   Web of Science ®Google Scholar
• Wang Y, Ou S, Liu P, et al. Comparison of two different processes to synthesize biodiesel by waste cooking oil. Journal of Molecular Catalysis A. Chemical. 2006;252:107–112.
   Web of Science ®Google Scholar
• Issariyakul T, Dalai AK. Biodiesel from vegetable oils. Renewable and Sustainable Energy Reviews. 2014;31:446–471.
   Web of Science ®Google Scholar
• Mahdavian L, Bohlouli A. Advanced Techniques in the Production of Biodiesel. Tehran: Artistic and Cultural Institute Dibagaran Tehran. 2017.
   Google Scholar
• Fauzi AH, Amin NA. An overview of ionic liquids as solvents in biodiesel synthesis. Renewable and Sustainable Energy Reviews. 2012;16:5770–5786.
   Web of Science ®Google Scholar
• Baskar G, Aiswarya R. Trends in catalytic production of biodiesel from various feedstocks. Renewable and Sustainable Energy Reviews. 2016;57:496–504.
   Web of Science ®Google Scholar
• Kung HH, Kung MC. Nanotechnology and heterogeneous catalysis, in Nanotechnology in Catalysis. 2007, New York: Springer. p.1–11.
   Google Scholar
• Avhad MR, Marchetti JM. A review on recent advancement in catalytic materials for biodiesel production. Renewable and Sustainable Energy Reviews. 2015;50:696–718.
   Web of Science ®Google Scholar
• Graboski MS, McCormick RL. Combustion of fat and vegetable oil derived fuels in diesel engines. Progress in Energy and Combustion Science. 1998; 24:125–164.
   Web of Science ®Google Scholar
• Zhang Y, Dube MA, McLean DD, et al. Biodiesel production from waste cooking oil: 1. Process design and technological assessment. Bioresour Technol. 2003;89:1–6.
   PubMed Web of Science ®Google Scholar
• Helwani Z, Othman MR, Aziz N, et al. Solid heterogeneous catalysts for transesterification of triglycerides with methanol: a review. Applied Catalysis A: General. 2009;363:1–0.
   Web of Science ®Google Scholar
• De Boer K. Optimised small scale reactor technology, a new approach for the Australian biodiesel industry. Thesis in Murdoch University. Western Australia. 2010.
   Google Scholar
• Lotero E, Goodwin JG, Bruce DA, et al. The catalysis of biodiesel synthesis. catalysis. 2006;19:41–83.
   Google Scholar
• Mittelbach M, Remschmidt C. Biodiesel–The comprehensive handbook. Martin Mittelbach (Publisher), Am Blumenhang 27, A8010 Graz, Austria. 340 s. ISBN 3-200-00249-2; 2005.
   Google Scholar
• Kulkarni MG, Dalai AK. Waste cooking oil an economical source for biodiesel: a review. Ind Eng Chem Res. 2006;45:2901–2913.
   Web of Science ®Google Scholar
• Atadashi IM, Aroua MK, Aziz AA, et al. The effects of catalysts in biodiesel production: A review. Journal of Industrial and Engineering Chemistry. 2013;19:14–26.
   Web of Science ®Google Scholar
• Sharma YC, Singh B. Development of biodiesel: current scenario. Renewable and Sustainable Energy Reviews. 2009;13:1646–1651.
   Web of Science ®Google Scholar
• Lotero E, Liu Y, Lopez DE, et al. Synthesis of biodiesel via acid catalysis. Ind Eng Chem Res. 2005;44:5353–5363.
   Web of Science ®Google Scholar
• Tariq M, Ali S, Khalid N. Activity of homogeneous and heterogeneous catalysts, spectroscopic and chromatographic characterization of biodiesel: a review. Renewable and Sustainable Energy Reviews. 2012;16:6303–6316.
   Web of Science ®Google Scholar
• Freedman BE, Pryde EH, Mounts TL. Variables affecting the yields of fatty esters from transesterified vegetable oils. J Am Oil Chem Soc. 1984;61:1638–1643.
   Web of Science ®Google Scholar
• Huang YP, Chang JI. Biodiesel production from residual oils recovered from spent bleaching earth. Renewable Energy. 2010;35:269–274.
