Alkylation, Hydrogenation and Oxidation Catalyzed by Mesoporous Materials

References

• Kresge , C. Y. , Leonowiez , M. E. , Roth , W. J. , Vartuli , J. C. and Beck , J. S. 1992 . Ordered mesoporous molecular sieves synthesized by a liquid crystal template method . Nature , 359 : 710 – 712 .
   Web of Science ®Google Scholar
• Trong , D. , On , D. D. , Danumah , C. and Kaliaguine , S. 2001 . Perspectives in catalytic applications of mesostructured materials . Applied Catal. A , 222 : 299 – 357 .
   Web of Science ®Google Scholar
• Biz , S. and Occelli , M. L. 1998 . Synthesis and characterization of mesostructured materials . Catal. Rev. Sci. Engr. , 40 ( 3 ) : 329 – 407 .
   Web of Science ®Google Scholar
• Perego , C. and Ingallina , P. 2002 . Recent advances in the industrial alkylation of aromatics: new catalysts and new processes . Catal. Today , 73 : 3 – 22 .
   Web of Science ®Google Scholar
• Corma , A. 1997 . From microporous to mesoporous materials and their use in catalysis . Chem. Rev. , 97 : 2373 – 2419 .
   PubMed Web of Science ®Google Scholar
• Brunel , D. , Blanc , A. C. , Galarneau , A. and Fajula , F. 2002 . New trends in the design of supported catalysts on mesoporous silicas and their applications in fine chemicals . Catal. Today , 73 : 139 – 152 .
   Web of Science ®Google Scholar
• Corma , A. and Garcia , H. 1997 . Organic reactions catalyzed over solid acids . Catal. Today , 38 : 257 – 308 .
   Web of Science ®Google Scholar
• Viswanathan , B. 2000 . Catalytic alkylation of aromatic substrates—Part II . Bull. Catal. Soc. India , 10 ( 1 )
   Google Scholar
• Venuto , P. B. , Hamilton , L. A. , Landis , P. S. and Wise , J. J. 1966 . Organic reactions catalyzed by crystalline aluminosilicates . J. Catal. , 5 : 81 – 98 .
   Web of Science ®Google Scholar
• Wight , C. G. US Patent 4,169,111 . 1979 . Union Oil Company of California
   Google Scholar
• Bellusi , G. , Pazzuconi , G. , Perego , C. , Girotti , G. and Terzoni , G. 1995 . Liquid‐phase alkylation of benzene with light olefins catalyzed by β‐zeolites . J. Catal. , 157 : 227 – 234 .
   Web of Science ®Google Scholar
• Forni , L. , Cremona , G. , Missineo , F. , Bellusi , G. , Perego , C. and Pazzuconi , G. 1995 . Transalkylation of m‐diethylbenzene over large‐pore zeolites . Appl. Catal. A , 121 : 261 – 272 .
   Web of Science ®Google Scholar
• Shinae , J. and Ryoo , R. 2000 . Aluminum impregnation into mesoporous silica molecular sieves for catalytic application to Friedel‐Crafts alkylation . J. Catal. , 195 : 237 – 243 .
   Web of Science ®Google Scholar
• Valtierra , J. M. , Zaldivar , O. , Sanchez , M. A. , Montoya , J. A. , Juan navarrete and de Los Reyes , J. A. 1998 . Selectivity to cumene in the alkylation of benzene with isopropanol on a MCM‐41/γ‐Al2O3 catalyst . Applied Catal. A , 166 : 387 – 392 .
   Web of Science ®Google Scholar
• Okumura , K. , Nishigaki , K. and Niwa , M. 2001 . Prominent catalytic activity of Ga‐containing MCM‐41 in the Friedel‐Crafts alkylation . Micro. Meso. Mater. , 44 : 509 – 516 .
   Web of Science ®Google Scholar
• He , N. , Bao , S. and Xu , Q. 1998 . Fe‐containing mesoporous molecular sieves materials: very active Friedel–Crafts alkylation catalysts . Applied Catal. A , 169 : 29 – 36 .
   Web of Science ®Google Scholar
• Righter , E. G. , Tzou , M. S. and Pinnavaia , T. J. 1991 . Iron oxide pillard clay with large gallery height: synthesis and preparation as a Fischer–Tropsch catalyst . J. Catal. , 130 : 29 – 40 .
   Web of Science ®Google Scholar
• Choudary , B. M. , Kantam , M. L. , Sateesh , M. , Rao , K. K. and Santhi , P. I. 1997 . Iron pillared clays—efficient catalysts for Friedel–Crafts reactions . Appl. Catal. A , 149 : 257 – 264 .
   Web of Science ®Google Scholar
• Choudary , V. R. , Jana , S. K. and Kiran , B. P. 2000 . Highly active and moisture‐ insensitive solid catalysts—GaCl3 and InCl3 supported on montmorillonite‐K10 and Si‐MCM‐41 for benzylation of benzene . Catal. Lett. , 64 ( 2 ) : 223 – 226 .
   Web of Science ®Google Scholar
• Miller , J. M. , Wails , D. , Hartman , J. S. , Schebesh , K. and Belelie , J. L . 1998 . Friedel–Crafts catalysts using supported reagents: synthesis, characterization and catalytic application of sol‐gel derived silica . Canadian J. Chem. , 76 ( 4 ) : 382 – 388 .
   Web of Science ®Google Scholar
• Bachari , K. , Millet , J. M.M. , Benaïchouba , B. , Cherifi , O. and Figueras , F. 2004 . Benzylation of benzene by benzyl chloride over iron mesoporous molecular sieves materials . Journal of Catalysis , 221 : 55 – 61 .
   Web of Science ®Google Scholar
• Frank , H. G. and Stadelhofer , J. W. 1988 . Industrial Aromatic Chemistry Berlin : Springer .
   Google Scholar
• Sivasanker , S. and Thangaraj , A. 1992 . J. Catal. , 138 : 386
   Web of Science ®Google Scholar
• Berna Tejero , J. L. and Danvila , A. M. US Patent 5,146,026 . 1992 . Petroquimica Espanola, S.A.Petresa
   Google Scholar
• Clark , J. H. , Monks , G. L. , Nightingale , D. J. , Price , P. M. and White , J. F. 2000 . A new solid acid‐based route to linear alkylbenzenes . J. Catal. , 193 : 348 – 350 .
   Web of Science ®Google Scholar
• Climent , M. J. , Corma , A. , Iborra , S. , Miquel , S. , Primo , J. and Rey , F. 1999 . Mesoporous materials as catalysts for the production of chemicals: Synthesis of alkyl glucosides on MCM‐41 . J. Catal. , 183 : 76 – 82 .
