158
Views
0
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis, characterization, and styrene polymerization performance of organo yttrium complexes supported by imino-fuctionalized indenyl ligand

, &
Pages 1179-1185 | Received 23 Aug 2016, Accepted 16 Jan 2017, Published online: 23 Mar 2017

References

  • Edelmann, F. T. Lanthanide and actinides: Annual survey of their organometallic chemistry covering the year 2015. Coord. Chem. Rev. 2016, 318, 29–130.
  • Zimmermann, M.; Anwander, R. Homoleptic rare-earth metal complexes containing Ln-C σ;-bonds. Chem. Rev. 2010, 110, 6194–6259.
  • Gromada, J.; Carpentier, J. F.; Mortreux, A. Group 3 metal catalysts for ethylene and α-olefin polymerization. Coord. Chem. Rev. 2004, 248, 397–410.
  • Edelmann, F. T.; Freckmann, D. M. M.; Schumann, H. Synthesis and structural chemistry of non-cyclopentadienyl organolanthanide complexes. Chem. Rev. 2002, 102, 1851–1896.
  • Molander, G. A.; Romero, J. A. C. Lanthanocene catalysts in selective organic synthesis. Chem. Rev. 2002, 102, 2161–2186.
  • Piers, W. E.; Emsile, D. J. H. Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design. Coord. Chem. Rev. 2002, 233, 131–155.
  • Schumann, H.; Meese-Marktscheffel, J. A.; Esser, L. Synthesis, structure, and reactivity of organometallic π−χομπλϵξϵσ οφ τηϵ ραρϵ ϵαρτησ ιν τηϵ οξιδατιον στατϵ Λν3+ ωιτη αροματιχ λιγανδσ. Χηϵμ. Ρϵϖ. 1995, 95, 865–986.
  • Nishiura, M.; Hou, Z. M. Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls. Nat. Chem. 2010, 2, 257–268.
  • Zeimentz, P. M.; Arndt, S.; Elvidge, B. R.; Okuda, J. Cationic organometallic complexes of scandium, yttrium, and the lanthanoids. Chem. Rev. 2006, 106, 2404–2433.
  • Lappert, M. F.; Protchenko, A. V.; Power, P. P.; Seeber, A. L. Metal Amide Chemistry; Wiley: Hoboken, NJ, 2008.
  • Nolan, S. P.; Stern, D.; Marks, T. J. Organo-f-element thermochemistry. Absolute metal-ligand bond disruption enthalpies in bis(pentamethylcyclopentadieny1) samarium hydrocarbyl, hydride, dialkylamide, alkoxide, halide, thiolate, and phosphide complexes, implications for organolanthanide bonding and reactivity. J. Am. Chem. Soc. 1989, 111, 7844–7853.
  • Yuan, J.; Hu, H. F.; Cui, C. M. N-Heterocyclic carbene–ytterbium amide as a recyclable homogeneous precatalyst for hydrophosphination of alkenes and alkynes. Chem.—Eur. J. 2016, 22, 5778–5785.
  • Zhu, X. C.; Li, Y.; Wei, Y.; Wang, S. W.; Zhou, S. L.; Zhang, L. J. Reactivity of 3-imino-functionalized indoles with rare-earth-metal amides: Unexpected substituent effects on C–H activation pathways and assembly of rare-earth-metal complexes. Organometallics 2016, 35, 1838–1846.
  • Chen, H.; Zhao, B.; Yao, Y. M.; Lu, C. R. Carboxylation of terminal alkynes with CO2 catalyzed by bis(amidate) rare-earth metal amides. Green Chem. 2015, 17, 1675–1682.
  • Buchard, A.; Platel, R. H.; Auffrant, A.; Goff, X. F. L.; Floch, P. L.; Williams, C. K. Iminophosphorane neodymium(III) complexes as efficient initiators for lactide polymerization. Organometallics 2010, 29, 2892–2900.
  • Trambitas, A. G.; Panda, T.; Jenter, J.; Roesky, P. W.; Daniliuc, C.; Hrib, C. G.; Jones, P. G.; Tamm, M. Rare-earth metal alkyl, amido, and cyclopentadienyl complexes supported by imidazolin-2-iminato ligands: synthesis, structural characterization, and catalytic application. Inorg. Chem. 2010, 49, 2435–2446.
  • Döring, C.; Kempe, R. Synthesis and structure of aminopyridinato-stabilized yttrium and lanthanum amides and their reactivity towards alkylaluminium compounds. Eur. J. Inorg. Chem. 2009, 412–418.
  • Cui, P.; Chen, Y. F.; Li, G. Y.; Xia, W. An ansa-heteroborabenzene divalent lanthanide amide through C-H bond cleavage. Angew. Chem., Int. Ed. 2008, 47, 9944–9947.
  • Shi, L. Q.; Su, Q.; Chen, J.; Li, X. N.; Luo, Y. J. Rare-earth metal bis(silylamide) complexes supported by mono-dentate arylamido ligand: synthesis, reactivity, and catalyst precursors in living cis-1,4-selective polymerization of isoprene. Dalton Trans. 2016, 45, 1391–1397.
