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Articles

Sulfonated (graphene oxide/poly(ether ketone ether sulfone) (S-GO/S-PEKES) composite proton exchange membrane with high proton conductivity for direct methanol fuel cell

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Pages 1900-1913 | Received 23 Nov 2018, Accepted 23 Feb 2019, Published online: 26 Mar 2019

References

  • Carette, L.; Friedrich, K. A.; Stimming, U. Fuel Cells–Fundamentals and Applications. Fuel Cells. 2001, 1, 5–39. DOI: 10.1002/1615-6854(200105)1:1<5::AID-FUCE5>3.0.CO;2-G.
  • Kim, D. J.; Jo, M. J.; Nam, S. Y. A Review of Polymer–Nanocomposite Electrolyte Membranes for Fuel Cell Application. J. Ind. Eng. Chem. 2015, 21, 36–52. DOI: 10.1016/j.jiec.2014.04.030.
  • Rambabu, G.; Bhat, S. D. Amino Acid Functionalized Graphene Oxide Based Nanocomposite Membrane Electrolytes for Direct Methanol Fuel Cells. J. Membr. Sci. 2018, 551, 1–11. DOI: 10.1016/j.memsci.2018.01.026.
  • Feng, M.; Huang, Y.; Wei, M.; Liu, X. Sulfonated Poly(Arylene Ether Nitrile)-Based Hybrid Membranes Containing Amine-Functionalized GO for Constructing Long-Range Ionic Nanochannels. Int. J. Hydrog. Energy. 2018, 43, 11214–11222. DOI: 10.1016/j.ijhydene.2018.04.227.
  • Uma Devi, A.; Divya, K.; Rana, D.; Sri Abirami Saraswathi, M.; Nagendran, A. Highly Selective and Methanol Resistant Polypyrrole Laminated SPVdF-co- HFP/PWA Proton Exchange Membranes for DMFC Applications. Mater. Chem. Phys. 2018, 212, 533–542. DOI: 10.1016/j.matchemphys.2018.03.086.
  • Wu, Q.; Wang, H.; Lu, S.; Xu, X.; Liang, D.; Xiang, Y. Novel Methanol-Blocking Proton Exchange Membrane Achieved via Self-Anchoring Phosphotungstic Acid into Chitosan Membrane with Submicro-Pores. J. Membr. Sci. 2016, 500, 203–210. DOI: 10.1016/j.memsci.2015.11.019.
  • Liu, X.; Zhang, Y.; Chen, Y.; Li, C.; Dong, J.; Zhang, Q.; Wang, J.; Yang, Z.; Cheng, H. A Superhydrophobic Bromomethylated Poly(Phenylene Oxide) as A Multifunctional Polymer Filler in SPEEK Membrane Towards Neat Methanol Operation of Direct Methanol Fuel Cells. J. Membr. Sci. 2017, 544, 58–67. DOI: 10.1016/j.memsci.2017.09.013.
  • Nambi Krishnan, N.; Henkensmeier, D.; Park, Y.; Jang, J.; Kwon, T.; Koo, C. M.; Kim, H.; Han, J.; Nam, S. Blue Membranes: Sulfonated Copper (II) Phthalocyanine Tetrasulfonic Acid Based Composite Membranes for DMFC and Low Relative Humidity PEMFC. J. Membr. Sci. 2016, 502, 1–10. DOI: 10.1016/j.memsci.2015.12.035.
  • Neburchilov, V.; Martin, J.; Wang, H.; Zhang, J. A Review of Polymer Electrolyte Membranes for Direct Methanol Fuel Cells. J. Power Sources. 2000, 169, 221–238. DOI: 10.1016/j.jpowsour.2007.03.044.
  • Zhao, C.; Lin, H.; Na, H. Novel Cross-Linked Sulfonated Poly (Arylene Ether Ketone) Membranes for Direct Methanol Fuel Cell. Int. J. Hydrog. Energy. 2010, 35, 2176–2182. DOI: 10.1016/j.ijhydene.2009.12.149.
  • Iojoiu, C.; Maréchal, M.; Chabert, F.; Sanchez, J. Y. Mastering Sulfonation of Aromatic Polysulfones: Crucial for Membranes for Fuel Cell Application. Fuel Cells. 2005, 5, 344–354. DOI: 10.1002/fuce.200400082.