   Web of Science ®Google Scholar
• der Heijden , A. M. , Van Rantwij , K. F. and Van Bekkam , H. 1999 . MCM‐41 materials as catalysts for the synthesis of alkyl fructosides . J. Carbohydr. Chem. , 18 ( 2 ) : 131 – 147 .
   Web of Science ®Google Scholar
• Chuah , L. X. and Jaenicke , S. 1999 . Base‐functionalized MCM‐41 as catalysts for the synthesis of monoglycerides . J. Mol. Catal. A , 150 : 287 – 294 .
   Google Scholar
• Chuah , G. K. , Hu , X. , Zhan , P. and Jaenicke , S. 2002 . Catalysts from MCM‐41: framework modification, pore size engineering, and organic‐inorganic hybrid materials . J. Mol. Cat. A , 181 : 25 – 31 .
   Google Scholar
• Xucan , H. , Foo , M. L. , Chuah , G. K. and Jaenicke , S. 2000 . Pore size engineering on MCM‐41: Selectivity Tuning of Heterogenized AlCl3 for the Synthesis of Linear Alkyl benzenes . J. Catal. , 195 : 412 – 415 .
   Web of Science ®Google Scholar
• Kodenev , E. G. , Shmakov , A. N. , Yu Derevyankin , A. , Lapina , O. P. and Romannikov , V. N. 2000 . Highly‐ordered aluminosilicate mesoporous mesophase materials: physico‐chemical properties and catalytic behaviour . J. Mol. Catal. , 158 : 349 – 354 .
   Google Scholar
• Perego , C. , Amarilli , S. , Carati , A. , Flego , C. , Pazzuconi , G. , Rizzo , C. and Bellussi , G. 1999 . Mesoporous silica‐aluminas as catalysts for the alkylation of aromatic hydrocarbons with olefins . Micropor. Mesopor. Mater. , 27 : 345 – 354 .
   Web of Science ®Google Scholar
• Hu , X. , Chuah , G. K. and Jaenicke , S. 2001 . Solid acid catalysts for the efficient synthesis of 2‐(2,4‐difluorophenyl) propane . Appl. Catal. A. Gen. , 209 : 117 – 123 .
   Web of Science ®Google Scholar
• Hu , X. , Chuah , G. K. and Jaenicke , S. 2001 . Room temperature synthesis of diphenylmethane over MCM‐41 supported AlCl3 and other Lewis acids . Appl. Catal. A , 217 : 1 – 9 .
   Web of Science ®Google Scholar
• Hu , X. , Chuah , G. K. and Jaenicke , S. 2002 . Liquid‐phase regioselective benzylation of bromobenzene and other aromatics over microporous zeolites . Micropor. Mesopor. Mater. , 53 : 153 – 161 .
   Web of Science ®Google Scholar
• Misono , M. and Nojiri , N. 1990 . Recent progress in catalytic technology in Japan . Appl. Catal. , 64 ( 1 ) : 1
   Google Scholar
• Pizzio , L. R. , Caceres , C. V. and Blanco , M. N. 1998 . Acid catalysts prepared by impregnation of tungstophosphoric acid solutions on different supports . Appl. Catal. A , 167 : 283 – 294 .
   Web of Science ®Google Scholar
• Kozhevnikov , I. V. , Sinnema , A. , Jansen , R. J.J. , Pamin , K. and Van Bekkum , H. 1995 . New acid catalysts comprising heteropoly acid on a mesoporous molecular sieve MCM‐41 . Catal. Lett. , 30 ( 1–4 ) : 241 – 252 .
   Web of Science ®Google Scholar
• Kozhenivkov , I. V. , Kloetstra , K. R. , Sinnema , A. , Zandbergen , H. W. and van Bekkum , H. 1996 . Study of catalysts comprising heteropoly acid H3PW12O40 supported on MCM‐41 molecular sieve and amorphous silica . J. Mol. Catal. A , 114 : 287 – 298 .
   Google Scholar
• Blasco , T. , Corma , A. , Martinez , A. and Martinez‐Escolano , P. 1998 . Supported heteropolyacid (HPW) catalysts for the continuous alkylation of isobutane with 2‐butene: The benefit of using MCM‐41 with larger pore diameters . J. Catal. , 177 : 306 – 313 .
   Web of Science ®Google Scholar
• Kresge , C. T. , Marler , D. S. , Rav , G. S. and Rose , R. H. US Patent 5366945 . 1994 .
   Google Scholar
• Choi , S. , Wang , Y. , Nie , Z. , Liu , J. and Peden , C. H.F. 2000 . Cs‐substituted tungstophosphoric acid salt supported on mesoporous silica . Catal. Today , 55 : 117 – 124 .
   Web of Science ®Google Scholar
• Soled , S. , Miseo , S. , Mc Vicker , G. , Gates , W. E. , Gutierrez , A. and Paes , J. 1997 . Preparation of bulk and supported heteropoly acid salts . Catal. Today , 36 : 441 – 450 .
   Web of Science ®Google Scholar
• Cejka , J. , Krejci , A. , Zilkova , N. , Dedecek , J. and Hanika . 2001 . Alkylation and disproportionation of aromatic hydrocarbons over mesoporous molecular sieves . J. Micropor. Mesopor. Mater. , 44–45 : 499 – 507 .
   Web of Science ®Google Scholar
• Misono , M. and Okuhara , T. 1993 . Chemtech. , 11 : 23
   Google Scholar
• Parikh , P. A. , Subrahmanyam , N. , Bhat , Y. S. and Halgen , A. B. 1992 . Toluene isopropylation over zeolite β and metallosilicates of MFI structure . Appl. Catal. A , 90 : 1 – 10 .
   Web of Science ®Google Scholar
• Selvaraj , M. , Pandurangan , A. , Seshadri , K. S. , Sinha , P. K. , Krishnasamy , V. and Lal , K. B. 2002 . Comparison of mesoporous Al‐MCM‐41 molecular sieves in the production of p‐cymene for isopropylation of toluene . J. Mol. Catal. A: Chem. , 186 : 173 – 186 .
   Google Scholar
• Thomas , J. M. 1998 . Angew. Chem. Int. Ed. Engl. , 27 : 1673
   Google Scholar
• Kim , J. H. , Sugi , Y. , Matsuzaki , T. , Hanoaka , T. , Kubota , Y. , Tu , X. and Matsumato , M. 1995 . Effect of SiO2/Al2O3 ratio of H‐mordenite in the isopropylation of naphthalene with propylene . Microporous Mater. , 5 ( 3 ) : 113 – 121 .
