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Research Article

Sulfonated Poly(Vinyl Alcohol) / Fly Ash Composite Membranes for Polymer Electrolyte Membrane Fuel Cell Applications

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Pages 571-578 | Received 20 Jul 2020, Accepted 09 Nov 2020, Published online: 29 Nov 2020

References

  • Devanathan, R.;. Recent Developments in Proton Exchange Membranes for Fuel Cells. Energy Environ. Sci. 2008, 1, 101–119. DOI: 10.1039/B808149M.
  • Muthu Lakshmi, R. T. S.; Choudhary, V.; Varma, I. K. Sulfonated Poly(ether Ether Ketone): Synthesis and Characterisation. J. Mater. Sci. 2005, 40, 629–636. DOI: 10.1007/s10853-005-6300-2.
  • Deivanayagam, P.; Jaisankar, S. N. Synthesis and Characterization of Composite Membranes Derived from Mono Sulfonated Poly (Ether Sulfone) and Silicotungstic Acid. J. Macromol. Sci. Part A: Pure Appl. Chem. 2012, 49, 1092–1098. DOI: 10.1080/10601325.2012.728490.
  • Vinodh, R.; Purushothaman, M.; Sangeetha, D. Novel Quaternized polysulfone/ZrO2 Composite Membranes for Solid Alkaline Fuel Cell Applications. Int. J. Hydrogen Energy. 2011, 36, 7291–7302. DOI: 10.1016/j.ijhydene.2011.03.056.
  • Muthumeenal, A.; Neelakandan, S.; Kanagaraj, P.; Nagendran, A. Synthesis and Properties of Novel Proton Exchange Membranes Based on Sulfonated Polyethersulfone and N-phthaloyl Chitosan Blends for DMFC Applications. Renew. Energy. 2016, 86, 922–929. DOI: 10.1016/j.renene.2015.09.018.
  • Shen, K.; Dong, B.; Wang, Y.; Lin, L.; Chen, Z. Synthesis and Properties of Sulfonated Poly(arylene Ether Ketone Sulfone) Copolymer. High Perform. Polym. 2016, 28, 315–321. DOI: 10.1177/0954008315580002.
  • Muthumeenal, A.; John Rethinam, A.; Nagendran, A. Sulfonated Polyethersulfone Based Composite Membranes Containing Heteropolyacids Laminated with Polypyrrole for Electrochemical Energy Conversion Devices. Solid State Ionics. 2016, 296, 106–113. DOI: 10.1016/j.ssi.2016.09.010.
  • Vinothkannan, M.; Kim, A. R.; Gnana Kumar, G.; Yoo, D. J. Sulfonated Graphene oxide/Nafion Composite Membranes for High Temperature and Low Humidity Proton Exchange Membrane Fuel Cells. RSC Adv. 2018, 8, 7494–7508. DOI: 10.1039/c7ra12768e.
  • Chen, T. Y.; Leddy, J. Ion Exchange Capacity of Nafion and Nafion Composites. Langmuir. 2000, 16, 2866–2871. DOI: 10.1021/la991094x.
  • Deivanayagam, P.; Ramamoorthy, A. R. Sulfonated Poly(ether Ether Ketone) and Poly(ethylene Glycol) Diacrylate Based Semi-interpenetrating Network Membranes for Fuel Cells. J. Macromol. Sci. Part A: Pure Appl. Chem. 2012, 49, 191–200. DOI: 10.1080/10601325.2012.649197.
  • Divya, K.; Saraswathi, M. S.; Rana, D.; Alwarappan, S.; Nagendran, A. Custom-made Sulfonated Poly (Ether Sulfone) Nanocomposite Proton Exchange Membranes Using Exfoliated Molybdenum Disulfide Nanosheets for DMFC Applications. Polymer. 2018, 147, 48–55. DOI: 10.1016/j.polymer.2018.05.054.
  • Gahlot, S.; Sharma, P. P.; Jha, P. K.; Kulshrestha, V. CNT/SPEEK Nano-Composite Membranes: Toward Improved Properties. Macromol. Symp. 2017, 376, 1700048. DOI: 10.1002/masy.201700048.
  • Kim, A. R.; Park, C. J.; Vinothkannan, M.; Yoo, D. J. Sulfonated Poly Ether Sulfone/heteropoly Acid Composite Membranes as Electrolytes for the Improved Power Generation of Proton Exchange Membrane Fuel Cells. Compos. B. Eng. 2018, 155, 272–281. DOI: 10.1016/j.compositesb.2018.08.016.