   Web of Science ®Google Scholar
• Ramadhas AS, Jayaraj S, Muraleedharan C. Biodiesel production from high FFA rubber seed oil. Fuel. 2005;84:335–340.
   Web of Science ®Google Scholar
• Tiwari AK, Kumar A, Raheman H. Biodiesel production from jatropha oil (Jatropha curcas) with high free fatty acids: an optimized process. Biomass and Bioenergy. 2007;31:569–575.
   Web of Science ®Google Scholar
• Chongkhong S, Tongurai C, Chetpattananondh P. Continuous esterification for biodiesel production from palm fatty acid distillate using economical process. Renewable Energy. 2009;34:1059–1063.
   Web of Science ®Google Scholar
• Marchetti JM, Miguel VU, Errazu AF. Possible methods for biodiesel production. Renewable and Sustainable Energy Reviews. 2007;11:1300–1311.
   Web of Science ®Google Scholar
• Sahoo PK, Das LM, Babu MK, et al. Biodiesel development from high acid value polanga seed oil and performance evaluation in a CI engine. Fuel. 2007;86:448–454.
   Web of Science ®Google Scholar
• Ma F, Hanna MA. Biodiesel production: a review. Bioresource Technology. 1999;70:1–5.
   Web of Science ®Google Scholar
• Encinar JM, González JF, Rodríguez-Reinares A. Ethanolysis of used frying oil. Biodiesel preparation and characterization. Fuel Processing Technology. 2007;88:513–522.
   Web of Science ®Google Scholar
• Dmytryshyn SL, Dalai AK, Chaudhari ST, et al. Synthesis and characterization of vegetable oil derived esters: evaluation for their diesel additive properties. Bioresour Technol. 2004;92:55–64.
   PubMed Web of Science ®Google Scholar
• Karmee SK, Chadha A. Preparation of biodiesel from crude oil of Pongamia pinnata. Bioresour Technol. 2005;96:1425–1429.
   PubMed Web of Science ®Google Scholar
• Leung DY, Guo Y. Transesterification of neat and used frying oil: optimization for biodiesel production. Fuel Processing Technology. 2006;87:883–890.
   Web of Science ®Google Scholar
• Rashid U, Anwar F. Production of biodiesel through optimized alkaline-catalyzed transesterification of rapeseed oil. Fuel. 2008;87:265–273.
   Web of Science ®Google Scholar
• Rashid U, Anwar F, Moser BR, et al. Production of sunflower oil methyl esters by optimized alkali-catalyzed methanolysis. Biomass and Bioenergy. 2008;32:1202–1205.
   Web of Science ®Google Scholar
• Keera ST, El Sabagh SM, Taman AR. Transesterification of vegetable oil to biodiesel fuel using alkaline catalyst. Fuel. 2011;90:42–47.
   Web of Science ®Google Scholar
• Dias JM, Alvim-Ferraz MC, Almeida MF. Comparison of the performance of different homogeneous alkali catalysts during transesterification of waste and virgin oils and evaluation of biodiesel quality. Fuel. 2008;87:3572–3578.
   Web of Science ®Google Scholar
• Uzun BB, Kılıç M, Özbay N, et al. Biodiesel production from waste frying oils: Optimization of reaction parameters and determination of fuel properties. Energy. 2012;44:347–351.
   Web of Science ®Google Scholar
• Chung KH, Kim J, Lee KY. Biodiesel production by transesterification of duck tallow with methanol on alkali catalysts. Biomass and Bioenergy. 2009;33:155–158.
   Web of Science ®Google Scholar
• Chen KS, Lin YC, Hsu KH, et al. Improving biodiesel yields from waste cooking oil by using sodium methoxide and a microwave heating system. Energy. 2012;38:151–156.
   Web of Science ®Google Scholar
• Hassani M, Najafpour GD , Mohammadi M. Transesterification of Waste Cooking Oil to Biodiesel using γ-alumina Coated on Zeolite Pellets. Mater. Environ. Sci. 2016;7(4): 1193-1203.
   Google Scholar
• Canacki M, Gerpen JV. Biodiesel production via acid catalysis. Trans ASAE. 1999;42:1203–1210.