   Google Scholar
• Moreau , P. , Finiels , A. , Geneste , P. , Joffre , J. , Moreau , F. and Solofo , J. 1996 . Selective dialkylation of naphthalene with hindered alkylating agents over HM and HY zeolites under liquid phase conditions . Catal. Today , 31 : 11 – 17 .
   Web of Science ®Google Scholar
• Reddy , K. M. and Song , C. 1996 . Synthesis of mesoporous zeolites and their application for catalytic conversion of polycyclic aromatic hydrocarbons . Catal. Today , 31 : 137 – 144 .
   Web of Science ®Google Scholar
• Sugi , Y. and Toba , M. 1994 . Chapter 7, Shape‐selective alkylation of polynuclear aromatics . Catal. Today , 19 : 187 – 211 .
   Web of Science ®Google Scholar
• Fraenkel , N. , Cherniavsky , M. , Ittah , B. and Levy , M. 1986 . Shape selective alkylation of naphthalene and methylnaphthalene with methanol over H‐ZSM‐5 zeolite catalysts . J. Catal. , 191 : 273 – 283 .
   Google Scholar
• Cusumano , J. A. 1992 . Chemtech. , : 482
   Google Scholar
• Zhao , X. S. , Lu , G. Q. and Song , C. 2003 . Immobilization of aluminum chloride on MCM‐41 as a new catalyst system for liquid‐phase isopropylation of naphthalene . J. Mol. Catal. A: Chem. , 191 : 67 – 74 .
   Google Scholar
• Chakraborthy , B. , Pulikkottil , A. C. and Viswanathan , B. 1996 . Alkylation of naphthalene with alcohols over mesoporous MCM‐41 . Catal. Lett. , 39 : 63
   Web of Science ®Google Scholar
• Kamalakar , G. , Prasad , M. R. , Kulkarni , S. J. , Narayanan , S. and Raghavan , K. V. 2000 . Vapor phase ethylation of naphthalene with ethanol over molecular sieve catalysts . Micropor. Mesopor. Mater. , 38 : 135 – 142 .
   Web of Science ®Google Scholar
• Kamalakar , G. , Kulkarni , S. J. , Raghavan , K. V. , Unnikrishnan , S. and Halgeri , A. B. 1999 . Isopropylation of naphthalene over modified HMCM‐41, HY and SAPO‐5 catalysts . J. Mol. Catal. A: Chem. , 149 : 283 – 288 .
   Google Scholar
• Kamalakar , G. , Prasad , M. R. , Kulkarni , S. J. and Raghavan , K. V. 2002 . Vapour phase tert‐butylation of naphthalene over molecular sieve catalysts . Micropor. Mesopor. Mater. , 52 : 151 – 158 .
   Web of Science ®Google Scholar
• Armengol , E. , Corma , A. , Garcia , H. and Primo , J. 1997 . Acid zeolites as catalysts in organic reactions. tert‐Butylation of anthracene, naphthalene and thianthrene . Appl. Catal. A: Gen. , 149 : 411 – 423 .
   Web of Science ®Google Scholar
• Sakthivel , A. , Badamali , S. K. and Selvam , P. 2000 . para‐Selective t‐butylation of phenol over mesoporous H‐AlMCM‐41 . Micropor. Mesopor. Mater. , 39 : 457 – 463 .
   Web of Science ®Google Scholar
• Badamali , S. K. , Sakthivel , A. and Selvam , P. 2000 . Influence of aluminium sources on the synthesis and catalytic activity of mesoporous AlMCM‐41 molecular sieves . Catal. Today , 63 : 291 – 295 .
   Web of Science ®Google Scholar
• Sakthivel , A. and Selvam , P. 2002 . Vapor‐phase tertiary butylation of phenol over mesoporous gallosilicate molecular sieves . Cat. Lett. , 84 ( 1–2 ) : 37 – 43 .
   Web of Science ®Google Scholar
• Savidha , R. , Pandurangan , A. , Palanichamy , M. and Murugesan , V. 2004 . A comparative study on the catalytic activity of Zn and Fe containing Al‐MCM‐41 molecular sieves on the vapour phase tertiary butylation of phenol . Journal of Molecular Catalysis A: Chem. , 211 : 165 – 177 .
   Google Scholar
• Bhattacharyya , K. G. , Taludkar , A. K. , Das , P. and Sivasanker , S. 2003 . Al‐MCM‐41 catalysed alkylation of phenol with methanol . J. Mol. Catal. A: Chem. , 197 ( 1–2 ) : 255 – 262 .
   Google Scholar
• Landau , M. V. , Dafa , E. , Kaliya , M. L. , Sen , T. and Herskowitz , M. 2001 . Mesoporous alumina catalytic material prepared by grafting wide‐pore MCM‐41 with an alumina multiplayer . Micropor. Mesoporous Mater. , 49 : 65 – 81 .
   Web of Science ®Google Scholar
• Armengol , E. , Cano , M. L. , Corma , A. , Garcia , H. and Navarro , M. T. 1995 . Mesoporous aluminosilicate MCM‐41 as a convenient catalyst for Friedel‐Crafts alkylation of a bulky aromatic compound with cinnamyl alcohol . J. Chem. Soc. Chem. Commun. , : 519 – 520 .
   Google Scholar
• Tismaneanu , R. , Ray , B. , Khalfin , R. , Semiat , R. and Eisen , M. S. 2001 . Synthesis, characterization and catalytic activity of actinide Th‐MCM‐41 and U‐MCM‐41 hexagonal packed mesoporous molecular sieves . J. Mol. Catal. A: Gen. , 171 : 229 – 241 .
   Web of Science ®Google Scholar
• Wang , Y. , Kim , A. Y. , Li , S. , Wang , L.‐Q. , Peden , C. H.F. and Bunker , B. C. 2000 . Shape selective solid acid catalysts based on tunstophosphoric acid supported on mesoporous silica . ACS Symp. Ser. , 738 : 353 – 368 .
   Google Scholar
• Umamaheswary , V. , Palanichamy , M. , Arabindoo , B. and Murugesan , V. 2000 . Regioselective ter‐butylation of m‐cresol over mesoporous Al‐MCM‐41 molecular sieves . Indian J. of Chemistry , 39A ( 12 ) : 1241 – 1247 .
   Google Scholar
• Chen , L. W. , Chou , C. Y. and Ko , A. N. 1999 . Novel efficient synthesis of β‐naphthyl methyl ether using sulfated mesoporous molecular sieve Al‐MCM‐41 . Appl. Catal. A: Gen. , 178 : L1 – L6 .