  • Sun, S.; Yang, H. O.; Luo, Y. J.; Zhang, Y.; Shen, Q.; Yao, Y. M. Synthesis of β-diketiminate-ligated bimetallic and monometallic lanthanide amide complexes and their reactivity with isoprene and AlMe3. Dalton Trans. 2013, 42, 16355–16364.
  • Luo, Y. J.; Lei, Y. L.; Fan, S. M.; Wang, Y. B.; Chen, J. Synthesis of Mono-amidinate-ligated rare-earth-metal bis(silylamide) complexes and their reactivity with [Ph3C][B(C6F5)4], AlMe3 and isoprene. Dalton Trans. 2013, 42, 4040–4051.
  • Wang, Y. B.; Lei, Y. L.; Chi, S. H.; Luo, Y. J. Rare earth metal bis(silylamide) complexes bearing pyridyl-functionalized indenyl ligand: synthesis, structure and performance in the living polymerization of L-lactide and rac-lactide. Dalton Trans. 2013, 42, 1862–1871.
  • Luo, Y. J.; Chi, S. H.; Chen, J. Half-sandwich rare-earth-metal derivatives bearing pyrrolidinyl-functionalized cyclopentadienyl ligand: synthesis, characterization and catalysis in syndiospecific polymerization of styrene. New J. Chem. 2013, 37, 2675–2682.
  • Chen, F.; Fan, S. M.; Wang, Y. B.; Chen, J.; Luo, Y. J. Unusual Si–H bond activation and cationic scandium amide complex formation from a mono-amidinate-ligated scandium bis(silylamide) complex and their performance in isoprene polymerization. Organometallics 2012, 31, 3730–3735.
  • Wang, Y. B.; Luo, Y. J.; Chen, J.; Xue, H. M.; Liang, H. Z. Synthesis of mono(guanidinate) rare earth metal bis(amide) complexes and their performance for the ring-opening polymerization of L-lactide and rac-lactide. New J. Chem. 2012, 36, 933–940.
  • Luo, Y. J.; Feng, X. Y.; Wang, Y. B.; Fan, S. M.; Chen, J.; Lei, Y. L.; Liang, H. Z. Half-sandwich scandium bis(amide) complexes as efficient catalyst precursors for syndiospecific polymerization of styrene. Organometallics 2011, 30, 3270–3274.
  • Luo, Y. J.; Fan, S. M.; Yang, J. P.; Fang, J. H.; Xu, P. Rare earth metal bis(amide) complexes bearing amidinate ancillary ligands: Synthesis, characterization, and performance as catalyst precursors for cis-1,4 selective polymerization of isoprene. Dalton Trans. 2011, 40, 3053–3059.
  • O'Connor, J. M.; Casey, C. P. Ring-slippage chemistry of transition-metal cyclopentadienyl and indenyl complexes. Chem. Rev. 1987, 87, 307–318.
  • Anwander, R.; Runte, O.; Eppinger, J.; Gerstberger, G.; Herdtweck, E.; Spiegler, M. Synthesis and structural characterisation of rare-earth bis(dimethylsilyl)amides and their surface organometallic chemistry on mesoporous MCM-41. J. Chem. Soc., Dalton Trans. 1998, 847–858.
  • Ross, J. H.; Rohjans, S. H.; Schmidtmann, M.; Doye, S. Highly flexible synthesis of indenylethylamines as ligand precursors for titanium complexes. Arkivoc 2015, ii, 76–92.
  • Kaneko, H.; Tsurugi, H.; Panda, T. K.; Mashima, K. Intramolecular alkylation of α-diimine ligands giving amido-imino and diamido scandium and yttrium complexes as catalysts for intramolecular hydroamination/cyclization. Organometallics 2010, 29, 3463–3466.
  • Faller, J. W.; Crabtree, R. H.; Habib, A. Control of slippage and conformation in indenyl complexes. Organometallics 1985, 4, 929–935.
  • Feng, Z. J.; Zhu, X. C.; Wang, S. Y.; Wang, S. W.; Zhou, S. L.; Wei, Y.; Zhang, G. C.; Deng, B.; Mu, X. L. Synthesis, structure, and reactivity of lanthanide complexes incorporating indolyl ligands in novel hapticities. Inorg. Chem. 2013, 52, 9549–9556.
  • Luo, Y. J.; Baldamus, J.; Hou, Z. M. Scandium half-metallocene-catalyzed syndiospecific styrene polymerization and styrene-ethylene copolymerization: unprecedented incorporation of syndiotactic styrene-styrene sequences in styrene-ethylene copolymers. J. Am. Chem. Soc. 2004, 126, 13910–13911.
  • Bonnet, F.; Violante, C. D. C.; Roussel, P.; Mortreux, A.; Visseaux, M. Unprecedented dual behaviour of a half-sandwich scandium-based initiator for both highly selective isoprene and styrene polymerisation. Chem. Commun. 2009, 3380–3382.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.