  • Auimviriyavat, J.; Changkhamchom, S.; Sirivat, A. Development of Poly(Ether Ether ketone)(PEEK) with Inorganic Filler for Direct Methanol Fuel Cells (Dmfcs). Ind. Eng. Chem. Res. 2011, 50, 12527–12533. DOI: 10.1021/ie2006005.
  • Changkhamchom, S.; Sirivat, A. Composite Proton Exchange Membranes of Sulfonated Poly(Ether Ketone Ether sulfone)(S-PEKES) and Molecular Sieve with High Mechanical Strength for Direct Methanol Fuel Cell. Int. J. Polym. Mater. Polym. Biomat. 2014, 63, 315–322. DOI: 10.1080/00914037.2013.845185.
  • Changkhamchom, S.; Sirivat, A. Polymer Electrolyte Composite Membrane Based on Molecular Sieve 13X Mixed with Sulfonated Poly(Ether Ketone Ether sulfone)(S- PEKES)/poly(phenylene Ether Ether sulfone)(PPEES) Blended Membrane for Use in Direct Methanol Fuel Cell. Adv. Polym. Technol. 2017, 36, 385–391. DOI: 10.1002/adv.21744.
  • Changkhamchom, S.; Sirivat, A. High Proton Conductivity ZSM-5/sulfonated Poly(Ether Ketone Ether sulfone)(S-PEKES) Composite Proton Exchange Membrane for Using in Direct Methanol Fuel Cell. Solid State Ion. 2014, 263, 161–166. DOI: 10.1016/j.ssi.2014.06.008.
  • Bunlengsuwan, P.; Paradee, N.; Sirivat, A. Influence of Sulfonated Graphene Oxide on Sulfonated Polysulfone Membrane for Direct Methanol Fuel Cell. Polym.-Plast. Technol. Eng. 2017, 56, 1695–1703. DOI: 10.1080/03602559.2017.1289398.
  • Zarrin, H.; Higgins, D.; Jun, Y.; Chen, Z.; Fowler, M. Functionalized Graphene Oxide Nanocomposite Membrane for Low Humidity and High Temperature Proton Exchange Membrane Fuel Cells. J. Phys. Chem. C. 2011, 115, 20774–20781. DOI: 10.1021/jp204610j.
  • Chien, H. C.; Tsai, L. C.; Huang, C. P.; Chi-Yun Kang, C.; Lin, J. N.; Chang, F. C. Sulfonated Graphene oxide/Nafion Composite Membranes for High-Performance Direct Methanol Fuel Cells. Int. J. Hydrog. Energy. 2013, 38, 13792–13801. DOI: 10.1016/j.ijhydene.2013.08.036.
  • Lin, C. W.; Lu, Y. S. Highly Ordered Graphene Oxide Paper Laminated with a Nafion Membrane for Direct Methanol Fuel Cells. J. Power Sources. 2013, 237, 187–194. DOI: 10.1016/j.jpowsour.2013.03.005.
  • Mishra, A. K.; Kim, N. H.; Jung, D.; Lee, J. H. Enhanced Mechanical Properties and Proton Conductivity of Nafion-SPEEK-GO Composite Membranes for Fuel Cell Applications. J. Membr. Sci. 2014, 458, 128–135. DOI: 10.1016/j.memsci.2014.01.073.
  • Nicotera, I.; Simari, C.; Coppola, L.; Zygouri, P.; Gournis, D.; Brutti, S.; Minuto, F. D.; Aricò, A. S.; Sebastian, D.; Baglio, V. Sulfonated Graphene Oxide Platelets in Nafion Nanocomposite Membrane: Advantages for Application in Direct Methanol Fuel Cells. J. Phys. Chem. C. 2014, 118, 24357–24368. DOI: 10.1021/jp5080779.
  • Feng, K.; Tang, B.; Wu, P. Sulfonated Graphene Oxide–Silica for Highly Selective Nafion- Based Proton Exchange Membranes. J. Mater. Chem. A. 2014, 2, 16083–16092. DOI: 10.1039/C4TA03207A.