   Web of Science ®Google Scholar
• Process for the preparation of alkylglycosides . Patent No: WO 96136640 . 1996 . Technische Universiteit Delft (applicant)
   Google Scholar
• Rylander , R. N. 1979 . Catalytic Hydrogenation in Organic Synthesis New York : Academic Press .
   Google Scholar
• March , J. 1985 . Advanced Organic Chemistry , 3rd Ed. New York : Wiley‐Interscience .
   Google Scholar
• Chou , P. and Vannice , M. A. 1987 . Benzene hydrogenation over supported and unsupported palladium . J. Catal. , 107 : 129 – 139 .
   Web of Science ®Google Scholar
• Cherkashin , G. M. , Shuikina , L. P. , Parengo , O. P. and Frilov , V. M. 1985 . Kinet. Katal. , 26 : 1110
   Google Scholar
• Argentiere , P. L.L. , Liprandi , D. A. , Marconetti , D. V. and Figoli , N. S. 1997 . High active, selective and sulfur resistant supported palladium tetra‐coordinated complex as catalyst in the selective hydrogenation of styrene . J. Mol. Catal. , 118 : 341 – 348 .
   Google Scholar
• Mathew , J. P. and Srinivasan , M. 1995 . Photo electron spectroscopy (XPS) studies on some palladium catalysts . Eur. Polym. J. , 31 ( 9 ) : 835 – 839 .
   Web of Science ®Google Scholar
• Raja , R. and Thomas , J. M. 2002 . Catalyst design strategies for controlling reactions in microporous and mesoporous molecular‐sieves . J. Mol. Cat. A: Chem. , 181 : 3 – 14 .
   Web of Science ®Google Scholar
• Vanmeertan , R. Z.C. and Coenen , J. W.E. 1975 . Gas phase benzene hydrogenation on a nickel‐silica catalyst . J. Catal. , 37 : 37 – 43 .
   Web of Science ®Google Scholar
• Martin , G. A. and Dalmon , J. A. 1982 . Benzene hydrogenation over nickel catalysts at low and high temperature: structure sensitivity and Cu alloying effects . J. Catal. , 75 : 233 – 242 .
   Web of Science ®Google Scholar
• Lefondeur , S. , Monteverdi , S. , Molina , S. , Bettahar , S. and Fort , Y. 2001 . Ni nanoparticles inserted in tBuONa matrix deposited on alumina: part.11: Thermal treatment and Ni content effects on their stability and catalytic activity . J. Mater. Sci. , 36 ( 11 ) : 2633 – 2638 .
   Web of Science ®Google Scholar
• Richardson , J. T. 1971 . Dual functional activities in nickel acid catalysts . J. Catal. , 21 : 122 – 129 .
   Web of Science ®Google Scholar
• Lewandowska , A. , Monteverdi , S. , Bettahar , M. and Ziolek , M. 2002 . MCM‐41 mesoporous molecular sieves supported nickel—physico‐chemical properties and catalytic activity in hydrogenation of benzene . J. Mol. Catal. A: Chem. , 188 : 85 – 95 .
   Google Scholar
• Peng , T. , Blanchard , J. , Fajerwerg , K. , Breysse , M. , Vrinat , M. and Zhongmin , L. 2003 . Preparation of Ru metal nanoparticles in mesoporous materials: influence of sulfur on the hydrogenating activity . Microporous and Mesoporous Materials , 60 : 197 – 206 .
   Web of Science ®Google Scholar
• Mandreoli , M. , Vaccari , A. , Veggetti , E. , Jacquin , M. , Jones , D. J. and Roziere , J. 2002 . Vapour phase hydrogenation of naphthalene on a novel Ni‐containing mesoporous aluminosilicate catalyst . Appl. Catal. A: Gen. , 231 : 263 – 268 .
   Web of Science ®Google Scholar
• Albertazzi , S. , Ganzerla , R. , Gobbi , C. , Lenarda , M. , Mandreoli , M. , Salatelli , E. , Savini , P. , Storato , L. and Vaccari , A. 2003 . Hydrogenation of naphthalene on noble‐metal‐containing mesoporous MCM‐41 aluminosilicates . J. Mol. Cat. A: Chem. , 200 : 261 – 270 .
   Google Scholar
• Castellon , E. R. , Diaz , L. , Garcia , P. B. , Robles , J. M. , Torres , P. M. , Lopez , A. J. and Vaccari , A. 2002 . Nickel impregnated zirconium doped mesoporous molecular sieves as catalysts for the hydrogenation and ring opening of tetralin . Appl. Catal. A: Gen. , 6222 : 1 – 12 .
   Google Scholar
• Pasto , D. J. 1979 . J. Am. Chem. Soc. , 101 : 6852
   Web of Science ®Google Scholar
• Mohapatra , S. K. , Sonavane , S. U. , Jayaram , R. V. and Selvam , P. 1979 . Heterogeneous catalytic transfer hydrogenation of aromatic nitro and carbonyl compounds over Co(II) substituted hexagonal mesoporous aluminophosphate molecular sieves . Tetrahedron Lett. , 43 ( 47 ) : 8527 – 8529 .
   Google Scholar
• Choudary , B. M. , Kantam , M. L. , Reddy , N. M. , Koteswara Rao , K. , Haritha , Y. , Bhaskar , V. , Figueras , F. and Tuel , A. 1999 . Hydrogenation of acetylenics by Pd‐exchanged mesoporous materials . Appl. Catal. A: Gen. , 181 : 139 – 144 .
   Web of Science ®Google Scholar
• Card , R. J. , Liesner , C. E. and Neckers , D. C. 1979 . Poly(styryl) bipyridinepalladium complexes as heterogeneous catalysts for hydrogenation of alkenes and alkynes . J. Org. Chem. , 44 ( 7 ) : 1095 – 1098 .
   Web of Science ®Google Scholar
• Choudary , B. M. , Ravikumar , K. and Lakshmi Kantam , M. 1991 . Synthesis and catalytic activity in selective hydrogenation of palladium complexes anchored in montmorillonite . J. Catal. , 130 : 41 – 51 .
   Web of Science ®Google Scholar
• Choudary , B. M. and Bharati , P. 1987 . Synthesis of interlamellar montmorillonite bipyridinepalladium(II) catalysts: The first example of chelation in smectite clay . J. Chem. Soc. Chem. Commun. , : 1505 – 1506 .
   Google Scholar
• De Bellefon , C. and Fouillox , P. 1994 . Homogeneous and heterogeneous hydrogenation of nitriles in liquid phase: chemical, mechanistic and catalytic approach . Catal. Rev. Sci. Eng. , 36 : 459 – 506 .