   Google Scholar
• Veljković VB, Lakićević SH, Stamenković OS, et al. Biodiesel production from tobacco (Nicotiana tabacum L.) seed oil with a high content of free fatty acids. Fuel. 2006;85:2671–2675.
   Web of Science ®Google Scholar
• Zhang J, Jiang L. Acid-catalyzed esterification of Zanthoxylum bungeanum seed oil with high free fatty acids for biodiesel production. Bioresource Technology. 2008;99:8995–8998.
   PubMed Web of Science ®Google Scholar
• Bhatti HN, Hanif MA, Qasim M. Biodiesel production from waste tallow. Fuel. 2008;87:2961–2966.
   Web of Science ®Google Scholar
• Miao X, Li R, Yao H. Effective acid-catalyzed transesterification for biodiesel production. Energy Conversion and Management. 2009;50:2680–2684.
   Web of Science ®Google Scholar
• Dalvand P, Mahdavian L. Calculation of the properties of biodiesel produced from castor seed by eggshell catalyst. Biofuel. Biofuels. 2018; 9(6): 705-710.
   Google Scholar
• Mardhiah HH, Ong HC, Masjuki HH, et al. A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils. Renewable and Sustainable Energy Reviews. 2017;67:1225–1236.
   Web of Science ®Google Scholar
• Farooq M, Ramli A, Subbarao D. Biodiesel production from waste cooking oil using bifunctional heterogeneous solid catalysts. Journal of Cleaner Production. 2013;59:131–140.
   Web of Science ®Google Scholar
• Ma Y, Wang Q, Sun X, et al. Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst. Renewable Energy. 2017;107:522–530.
   Web of Science ®Google Scholar
• Meher LC, Churamani CP, Arif M, et al. Jatropha curcas as a renewable source for bio-fuels—A review. Renewable and Sustainable Energy Reviews. 2013;26:397–407.
   Web of Science ®Google Scholar
• Tan YH, Abdullah MO, Nolasco-Hipolito C, et al. Waste ostrich-and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: Catalyst characterization and biodiesel yield performance. Appl Energy. 2015;160:58–70.
   Web of Science ®Google Scholar
• Borges ME, Díaz L. Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: a review. Renewable and Sustainable Energy Reviews. 2012;16:2839–2849.
   Web of Science ®Google Scholar
• Sandesh S, Kristachar PK, Manjunathan P, et al. Synthesis of biodiesel and acetins by transesterification reactions using novel CaSn (OH) 6 heterogeneous base catalyst​. Applied Catalysis A: General. 2016;523:1–11.
   Web of Science ®Google Scholar
• Fraile JM, García N, Mayoral JA, et al. The influence of alkaline metals on the strong basicity of Mg–Al mixed oxides: the case of transesterification reactions. Applied Catalysis A: General. 2009;364:87–94.
   Web of Science ®Google Scholar
• Sree R, Babu NS, Prasad PS, et al. Transesterification of edible and non-edible oils over basic solid Mg/Zr catalysts. Fuel Processing Technology. 2009;90:152–157.
   Web of Science ®Google Scholar
• Uprety BK, Chaiwong W, Ewelike C, et al. Biodiesel production using heterogeneous catalysts including wood ash and the importance of enhancing byproduct glycerol purity. Energy Conversion and Management. 2016;115:191–199.
   Web of Science ®Google Scholar
• Chen KT, Wang JX, Dai YM, et al. Rice husk ash as a catalyst precursor for biodiesel production. Journal of the Taiwan Institute of Chemical Engineers. 2013;44:622–629.
   Web of Science ®Google Scholar
• Laskar IB, Rajkumari K, Gupta R, et al. Waste snail shell derived heterogeneous catalyst for biodiesel production by the transesterification of soybean oil. RSC Adv. 2018; 8:20131–20142.
   PubMed Web of Science ®Google Scholar
• Kostić MD, Bazargan A, Stamenković OS, et al. Optimization and kinetics of sunflower oil methanolysis catalyzed by calcium oxide-based catalyst derived from palm kernel shell biochar. Fuel. 2016; 163:304–313.