  • Lee, D. C.; Yang, H. N.; Park, S. H.; Kim, W. J. Nafion/Graphene Oxide Composite Membranes for Low Humidifying Polymer Electrolyte Membrane Fuel Cell. J. Membr. Sci. 2014, 452, 20–28. DOI: 10.1016/j.memsci.2013.10.018.
  • Shirdast, A.; Sharif, A.; Abdollahi, M. Prediction of Proton Conductivity of Graphene Oxide-Containing Polymeric Membranes. Int. J. Hydrog. Energy. 2014, 39, 1760–1768. DOI: 10.1016/j.ijhydene.2013.11.046.
  • Sahu, A. K.; Ketpang, K.; Shanmugam, S.; Kwon, O.; Lee, S.; Kim, H. Sulfonated graphene–Nafion Composite Membranes for Polymer Electrolyte Fuel Cells Operating under Reduced Relative Humidity. J. Phys. Chem. C. 2016, 120, 15855–15866. DOI: 10.1021/acs.jpcc.5b11674.
  • Jiang, Z.; Zhao, X.; Manthiram, A. Sulfonated Poly(Ether Ether Ketone) Membranes with Sulfonated Graphene Oxide Fillers for Direct Methanol Fuel Cells. Int. J. Hydrog. Energy. 2013, 38, 5875–5884. DOI: 10.1016/j.ijhydene.2013.02.129.
  • Heo, Y.; Im, H.; Kim, J. The Effect of Sulfonated Graphene Oxide on Sulfonated Poly (Ether Ether Ketone) Membrane for Direct Methanol Fuel Cells. J. Membr. Sci. 2013, 425–426, 11–22. DOI: 10.1016/j.memsci.2012.09.019.
  • Wu, W.; Li, Y.; Chen, P.; Liu, J.; Wang, J.; Zhang, H. Constructing Ionic Liquid-Filled Proton Transfer Channels within Nanocomposite Membrane by Using Functionalized Graphene Oxide. ACS Appl. Mater. Interfaces. 2016, 8, 588–599. DOI: 10.1021/acsami.5b09642.
  • Yin, Y.; Wang, H.; Cao, L.; Li, Z.; Li, Z.; Gang, M.; Wang, C.; Wu, H.; Jiang, Z.; Zhang, P. Sulfonated Poly(Ether Ether Ketone)-Based Hybrid Membranes Containing Graphene Oxide with Acid-Base Pairs for Direct Methanol Fuel Cells. Electrochim. Acta. 2016, 203, 178–188. DOI: 10.1016/j.electacta.2016.04.040.
  • Bakangura, E.; Wu, L.; Ge, L.; Yang, Z.; Xu, T. Mixed Matrix Proton Exchange Membranes for Fuel Cells: State of the Art and Perspectives. Prog. Polym. Sci.. 2016, 57, 103–152. DOI: 10.1016/j.progpolymsci.2015.11.004.
  • Qiu, X.; Dong, T.; Ueda, M.; Zhang, X.; Wang, L. Sulfonated Reduced Graphene Oxide as a Conductive Layer in Sulfonated Poly(Ether Ether Ketone) Nanocomposite Membranes. J. Membr. Sci. 2017, 524, 663–672. DOI: 10.1016/j.memsci.2016.11.064.
  • Pandey, R. P.; Shukla, G.; Manohar, M.; Shahi, V. K. Graphene Oxide Based Nanohybrid Proton Exchange Membranes for Fuel Cell Applications: An Overview. Adv. Colloid Interface Sci. 2017, 240, 15–30. DOI: 10.1016/j.cis.2016.12.003.
  • Liu, S.; Li, D.; Wang, L.; Yang, H.; Han, X.; Liu, B. Ethylenediarnine- Functionalized Graphene Oxide Incorporated Acid-Base Ion Exchange Membranes for Vanadium Redox Flow Battery. Electrochim. Acta. 2017, 230, 204–211.
  • Xu, C.; Cao, Y.; Kumar, R.; Wu, X.; Wang, X.; Scott, K. A Polybenzimidazole/Sulfonated Graphite Oxide Composite Membrane for High Tem- Perature Polymer Electrolyte Membrane Fuel Cells. J. Mater. Chem. 2011, 21, 11359–11364.