   Web of Science ®Google Scholar
• Volf , J. , Pasek , J. and Cerveny . 1986 . Stu. Surf. Sci. Catal. , 27 : 105 Ed
   Google Scholar
• Garcia , P. B. , Torres , P. M. , Castellon , E. R. and Lopez , A. J. 2002 . J. Mol. Catal. A: Chem. , 3774 : 1
   Google Scholar
• Yan Huang , Y. and Sachtler , W. M.H. 1997 . The effect of catalyst pore structure on liquid phase catalysis: Hydrogenation of stearonitrile over ruthenium supported on mesoporous sulfated zirconia . Appl. Catal. A: Gen. , 163 : 245 – 254 .
   Web of Science ®Google Scholar
• Iglesia , E. 1997 . Design, synthesis, and use of cobalt‐based Fischer‐Tropsch synthesis catalysts . Appl. Catal. A , 161 : 59 – 78 .
   Web of Science ®Google Scholar
• Dry , M. E. 1990 . The Fischer–Tropsch process—commercial aspects . Catal. Today , 6 : 183 – 206 .
   Google Scholar
• Kraum , M. and Baerns , M. 1999 . Fischer–Tropsch synthesis: the influence of various cobalt compounds applied in the preparation of supported cobalt catalysts on their performance . Appl. Catal. A: Gen. , 186 : 189 – 200 .
   Web of Science ®Google Scholar
• Iglesia , E. , Soled , S. L. and Fiato , R. A. 1995 . Bimetallic synergy in cobalt ruthenium Fischer–Tropsch synthesis catalysts . J. Catal. , 143 : 345 – 368 .
   Web of Science ®Google Scholar
• Corma , A. , Martines , V. and Soria , V. 1997 . Hydrogenation of aromatics in diesel fuels on Pt/MCM‐41 catalysts . J. Catal. , 169 : 480 – 489 .
   Web of Science ®Google Scholar
• Song , C. and Reddy , K. M. 1999 . Mesoporous molecular sieve MCM‐41 supported Co–Mo catalyst for hydrodesulfurization of dibenzothiophene in distillate fuels . Appl. Catal. A , 176 : 1 – 10 .
   Web of Science ®Google Scholar
• Schuth , F. , Wingen , A. and Sauer . 2001 . Oxide loaded ordered mesoporous oxides for catalytic applications . J. Micropor. Mesopor. Mater. , 465 : 465 – 476 .
   Google Scholar
• Adasina , A. A. 1996 . Hydrocarbon synthesis via Fischer–Tropsch reaction: travails and triumphs . Appl. Catal. A , 138 : 345 – 367 .
   Web of Science ®Google Scholar
• Yin , D. , Li , W. , Yang , W. , Xiang , H. , Sun , Y. , Zhong , B. and Peng , S. 2001 . Mesoporous HMS molecular sieves supported cobalt catalysts for Fischer–Tropsch synthesis . Micropor. Mesopor. Mater. , 47 : 15 – 24 .
   Web of Science ®Google Scholar
• Tanev , P. T. , Chibwe , M. and Pinnavaia , T. J. 1994 . Nature , 368 : 317
   Web of Science ®Google Scholar
• Panpranot , J. Jr. and Sayari , A. 2002 . CO hydrogenation on Ru‐promoted Co/MCM‐41 catalysts . J. Catal. , 211 : 530 – 539 .
   Web of Science ®Google Scholar
• Iwasaki , T. , Reinikainen , M. , Onodera , Y. , Hayashi , H. , Ebina , T. , Nagase , T. , Torilli , K. , Kataja , K. and Chatterjee , A. 1998 . Use of silicate crystalline mesoporous material as catalyst support for Fischer–Tropsch reaction . Appl. Surf. Science , 130 : 845 – 850 .
   Web of Science ®Google Scholar
• Corma , A. , Iglesia , M. , Mohino , F. and Sanchez , F. 1997 . Heterogenized catalysts on zeolites: synthesis of new chiral Rh(I) complexes with (2S,4R)‐trans‐4‐RCOO‐2‐(t‐butylaminocarbonyl)pyrrolidines and (2S,4S)cis‐4‐RCONH‐2‐(t‐ butylaminocarbonyl). Heterogenization of silica and a USY zeolite and study of the role of support on their catalytic profile in hydrogenation of olefins . J. Organomet. Chem. , 544 ( 2 ) : 147 – 156 .
   Google Scholar
• Shimazu , S. , Ro , K. , Sento , T. , Ichikuni , N. and Uematsu , T. 1996 . Asymmetric hydrogenation of α,β‐unsaturated carboxylic acid esters by rhodium(I)‐phosphine complexes supported on smectites . J. Mol. Catal. A: Chem. , 107 : 297 – 303 .
   Google Scholar
• Pu , L. 1999 . Rigid and sterically regular chiral 1,1′‐binaphthylpolymers in asymmetric catalysis . Chem. Eur. J. , 5 ( 8 ) : 2227 – 2232 .
   Web of Science ®Google Scholar
• Jamis , J. , Anderson , J. R. , Dickson , R. S. , Campi , E. M. and Jackson , W. R. 2000 . Aqueous enantioselective hydrogenation involving silica heterogenized catalysts . J. Org. Metallic. Chem. , 603 ( 1 ) : 80 – 85 .
   Google Scholar
• Jamis , J. , Anderson , J. R. , Dickson , R. S. , Campi , E. M. and Jackson , W. R. 2001 . Modified silica heterogenized catalysts for use in aqueous enantioselective hydrogenations . J. Org. Metallic. Chem. , 627 ( 1 ) : 37 – 43 .
   Google Scholar
• Blaser , H. U. , Honig , H. , Studer , M. and Wedemeyer‐Exl , C. 1999 . Enantioselective synthesis of ethyl nipecotinate using cinchona modified heterogeneous catalysts . J. Mol. Catal. A: Gen. , 139 : 253 – 257 .
   Google Scholar
• Johnson , B. F.G. , Raynor , S. A. , Shephard , D. S. , Mashmeyer , T. , Thomas , J. M. , Sankar , G. , Bromley , S. , Oldroyd , R. , Gladden , L. and Mantle , M. D. 1999 . Superior performance of a chiral catalyst confined within mesoporous silica . Chem. Commun. , : 1167 – 1168 .
   Web of Science ®Google Scholar
• Burch , R. , Caps , V. , Gleeson , D. , Nishiyama , S. and Tsang , S. C. 2000 . Nanoscopic tin‐oxygen linings on mesoporous silica as a novel catalyst for organic hydrogen transfer reaction . Appl. Catal. A: Gen. , 194–195 : 297 – 307 .