  • Lee, S.; Jang, W.; Choi, S.; Tharanikkarasu, K.; Shul, Y.; Han, H. S. Sulfonated Polyimide and Poly(ethylene Glycol) Diacrylate Based semi-Interpenetrating Polymer Network Membranes for Fuel Cells. J. Appl. Polym. Sci. 2007, 104, 2965–2972. DOI: 10.1002/app.25966.
  • Uma Devi, A.; Divya, K.; Abirami Saraswathi, M. S.; Rana, D.; Nagendran, A. Highly Selective and Methanol Resistant Polypyrrole Laminated SPVdF-co-HFP/PWA Proton Exchange Membranes for DMFC Applications. Mater. Chem. Phys. 2018, 212, 533–542. DOI: 10.1016/j.matchemphys.2018.03.086.
  • Mader, J. A.; Benicewicz, B. C. Sulfonated Polybenzimidazoles for High Temperature PEM Fuel Cells. Macromol. 2010, 43, 6706–6715. DOI: 10.1021/ma1009098.
  • Divya, K.; Sri Abirami Saraswathi, M. S.; Alwarappan, S.; Nagendran, A.; Rana, D. Sulfonated Poly (Ether Sulfone)/poly (Vinyl Alcohol) Blend Membranes Customized with Tungsten Disulfide Nanosheets for DMFC Applications. Polymer. 2018, 155, 42–49. DOI: 10.1016/j.polymer.2018.09.010.
  • Poonkuzhali, K.; Berlina, M. M.; Paradesi, D. Novel Cross-linked Poly(vinyl Alcohol)-based Electrolyte Membranes for Fuel Cell Applications. RSC Adv. 2020, 10, 26521–26527. DOI: 10.1039/d0ra04360e.
  • Ajith, C.; Deshpande, A. P.; Varughese, S. Proton Conductivity in Crosslinked Hydrophilic Ionic Polymer System: Competitive Hydration, Crosslink Heterogeneity, and Ineffective Domains. J. Polym. Sci. Part B: Polym. Phys. 2016, 54, 1087–1101. DOI: 10.1002/polb.24012.
  • Dodda, J. M.; lsky, P. B.; Chmelar, J.; Remis, T.; Smolna, K.; Tomas, M.; Kullova, L.; Kadlec, J. Comparative Study of PVA/SiO2 and PVA/SiO2/glutaraldehyde (GA) Nanocomposite Membranes Prepared by Single-step Solution Casting Method. J. Mater. Sci. 2015, 50, 6477–6490. DOI: 10.1007/s10853-015-9206-7.
  • Rudra, R.; Kumar, V.; Pramanik, N.; Kundu, P. P. Graphite Oxide Incorporated Crosslinking Polyvinyl Alcohol and Sulfonated Styrene Nanocomposite Microbial Fuel Cell. J. Power Sources. 2017, 341, 285–293. DOI: 10.1016/j.jpowsour.2016.12.028.
  • Aparicio, G. M.; Vargas, R. A.; Bueno, P. R. Protonic Conductivity and Thermal Properties of Cross-linked PVA/TiO2 Nanocomposite Polymer Membranes. J. Non-cryst. Solids. 2019, 522, 119520–119527. DOI: 10.1016/j.jnoncrysol.2019.119520.
  • Vani, R.; Ramaprabhu, S.; Haridoss, P. Mechanically Stable and Economically Viable Polyvinyl Alcohol-based Membranes with Sulfonated Carbon Nanotubes for Proton Exchange Membrane Fuel Cells. Sustain. Energy Fuels. 2020, 4, 1372–1382. DOI: 10.1039/c9se01031a.
  • Anandan, S.;. Recent Trends in Fly Ash Utilization in Polymer Composites. Int. J. Waste Resour. 2014, 4(3), 1000149. DOI: 10.4172/2252-5211.1000149.
  • Paradesi, D.; Gandhimathi, S.; Krishnan, H.; Baskar, B.; Senthil Andavan, G. T. Energy Material - the Role of Silicotungstic Acid and Fly Ash in Sulfonated Poly(ether Sulfone) Composites for PEMFC Applications. J. Macromol. Sci. Part A: Pure Appl. Chem. 2019, 56(2), 146–152. DOI: 10.1080/10601325.2018.1552080.
  • Gandhimathi, S.; Krishnan, H.; Paradesi, D.; Jeyalakshmi, R. High Performance SPEEK/SWCNT/fly Ash Polymer Electrolyte Nanocomposite Membranes for Fuel Cell Applications. Polym. J. 2017, 49, 703–709. DOI: 10.1038/pj.2017.38.
  • Vetrivel, M.; Abirami Saraswathi, M. S.; Rana, D.; Nagendran, A. Fabrication of Cellulose Acetate Nanocomposite Membranes Using 2D-layered Nanomaterials for Macromolecular Separations. Int. J. Biol. Macromol. 2018, 107, 1607–1612. DOI: 10.1016/j.ijbiomac.2017.10.027.

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