  • Üregen, N.; Pehlivanoğlu, K.; Özdemir, Y.; Devrim, Y. Development of Polybenzimidazole/Graphene Oxide Composite Membranes for High Temperature PEM Fuel Cells. Int. J. Hydrog. Energy. 2017, 42, 2636–2647.
  • Cai, Y.; Yue, Z.; Xu, S. A Novel Polybenzimidazole Composite Modified by Sulfonated Graphene Oxide for High Temperature Proton Exchange Membrane Fuel Cells in Anhydrous Atmosphere. J. Appl. Polym. Sci. 2017, 134, 44986.
  • Ye, Y. S.; Cheng, M. Y.; Xie, X. L.; Rick, J.; Huang, Y. J.; Chang, F. C.; Hwang, B. J. Alkali Doped Polyvinyl Alcohol/Graphene Electrolyte for Direct Methanol Alkaline Fuel Cells. J. Power Sources. 2013, 239, 424–432.
  • Beydaghi, H.; Javanbakht, M.; Kowsari, E. Synthesis and Characterization of Poly(Vinyl Alcohol)/Sulfonated Graphene Oxide Nanocomposite Membranes for Use in Proton Exchange Membrane Fuel Cells (Pemfcs). Ind. Eng. Chem. Res. 2014, 53, 16621–16632.
  • Pandey, R. P.; Thakur, A. K.; Shahi, V. K. Sulfonated Polyimide/Acid- Functionalized Graphene Oxide Composite Polymer Electrolyte Membranes with Improved Proton Conductivity and Water-Retention Properties. ACS Appl. Mater. Interfaces. 2014, 6, 16993–17002.
  • He, Y.; Tong, C.; Geng, L.; Liu, L.; Lü, C. Enhanced Performance of the Sulfonated Polyimide Proton Exchange Membranes by Graphene Oxide: Size Effect of Graphene Oxide. J. Membr. Sci. 2014, 458, 36–46.
  • Liu, Y.; Wang, J.; Zhang, H.; Ma, C.; Liu, J.; Cao, S.; Zhang, X. Enhancement of Proton Conductivity of Chitosan Membrane Enabled by Sulfonated Graphene Oxide under Both Hydrated and Anhydrous Conditions. J. Power Sources. 2014, 269, 898–911.
  • Shirdast, A.; Sharif, A.; Abdollahi, M. Effect of the Incorporation of Sulfonated Chitosan/Sulfonated Graphene Oxide on the Proton Conductivity of Chitosan Membranes. J. Power Sources. 2016, 306, 541–551.
  • Yuan, T.; Pu, L.; Huang, Q.; Zhang, H.; Li, X.; Yang, H. An Effective Methanol-Blocking Membrane Modified with Graphene Oxide Nanosheets for Passive Direct Methanol Fuel Cells. Electrochim. Acta. 2014, 117, 393–397.
  • Kim, K.; Bae, J.; Lim, M. Y.; Heo, P.; So-Won Choi, S. W.; Kwon, H. H.; Lee, J. C. Enhanced Physical Stability and Chemical Durability of Sulfonated Poly(Arylene Ether Sulfone) Composite Membranes Having Antioxidant Grafted Graphene Oxide for Polymer Electrolyte Membrane Fuel Cell Applications. J. Membr. Sci. 2017, 525, 125–134.
  • Zhao, Y.; Fua, Y.; Hub, B.; Lü, C. Quaternized Graphene Oxide Modified Ionic Cross- Linked Sulfonated Polymer Electrolyte Composite Proton Exchange Membranes with Enhanced Properties. Solid State Ion. 2016, 294, 43–53.
  • Feng, M.; Huang, Y.; Cheng, T.; Liu, X. Synergistic Effect of Graphene Oxide and Carbon Nanotubes on Sulfonated Poly(Arylene Ether Nitrile)-Based Proton Conducting Membranes. Int. J. Hydrog. Energy. 2017, 42, 8224–8232.
  • Muthumeenal, A.; Sri Abirami Saraswathi, M.; Rana, D.; Nagendran, A. Fabrication and Electrochemical Properties of Highly Selective SPES/GO Composite Membranes for Direct Methanol Fuel Cells. J. Environ. Chem. Eng. 2017, 5, 3828–3833.