   Web of Science ®Google Scholar
• Coman , S. , Parvulescu , V. I. , Tesche , B. , Bonnemann , H. , Roux , J. F. , Kaliaguine , S. and Jacobs , P. A. 1999 . Stereocontrolled hydrogenation of prostaglandin intermediates over Ru‐MCM‐41 catalysts . J. Mol. Catal. A: Chem. , 146 : 247 – 256 .
   Google Scholar
• Clerici , M. G. 2000 . Zeolite catalysts for fine chemical production . Topics Catal. , 13 ( 4 ) : 373 – 386 .
   Web of Science ®Google Scholar
• Arends , I. W.C.E. and Sheldon , R. A. 2001 . Activities and stabilities of heterogeneous catalysts in selective liquid phase oxidations: recent developments . Appl. Catal. A: Gen. , 212 : 175 – 187 .
   Web of Science ®Google Scholar
• Sheldon , R. A. and Dakka , J. 1994 . Heterogeneous catalytic oxidations in the manufacture of fine chemicals . Catal. Today , 19 : 215 – 245 .
   Web of Science ®Google Scholar
• Centi , G. and Misono , M. 1998 . New possibilities and opportunities for basic and applied research on selective oxidation by solid catalysts: an overview . Catal. Today , 41 : 287 – 296 .
   Web of Science ®Google Scholar
• Rafelt , J. S. and Clark , J. H. 2000 . Recent advances in the partial oxidation of organic molecules using heterogeneous catalysis . Catal. Today , 57 : 33 – 34 .
   Web of Science ®Google Scholar
• Jentys , A. , Pham , N. H. , Vinek , H. , Englisch , M. and Lercher , J. A. 1996 . Synthesis and characterization of mesoporous materials containing highly dispersed cobalt . Microporous Mater. , 6 ( 1 ) : 13 – 17 .
   Google Scholar
• Blasco , T. , Corma , A. , Navarro , M. T. and Pérez Pariente , J. 1995 . Synthesis, characterization and catalytic activity of Ti‐MCM‐41 structures . J. Catal. , 156 : 65 – 74 .
   Web of Science ®Google Scholar
• Oldroyd , R. D. , Thomas , J. M. , Maschmeyer , T. , MacFaul , P. A. , Snelgrove , D. W. , Ingold , K. U. and Wayner , D. D.M. 1996 . The Ti(IV) catalyzed epoxidation of alkenes by tert‐alkyl hydroperoxides . Angew. Chem. Int. Ed. Engl. , 35 ( 23–24 ) : 2787 – 2790 .
   Web of Science ®Google Scholar
• Carvalho , W. A. , Varaldo , P. B. , Wallau , M. and Schuchardt , U. 1997 . Mesoporous redox molecular sieves analogous to MCM‐41 . Zeolites , 18 ( 5,6 ) : 408 – 416 .
   Google Scholar
• Tuel , A. 1999 . Modification of mesoporous silicas by incorporation of heteroelements in the framework . Micropor. Mesopor. Mater. , 27 : 151 – 169 .
   Web of Science ®Google Scholar
• Zho , D. , Goldfarb , D. , Bonneviot , L. and Kaliaguine , S. 1995 . Zeolites: A Refined Tool for Designing Catalytic Sites Edited by: Zho , D. , Goldfarb , D. , Bonneviot , L. and Kaliaguine , S. 181 Amsterdam : Elsevier .
   Google Scholar
• Arnold , A. J.J. , Niederer , J. P.M. , Nießen , T. E.W. and Hölderich , W. F. 1999 . The influence of synthesis parameters on the vanadium content and pore size of [V]‐MCM‐41 materials . Micropor. Mesopor. Mater. , 28 : 353 – 360 .
   Web of Science ®Google Scholar
• Hartmann , M. , Racouchot , S. and Bischof , C. 1999 . Characterization of copper and zinc containing MCM‐41 and MCM‐48 mesoporous molecular sieves by temperature programmed reduction and carbon monoxide adsorption . Micropor. Mesopor. Mater. , 27 : 309 – 320 .
   Web of Science ®Google Scholar
• Suvanto , S. , Hukkamäki , J. , Pakkanen , T. T. and Pakkanen , T. A. 2000 . High cobalt loaded MCM‐41 via the gas‐phase method . Langmuir , 16 ( 9 ) : 4109 – 4115 .
   Web of Science ®Google Scholar
• Carvalho , W. A. , Wallau , M. and Schuchardt , U. 1999 . Iron and copper immobilised on mesoporous MCM‐41 molecular sieves as catalysts for the oxidation of cyclohexane . J. Mol. Catal. A , 144 : 91 – 99 .
   Google Scholar
• Dusi , M. , Mallat , T. and Baiker , A. 2000 . Epoxidation of functionalized olefins over solid catalysts . Catal. Rev.‐Sci. Eng. , 42 ( 1,2 ) : 213 – 278 .
   Web of Science ®Google Scholar
• Hari Prasad Rao , P. R. , Ramaswamy , A. V. and Ratnasamy , P. 1992 . J. Catal. , 137 : 225
   Web of Science ®Google Scholar
• Sudhakar Reddy , J. , Sivasanker , S. and Ratnasamy , P. 1992 . Hydroxylation of phenol over ts‐2, a titanium silicate molecular sieve . J. Mol. Catal. , 71 : 373 – 381 .
   Google Scholar
• Okumura , J. , Nishiyama , S. , Tsuruya , S. and Masai , M. 1998 . Formation of Cu‐supported mesoporous silicates and aluminosilicates and liquid‐phase oxidation of benzene catalyzed by the Cu‐mesoporous silicates and aluminosilicates . J. Mol. Catal. A: Chem. , 135 : 133 – 142 .
   Google Scholar
• Tatsumi , T. , Yuasa , K. and Tominaga , H. 1992 . Hydroxylation of benzene and hexane by oxygen and hydrogen over palladium containing titanium silicalites . J. Chem. Soc. Chem. Commun. , : 1446
   Google Scholar
• Miyake , T. , Hamada , M. , Sasaki , S. and Oguri , M. 1995 . Direct synthesis of phenol by hydroxylation of benzene with oxygen and hydrogen . Appl. Catal. , 131 : 33 – 42 .
   Google Scholar
• Lee , C. W. , Lee , W. J. , Ki park , Y. and Park , S.‐E. 2000 . Catalytic hydroxylation of benzene over vanadium‐containing molecular sieves . Catalysis Today , 61 : 137 – 141 .