   Web of Science ®Google Scholar
• Olutoye MA, Hameed BH . Synthesis of fatty acid methyl ester from crude jatropha (Jatropha curcas Linnaeus) oil using aluminium oxide modified Mg-Zn heterogeneous catalyst. Bioresour Technol. 2011;102:6392–6398.
   PubMed Web of Science ®Google Scholar
• Wen L, Wang Y, Lu D, et al. Preparation of KF/CaO nanocatalyst and its application in biodiesel production from Chinese tallow seed oil. Fuel. 2010;89:2267–2271.
   Web of Science ®Google Scholar
• Bajaj A, Lohan P, Jha PN, et al. Biodiesel production through lipase catalyzed transesterification: An overview. J Mol Catal B Enzym. 2010; 62:9–14.
   Web of Science ®Google Scholar
• Alba-Rubio AC, Santamaría-González J, Mérida-Robles JM, et al. Heterogeneous transesterification processes by using CaO supported on zinc oxide as basic catalysts. Catalysis Today. 2010;149:281–287.
   Web of Science ®Google Scholar
• Zabeti M, Daud WM, Aroua MK. Biodiesel production using alumina-supported calcium oxide: an optimization study. Fuel Processing Technology. 2010;91:243–248.
   Web of Science ®Google Scholar
• Liu C, Lv P, Yuan Z, et al. The nanometer magnetic solid base catalyst for production of biodiesel. Renewable Energy. 2010;35:1531–1536.
   Web of Science ®Google Scholar
• Wen Z, Yu X, Tu ST, et al. Synthesis of biodiesel from vegetable oil with methanol catalyzed by Li-doped magnesium oxide catalysts. Appl Energy. 2010;87:743–748.
   Web of Science ®Google Scholar
• Zhu H, Wu Z, Chen Y, et al. Preparation of biodiesel catalyzed by solid super base of calcium oxide and its refining process. Chinese Journal of Catalysis. 2006;27:391–396.
   Web of Science ®Google Scholar
• Sun C, Qiu F, Yang D, et al. Preparation of biodiesel from soybean oil catalyzed by Al-Ca hydrotalcite loaded with K2CO3 as heterogeneous solid base catalyst. Fuel Processing Technology. 2014;126:383–391.
   Web of Science ®Google Scholar
• Navajas A, Campo I, Arzamendi G, et al. Synthesis of biodiesel from the methanolysis of sunflower oil using PURAL® Mg–Al hydrotalcites as catalyst precursors. Applied Catalysis B: Environmental. 2010;100:299–309.
   Web of Science ®Google Scholar
• Silva CC, Ribeiro NF, Souza MM, et al. Biodiesel production from soybean oil and methanol using hydrotalcites as catalyst. Fuel Processing Technology. 2010;91:205–210.
   Web of Science ®Google Scholar
• Kumar D, Kumar G, Singh CP. Ultrasonic-assisted transesterification of Jatropha curcus oil using solid catalyst, Na/SiO2. Ultrasonics Sonochemistry. 2010;17:839–844.
   PubMed Web of Science ®Google Scholar
• Guo F, Peng ZG, Dai JY, et al. Calcined sodium silicate as solid base catalyst for biodiesel production. Fuel Processing Technology. 2010;91:322–328.
   Web of Science ®Google Scholar
• Galadima A, Muraza O. Biodiesel production from algae by using heterogeneous catalysts: A critical review. Energy. 2014;78:72–83.
   Web of Science ®Google Scholar
• Guldhe A, Moura CV, Singh P, et al. Conversion of microalgal lipids to biodiesel using chromium-aluminum mixed oxide as a heterogeneous solid acid catalyst. Renewable Energy. 2017;105:175–182.
   Web of Science ®Google Scholar
• Arzamendi G, Campo I, Arguinarena E, et al. Synthesis of biodiesel with heterogeneous NaOH/alumina catalysts: comparison with homogeneous NaOH. Chemical Engineering Journal. 2007;134:123–130.
   Web of Science ®Google Scholar
• Ramos MJ, Casas A, Rodríguez L, et al. Transesterification of sunflower oil over zeolites using different metal loading: A case of leaching and agglomeration studies. Applied Catalysis A: General. 2008;346:79–85.