  • Devi, A. U.; Divya, K.; Kaleekkal, N. J.; Rana, D.; Nagendran, A. Tailored SPVdF-co- HFP/SGO Nanocomposite Proton Exchange Membranes for Direct Methanol Fuel Cells. Polymer. 2018, 140, 22–32.
  • Changkhamchom, S.; Sirivat, A. Synthesis and Properties of Sulfonated Poly(Ether Ketone Ether Sulfone) (S-PEKES) via Bisphenol S: Effect of Sulfonation. Polym. Bull. 2010, 65, 265–281. DOI: 10.1007/s00289-010-0243-8.
  • Wang, Z.; Ni, H.; Zhao, C.; Li, X.; Fu, T.; Na, H. Investigation of Sulfonated Poly(Ether Ether Ketone Sulfone/Heteropolyacid Composite Membranes for High Temperature Fuel Cell Applications. J. Polym. Sci. Pt. B-Polym. Phys. 2006, 44, 1967–1978.
  • Li, X.; Lui, C.; Lu, H.; Zhao, C.; Wang, Z.; Xing, W.; Na, H. Preparation and Characterization of Sulfonated Poly(Ether Ether Ketone Ketone) Proton Exchange Membranes for Fuel Cell Application. J. Membr. Sci. 2005, 255, 149–155.
  • Vetter, S.; Ruffmann, B.; Buder, I.; Nunes, S. P. Proton Conductive Membranes of Sulfonated Poly(Ether Ketone Ketone). J. Membr. Sci. 2005, 260, 181–186.
  • Huang, A.; Xia, C.; Xiao, C.; Zhuang, L. Composite Anion Exchange Membrane for Alkaline Direct Methanol Fuel Cell: Structural and Electrochemical Characterization. J. Appl. Polym. Sci. 2006, 100, 2248–2251.
  • Changkhamchom, S.; Sirivat, A. Polymer Electrolyte Membrane Based on Sulfonated Poly(Ether Ketone Ether sulfone)(S-PEKES) with Low Methanol Permeability for Direct Methanol Fuel Cell Application. Polym.-Plast. Technol. Eng. 2013, 52, 70–79.
  • Lakshmi, M.; Choudhary, V.; Varma, I. K. Sulphonated Poly(Ether Ether Ketone): Synthesis and Characterisation. J. Membr. Sci. 2005, 40, 629–636.
  • Zhang, L.; Tiejun Shi, T.; Wu, S.; Zhou, H. Sulfonated Graphene Oxide: The New and Effective Material for Synthesis of Polystyrene-Based Nanocomposites. Colloid Polym. Sci. 2013, 291, 2061–2068.
  • Tegou, E.; Pseiropoulos, G.; Filippidou, M. K.; Chatzandroulis, S. Low-Temperature Thermal Reduction of Graphene Oxide Films in Ambient Atmosphere: Infra-Red Spectroscopic Studies and Gas Sensing Applications. Microelectron. Eng. 2013, 159, 146–150.
  • Zaidi, J.;. Polymer Sulfonation - A Versatile Route to Prepare Proton-Conducting Membrane Material for Advanced Technologies. Arab. J. Sci. Eng. 2003, 28, 183–194.
  • Reyna-Valencia, A.; Kaliaguine, S.; Bousmina, M. Tensile Mechanical Properties of Sulfonated Poly(Ether Ether Ketone) (SPEEK) and BPO4/SPEEK Membrane. J. Appl. Polym. Sci. 2005, 98, 2380–2393.
  • Kraysberg, A.; Ein-Eli, Y. Review of Advanced Materials for Proton Exchange Membrane Fuel Cells. Energy Fuels. 2014, 28, 7303–7330.
  • Neelakandan, S.; Noel Jacob, K.; Kanagaraj, P.; Sabarathinam, R. M.; Muthumeenal, A. Nagendran, Effect of Sulfonated Graphene Oxide on the Performance Enhancement of Acid–Base Composite Membranes for Direct Methanol Fuel Cells. RSC Adv. 2016, 6, 51599–51608.

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