   Web of Science ®Google Scholar
• Park , S.‐E. , Yoo , J. W. and Lee , W. J. 1999 . Proceedings of the 12th IZC . 1999 , Baltimore, USA. Vol. II , pp. 1253
   Google Scholar
• Parvulescu , V. and Su , B.‐L. 2001 . Iron, cobalt or nickel substituted MCM‐41 molecular sieves for oxidation of hydrocarbons . B.‐L Catalysis Today , 69 : 315 – 322 .
   Web of Science ®Google Scholar
• Mahapatra , S. K. , Sahoo , B. , Keune , W. and Selvam , P. 2002 . Synthesis, characterization and catalytic properties of trivalent iron substituted hexagonal mesoporous aluminophosphates . Chem. Commun. , : 1466 – 1467 .
   PubMed Web of Science ®Google Scholar
• Subrahmanyam , Ch. , Louis , B. , Rainone , F. , Viswanathan , B. , Renken , A. and Varadarajan , T. K. 2003 . Catalytic oxidation of toluene with molecular oxygen over Cr‐substituted mesoporous materials . Appl. Catal. A: Gen. , 241 : 205 – 215 .
   Web of Science ®Google Scholar
• Franco , L. N. , Perez , I. H. , Pliego , J. A. and Franco , A. M. 2002 . Selective hydroxylation of phenol employing Cu–MCM‐41 catalysts . Catalysis Today , 75 : 189 – 195 .
   Web of Science ®Google Scholar
• Zhao , W. , Luo , Y. , Deng , P. and Li , Q. 2001 . Synthesis of Fe‐ MCM‐48 and its catalytic performance in phenol hydroxylation . Catal. Lett. , 73 ( 2 ) : 199 – 202 .
   Web of Science ®Google Scholar
• Ahn , W. S. , Kim , N. K. and Jeong , S. Y. 2001 . Synthesis, characterization, and catalytic properties of Ti‐containing mesoporous molecular sieves prepared using a fluorosilicon compound . Catal. Today , 68 : 83 – 88 .
   Web of Science ®Google Scholar
• Ahn , W. S. , Lee , D. H. , Kim , T. J. , Kim , J. H. , Seo , G. and Ryoo , R. 1999 . Post‐synthetic preparations of titanium‐containing mesopore molecular sieves . Appl. Catal. A , 181 : 39 – 49 .
   Web of Science ®Google Scholar
• Schudel , P. , Mayer , H. and Isler , O. 1972 . The Vitamins Edited by: Sebrell , W. H. Jr. and Harris , R. S. Vol. 5 , 165 New York : Academic Press .
   Google Scholar
• Shimizu , M. , Orita , H. , Hayakawa , T. and Takehera , K. 1989 . A convenient synthesis of alkyl substituted p‐benzoquinones from phenols by a H2O2/heteropoly acid system . Tetra. Lett. , 30 : 471
   Web of Science ®Google Scholar
• Kholdeeva , O. A. , Golovin , A. V. , Maksimovskaya , R. I. and Kozhevnikov , I. V. 1992 . Oxidation of 2,3,6‐trimethylphenol in the presence of molybdovanadophosphoric heteropoly acids . J. Mol. Catal. , 75 : 235 – 244 .
   Google Scholar
• Michelet , D. US Patent No. 3910967 . 1975 .
   Google Scholar
• Ito , S. , Aihara , K. and Masakatsu , M. 1983 . Ruthenium catalyzed oxidation of phenols with H2O2 . Tetra. Lett. , 24 ( 47 ) : 5249 – 5252 .
   Web of Science ®Google Scholar
• Bitter , J. G.A. , Maas , R. J. and Scheeman , J. H. US Patent No. 4250335 . 1981 .
   Google Scholar
• Gessner , T. US Patent no. 5712416 . 1998 .
   Google Scholar
• Thoemel , F. and Hoffmann , W. US Patent No. 4491545 . 1985 .
   Google Scholar
• Isshiki , T. , Yui , T. , Abe , M. , Jono , M. and Uno , H. US Patent No. 4828762 . 1989 .
   Google Scholar
• Hoercher , U. , Bockstiegel , B. , Grafen , P. and Lass , H. US Patent No. 5041572 . 1991 .
   Google Scholar
• Chou , B. , Tsai , J‐L. and Cheng , S. 2001 . Cu‐substituted molecular sieves as liquid phase oxidation catalysts . Micr. Meso. Mater. , 48 : 309 – 317 .
   Web of Science ®Google Scholar
• Tsai , C.‐L. , Chou , B. , Cheng , S. and Lee , J‐F. 2001 . Synthesis of TMBQ using Cu(II)‐substituted MCM‐41 as the catalyst . Appl. Catal. A , 208 : 279 – 289 .
   Web of Science ®Google Scholar
• Kholdeeva , O. A. , Trukhan , N. N. , Vanina , M. P. , Romannikov , V. N. , Parmon , V. N. , Mrowiec‐Bialon , J. and Jarzebski , A. B. 2002 . A new environmentally friendly method for the production of 2,3,5‐trimethyl‐p‐benzoquinone . Catal. Today , 75 : 203 – 209 .
   Web of Science ®Google Scholar
• Turk , D. Europian Patent 0127888Bi . 1987 .
   Google Scholar
• Trukhan , N. N. , Romannikov , V. N. , Shmakov , A. N. , Vanina , M. P. , Paukshtis , E. A. , Bukhtiyarov , V. I. , Kriventsov , V. V. , Danilov , I. Yu. and Kholdeeva , O. A. 2003 . H2O2‐based selective oxidations over titaniumsilicates of SBA‐15 type . Micro. Meso. Mater. , 59 : 73 – 84 .
   Web of Science ®Google Scholar
• Choudhary , K. , Bal , R. , Srinivas , D. , Chandwadkar , A. J. and Sivasanker , S. 2001 . Redox behavior and selective oxidation properties of mesoporous titano‐ and zirconosilicate MCM‐41 molecular sieves . Micro. Meso. Mater. , 50 : 209 – 218 .
   Web of Science ®Google Scholar
• Gontier , S. and Tuel , A. 1996 . Novel zirconium containing mesoporous silicas for oxidation reactions in the liquid phase . Appl. Catal. A , 143 : 125 – 135 .
   Web of Science ®Google Scholar
• Laha , S. C. and Kumar , R. 2002 . Promoter induced synthesis of MCM‐41 type mesoporous materials including Ti‐ and V‐MCM‐41 and their catalytic properties in oxidation reactions . Micro. Meso. Mater. , 53 : 163 – 177 .
   Web of Science ®Google Scholar
• Srinivas , N. , Rani , V. R. , Kishan , M. R. , Kulkarni , S. J. and Raghavan , K. V. 2001 . Liquid phase selective oxidation of alcohols over modified molecular sieves . J. Mol. Catal. A , 172 : 187 – 191 .