   Web of Science ®Google Scholar
• Peng BX, Shu Q, Wang JF, et al. Biodiesel production from waste oil feedstocks by solid acid catalysis. Process Safety and Environmental Protection. 2008;86:441–447.
   Web of Science ®Google Scholar
• Lou WY, Zong MH, Duan ZQ. Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts. Bioresource Technology. 2008;99:8752–8758.
   PubMed Web of Science ®Google Scholar
• Li W, Ma F, Su F, et al. One-Step Preparation of Efficient and Reusable SO42-/ZrO2-Based Hybrid Solid Catalysts Functionalized by Alkyl-Bridged Organosilica Moieties for Biodiesel Production. ChemSusChem. 2011; 4:744–756.
   PubMed Web of Science ®Google Scholar
• Zhang X, Li J, Chen Y, et al. Heteropolyacid Nanoreactor with Double Acid Sites as a Highly Efficient and Reusable Catalyst for the Transesterification of Waste Cooking Oil. 2009; 23: 4640–4646.
   Google Scholar
• Alhassan FH, Rashid U, Taufiq-Yap YH. Biodiesel Synthesis Catalyzed by Transition Metal Oxides: Ferric-Manganese Doped Tungstated/Molybdena Nanoparticle Catalys. Journal of Oleo Science. 2017;70:1–9.
   Web of Science ®Google Scholar
• Ayodele OO, Dawodu FA. Production of biodiesel from Calophyllum inophyllum oil using a cellulose-derived catalyst. Biomass and Bioenergy. 2014;70:239–248.
   Web of Science ®Google Scholar
• Petchmala A, Laosiripojana N, Jongsomjit B, et al. Transesterification of palm oil and esterification of palm fatty acid in near-and super-critical methanol with SO4–ZrO2 catalysts. Fuel. 2010;89:2387–2392.
   Web of Science ®Google Scholar
• Zanette AF, Barella RA, Pergher SB, et al. Screening, optimization and kinetics of Jatropha curcas oil transesterification with heterogeneous catalysts. Renewable Energy. 2011;36:726–731.
   Web of Science ®Google Scholar
• Yan F, Yuan Z, Lu P, et al. Fe–Zn double-metal cyanide complexes catalyzed biodiesel production from high-acid-value oil. Renewable Energy. 2011;36:2026–2031.
   Web of Science ®Google Scholar
• Jacobson K, Gopinath R, Meher LC, et al. Solid acid catalyzed biodiesel production from waste cooking oil. Applied Catalysis B: Environmental. 2008;85:86–91.
   Web of Science ®Google Scholar
• Shu Q, Gao J, Nawaz Z, et al. Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst. Appl Energy. 2010;87:2589–2596.
   Web of Science ®Google Scholar
• Sunita G, Devassy BM, Vinu A, et al. Synthesis of biodiesel over zirconia-supported isopoly and heteropoly tungstate catalysts. Catalysis Communications. 2008;9:696–702.
   Web of Science ®Google Scholar
• Chopade SG, Kulkarni KS, Kulkarni AD, et al. Solid heterogeneous catalysts for production of biodiesel from trans-esterification of triglycerides with methanol: a review. Acta Chimica & Pharmaceutica Indica. 2012;2:8–14.
   Google Scholar
• Chiang WH, Sankaran RM. Relating carbon nanotube growth parameters to the size and composition of nanocatalysts. Diamond and Related Materials. 2009;18:946–952.
   Web of Science ®Google Scholar
• Bhaskar M, Surekha M, Suma N. Esterification of phenyl acetic acid with p-cresol using metal cation exchanged montmorillonite nanoclay catalysts. R Soc Open Sci. 2018;5:171378.
   PubMed Web of Science ®Google Scholar
• Gao J, Zhong J, Bai L, et al. Revealing the role of catalysts in carbon nanotubes and nanofibers by scanning transmission X-ray Microscopy. Scientific Reports. 2014;4:3606.
   PubMed Web of Science ®Google Scholar
• da Silva AN, Neto AB, Oliveira AC, et al. Raman studies of nanocomposites catalysts: temperature and pressure effects of CeAl, CeMn and NiAl oxides. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2018;198:160–167.
   PubMed Web of Science ®Google Scholar
• Bhaumik A. Porous Nanomaterials for Energy, Environment and Biomedical Applications. J Mater Sci Nanomater. 2017; 1:e109.
   Google Scholar
• Karthikeyan S, Prathima A. Characteristics analysis of carbon nanowires in diesel: Neochloris oleoabundans algae oil biodiesel–ethanol blends in a CI engine. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. 2016;38:3089–3094.
   Web of Science ®Google Scholar
• Debbarma S, Misra RD. Effects of Iron Nanoparticles Blended Biodiesel on the Performance and Emission Characteristics of a Diesel Engine. J Energy Resour Technol. 2017;139:042212.
   Web of Science ®Google Scholar
• Banković–Ilić IB, Miladinović MR, Stamenković OS, et al. Application of nano CaO–based catalysts in biodiesel synthesis. Renewable and Sustainable Energy Reviews. 2017;72:746–760.
   Web of Science ®Google Scholar
• Van Hove MA. From surface science to nanotechnology. Catalysis Today. 2006;113:133–140.
   Web of Science ®Google Scholar
• Amini G, Najafpour GD, Rabiee SM, et al. Synthesis and Characterization of Amorphous Nano‐Alumina Powders with High Surface Area for Biodiesel Production. Chemical Engineering & Technology. 2013;36:1708–1712.
   Web of Science ®Google Scholar
• Chaturvedi S, Dave PN, Shah NK. Applications of nano-catalyst in new era. Journal of Saudi Chemical Society. 2012;16:307–325.
   Web of Science ®Google Scholar
• Boz N, Degirmenbasi N, Kalyon DM. Conversion of biomass to fuel: Transesterification of vegetable oil to biodiesel using KF loaded nano-γ-Al2O3 as catalyst. Applied Catalysis B: Environmental. 2009;89:590–596.
   Web of Science ®Google Scholar
• Deng X, Fang Z, Liu YH, et al. Production of biodiesel from Jatropha oil catalyzed by nanosized solid basic catalyst. Energy. 2011;36:777–784.
   Web of Science ®Google Scholar
• Faria EA, Marques JS, Dias IM, et al. Nanosized and reusable SiO2/ZrO2 catalyst for highly efficient biodiesel production by soybean transesterification. J Braz Chem Soc. 2009;20:1732–1737.
   Web of Science ®Google Scholar
• Feyzi M, Shahbazi E. Catalytic performance and characterization of Cs–Ca/SiO2–TiO2 nanocatalysts for biodiesel production. Journal of Molecular Catalysis A: Chemical. 2015;404:131–138.
   Google Scholar
• Han H, Guan Y. Synthesis of biodiesel from rapeseed oil using K2O/γ-Al2O3 as nano-solid-base catalyst. Wuhan Univ J Nat Sci. 2009;14:75–79.
   Google Scholar
• Kanimozhi S, Perinbam K. Biodesel Production from Pseudomonas Fluorescens Lp1 lipase immobilized on amino-silane modified super paramagnetic Fe3O4 Nanoparticles. J Phys: Conf Ser. . 2013;431:012010. In (Vol. IOP Publishing.
   Google Scholar
• Qiu F, Li Y, Yang D, et al. Heterogeneous solid base nanocatalyst: preparation, characterization and application in biodiesel production. Bioresour Technol. 2011;102:4150–4156.
   PubMed Web of Science ®Google Scholar
• Tamilmagan Maheswari A, PriyaBijesh GA. Biodiesel production from waste cooking oil using green synthesized nanoFe2O3 and CuO impregnated nano Fe3O4. International Journal of ChemTech Research. 2015;8:90–96.
   Google Scholar
• Tang S, Wang L, Zhang Y, et al. Study on preparation of Ca/Al/Fe3O4 magnetic composite solid catalyst and its application in biodiesel transesterification. Fuel Processing Technology. 2012;95:84–89.
   Web of Science ®Google Scholar
• Liu W. Catalyst technology development from macro-, micro-down to nano-scale. China Particuology. 2005;3:383–394.
   Google Scholar
• Hu S, Guan Y, Wang Y, et al. Nano-magnetic catalyst KF/CaO–Fe3O4 for biodiesel production. Appl Energy. 2011;88:2685–2690.
   Web of Science ®Google Scholar
• Ornelas C, Ruiz J, Salmon L, et al. Sulphonated “Click” Dendrimer‐Stabilized Palladium Nanoparticles as Highly Efficient Catalysts for Olefin Hydrogenation and Suzuki Coupling Reactions Under Ambient Conditions in Aqueous Media. Adv Synth Catal. 2008;350:837–845.
   Web of Science ®Google Scholar
• Liu W. Multi-scale catalyst design. Chemical Engineering Science. 2007;62:3502–3512.
   Web of Science ®Google Scholar
• Leeke GA, Lu T, Bridson RH, et al. Application of nano-particle coatings to carrier particles using an integrated fluidized bed supercritical fluid precipitation process. The Journal of Supercritical Fluids. 2014;91:7–14.
   Web of Science ®Google Scholar
• Kaur M, Ali A. Lithium ion impregnated calcium oxide as nano catalyst for the biodiesel production from karanja and jatropha oils. Renewable Energy. 2011;36:2866–2871.
   Web of Science ®Google Scholar
• Gurunathan B, Ravi A. Process optimization and kinetics of biodiesel production from neem oil using copper doped zinc oxide heterogeneous nanocatalyst. Bioresource Technology. 2015;190:424–428.
   PubMed Web of Science ®Google Scholar
• Baskar G, Gurugulladevi A, Nishanthini T, et al. Optimization and kinetics of biodiesel production from Mahua oil using manganese doped zinc oxide nanocatalyst. Renewable Energy. 2017;103:641–646.
   Web of Science ®Google Scholar
• Bet-Moushoul E, Farhadi K, Mansourpanah Y, et al. Application of CaO-based/Au nanoparticles as heterogeneous nanocatalysts in biodiesel production. Fuel. 2016;164:119–127.
   Web of Science ®Google Scholar
• Feyzi M, Hassankhani A, Rafiee HR. Preparation and characterization of Cs/Al/Fe3O4 nanocatalysts for biodiesel production. Energy Conversion and Management. 2013;71:62–68.
   Web of Science ®Google Scholar
• Baskar G, Selvakumari IAE, Aiswarya R. Biodiesel production from castor oil using heterogeneous Ni doped ZnO nanocatalyst. Bioresource Technology. 2018; 250:793–798.
   PubMed Web of Science ®Google Scholar
• Vahid BR, Haghighi M, Alaei S, et al. Reusability enhancement of combustion synthesized MgO/MgAl2O4 nanocatalyst in biodiesel production by glow discharge plasma treatment. Energy Conversion and Management. 2017; 143:23–32.
   Web of Science ®Google Scholar
• Feyzi M, Norouzi L. Preparation and kinetic study of magnetic Ca/Fe3O4@ SiO2 nanocatalysts for biodiesel production. Renewable Energy. 2016;94:579–586.
   Web of Science ®Google Scholar
• Teo SH, Rashid U, Taufiq-Yap YH. Green nano-catalyst for methanolysis of non-edible Jatropha oil. Energy Conversion and Management. 2014;87:618–627.
   Web of Science ®Google Scholar
• MacEiras R, Cancela A, Vega M, et al. Enzymatic alholysis for biodiesel production from waste cooking oil. Chemical Engineering Transactions. 2010;19:103–107.
   Google Scholar
• Brask J, Damstrup ML, Nielsen PM, et al. Combining enzymatic esterification with conventional alkaline transesterification in an integrated biodiesel process. Appl Biochem Biotechnol. 2011;163:918–927.
   PubMed Web of Science ®Google Scholar
• Christopher LP, Kumar H, Zambare VP. Enzymatic biodiesel: challenges and opportunities. Appl Energy. 2014;119:497–520.
   Web of Science ®Google Scholar
• Fukuda H, Kondo A, Noda H. Biodiesel fuel production by transesterification of oils. Journal of Bioscience and Bioengineering. 2001;92:405–416.
   PubMed Web of Science ®Google Scholar
• Gog A, Roman M, Toşa M, et al. Biodiesel production using enzymatic transesterification–current state and perspectives. Renewable Energy. 2012;39:10–16.
   Web of Science ®Google Scholar
• Magner E. Immobilisation of enzymes on mesoporous silicate materials. Chem Soc Rev. 2013;42:6213–6222.
   PubMed Web of Science ®Google Scholar
• Lotti M, Pleiss J, Valero F, et al. Enzymatic Production of Biodiesel: Strategies to Overcome Methanol Inactivation. Biotechnol J. 2018;13:1700155.
   Web of Science ®Google Scholar
• Babaki M, Yousefi M, Habibi Z, et al. Enzymatic production of biodiesel using lipases immobilized on silica nanoparticles as highly reusable biocatalysts: effect of water, t-butanol and blue silica gel contents. Renewable Energy. 2016;91:196–206.
   Web of Science ®Google Scholar
• Hartmann M, Jung D. Biocatalysis with enzymes immobilized on mesoporous hosts: the status quo and future trends. Journal of Materials Chemistry. 2010;20:844–857.
   Web of Science ®Google Scholar
• Zhao D, Feng J, Huo Q, et al. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. science. 1998;279:548–552.
   PubMed Web of Science ®Google Scholar
• Hwang ET, Gu MB. Enzyme stabilization by nano/microsized hybrid materials. Eng Life Sci. 2013;13:49–61.
   Web of Science ®Google Scholar
• Gupta R, Gupta N, Rathi P. Bacterial lipases: an overview of production, purification and biochemical properties. Appl Microbiol Biotechnol. 2004;64:763–781.
   PubMed Web of Science ®Google Scholar
• Patil KJ, Chopda MZ, Mahajan RT. Lipase biodiversity. Indian Journal of Science and Technology. 2011;4:971–982.
   Google Scholar
• Kumari A, Mahapatra P, Garlapati VK, et al. Enzymatic transesterification of Jatropha oil. Biotechnol Biofuels. 2009;2:1
   PubMed Web of Science ®Google Scholar
• Li X, Xu H, Wu Q. Large‐scale biodiesel production from microalga Chlorella protothecoides through heterotrophic cultivation in bioreactors. Biotechnol Bioeng. 2007;98:764–771.
   PubMed Web of Science ®Google Scholar
• Royon D, Daz M, Ellenrieder G, et al. Enzymatic production of biodiesel from cotton seed oil using t-butanol as a solvent. Bioresour Technol. 2007;98:648–653.
   PubMed Web of Science ®Google Scholar
• Xu, Wei Du, Jing Zeng and Dehua Liu Y. Conversion of soybean oil to biodiesel fuel using lipozyme TL IM in a solvent-free medium. Biocatalysis and Biotransformation. 2004;22:45–48.
   Web of Science ®Google Scholar
• Kamini NR, Iefuji H. Lipase catalyzed methanolysis of vegetable oils in aqueous medium by Cryptococcus spp. S-2. Process Biochemistry. 2001;37:405–410.
   Web of Science ®Google Scholar
• Oliveira AC, Rosa MF. Enzymatic transesterification of sunflower oil in an aqueous‐oil biphasic system. J Amer Oil Chem Soc. 2006;83:21–25.
   Web of Science ®Google Scholar
• Zhang KP, Lai JQ, Huang ZL, et al. Penicillium expansum lipase-catalyzed production of biodiesel in ionic liquids. Bioresource Technology. 2011;102:2767–2772.
   PubMed Web of Science ®Google Scholar
• Jegannathan KR, Jun-Yee L, Chan ES, et al. Production of biodiesel from palm oil using liquid core lipase encapsulated in κ-carrageenan. Fuel. 2010;89:2272–2277.
   Web of Science ®Google Scholar
• Abdullah SH, Hanapi NH, Azid A, et al. A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production. Renewable and Sustainable Energy Reviews. 2017;70:1040–1051.
   Web of Science ®Google Scholar
• Lam MK, Lee KT, Mohamed AR. Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: a review. Biotechnology Advances. 2010;28:500–518.
   PubMed Web of Science ®Google Scholar