   Google Scholar
• Srinivas , N. , Rani , V. R. , Kulkarni , S. J. and Raghavan , K. V. 2002 . J. Mol. Catal. A , 179 : 22
   Google Scholar
• Muzart , J. 1992 . Chem. Rev. , 92 : 113
   Web of Science ®Google Scholar
• Choudary , B. M. , Prasad , A. D. , Bhuma , V. and Swapna , V. 1992 . Chromium pillard clay as a catalyst for benzylic oxidation and oxidative deprotection of benzyl ethers and benzylamines: A simple and convenient procedure . J. Org. Chem. , 57 : 5841 – 5844 .
   Web of Science ®Google Scholar
• Lampers , H. E.B.L. and Sheldon , R. A. 1998 . The stability of chromium in CrAPO‐5, CrAPO‐11, and CrS‐1 during liquid phase oxidations . J. Catal. , 175 : 62 – 69 .
   Web of Science ®Google Scholar
• Das , T. K. , Choudhary , K. , Nandanan , E. , Chandwadkar , A. J. , Sudalai , A. , Ravindranathan , T. and Sivasankar , S. 1997 . Cr‐MCM‐41 catalyzed selective oxidation of alkylarenes with TBHP . Tetra. Lett. , 38 ( 20 ) : 3631 – 3634 .
   Web of Science ®Google Scholar
• Sakthivel , A. , Badamali , S. K. and Selvam , P. 2002 . Catalytic oxidation of alkylaromatics over mesoporous (Cr)MCM‐41 . Catal. Lett. , 80 ( 1,2 ) : 73 – 76 .
   Web of Science ®Google Scholar
• McDaniel , M. P. 1982 . J. Catal. , 76 : 17
   Web of Science ®Google Scholar
• Badamali , S. K. and Selvam , P. 1999 . Recent Trends in catalysis Edited by: Murugesan , V. , Arabindoo , B. and Palanichamy , M. 550
   Google Scholar
• Kim , S.‐S. , Zhang , W. and Pinnavaia , T. J. 1997 . Catalytic oxidation of styrene by manganese(II) bipyridine complex cations immobilized in mesoporous Al‐MCM‐41 . Catal. Lett. , 43 : 149 – 154 .
   Web of Science ®Google Scholar
• Burch , R. , Cruise , N. , Gleeson , D. and Tsang , S. C. 1996 . Surface grafted manganese‐oxo‐species on the walls of MCM‐41 channels—a novel oxidation catalyst . Chem. Commun. , : 951 – 952 .
   Web of Science ®Google Scholar
• Burch , R. , Cruise , N. A. , Gleeson , D. and Tsang , S. C. 1998 . Extended X‐ray absorption fine structure study of manganese‐oxo‐species and related compounds on the surface of MCM‐41 channels . J. Mater. Chem. , 8 ( 1 ) : 227 – 231 .
   Web of Science ®Google Scholar
• Gontier , S. and Tuel , A. 1995 . Liquid‐phase oxidation of aniline over various transition‐metal‐substituted molecular‐sieves . J. Catal. , 157 : 124 – 132 .
   Web of Science ®Google Scholar
• Tian , Z.‐R. , Tong , W. , Wang , J.‐Y. , Duan , N.‐G. , Krishnan , V. V. and Suib , S. L. 1997 . Manganese oxide mesoporous structures: mixed‐valent semiconducting catalyst . Science , 276 ( 5314 ) : 926 – 930 .
   Web of Science ®Google Scholar
• Yonemitsu , M. , Tanaka , Y. and Iwamoto , M. 1998 . Metal ion‐planted MCM‐41: 2. Catalytic epoxidation of stilbene and its derivatives with tert‐butyl hydroperoxide on Mn‐MCM‐41 . J. Catal. , 178 : 207 – 213 .
   Web of Science ®Google Scholar
• Fern'andez , I. , Pedro , J. R. and de la Salud , R. 1996 . Aerobic catalytic epoxidation of unfunctionalized olefins using a new (salen)manganese(III) complex bearing a sesquiterpene salicylaldehyde derivative . Tetrahedron , 52 ( 36 ) : 12031 – 12038 .
   Web of Science ®Google Scholar
• Sheldon , R. A. and Kochi , J. K. 1981 . “ Metal‐Catalyzed Oxidations of Organic Compounds ” . New York : Academic Press .
   Google Scholar
• Zhang , Q. , Wang , Y. , Itsuki , S. , Shishido , T. and Takehira , K. 2002 . Manganese‐containing MCM‐41 for epoxidation of styrene and stilbene . J. Mol. Catal. , 188 : 189 – 200 .
   Google Scholar
• Sakthivel , A. , Dapurkar , S. E. and Selvam , P. 2001 . Mesoporous (Cr)MCM‐41 and (Cr)MCM‐48 molecular sieves: promising heterogeneous catalysts for liquid phase oxidation reactions . Cat. Lett. , 77 ( 1 ) : 155 – 158 .
   Web of Science ®Google Scholar
• Wang , Y. , Zhang , Q. , Shishido , T. and Takehira , K. 2002 . Characterizations of iron‐containing MCM‐41 and its catalytic properties in epoxidation of styrene with hydrogen peroxide . J. Catal. , 209 : 186 – 196 .
   Web of Science ®Google Scholar
• Sutra , P. and Brunel , D. 1996 . Preparation of MCM‐41 type silica‐bound manganese(III) schiff‐base complexes . Chem. Commun. , : 2485 – 2486 .
   Web of Science ®Google Scholar
• Cauvel , A. , Renard , G. and Brunel , D. 1997 . Monoglyceride synthesis by heterogeneous catalysts using MCM‐41 type silicas functionalized with aminogroups . J. Org. Chem. , 62 : 749 – 751 .
   PubMed Web of Science ®Google Scholar
• Bellocq , N. , Brunel , D. , Laspéras , M. and Moreau , P. 1998 . Supported Reagents and Catalysts in Chemistry Edited by: Hodnett , B. K. 162 R. Soc. Chem.
   Google Scholar
• Laspéras , M. , Bellocq , N. , Brunel , D. and Moreau , P. 1998 . Chiral mesoporous templated silicas as heterogeneous inorganic‐organic catalyst in the enantioselective alkylation of benzaldehyde . Tetrahedron Asymm. , 9 ( 17 ) : 3053 – 3064 .
   Google Scholar
• Brunel , D. 1999 . Functionalized micelle templated silicas (MTS) and their use as catalysts for fine chemicals . Micropor. Mesopor. Mater. , 27 ( 2,3 ) : 329 – 344 .
   Web of Science ®Google Scholar
• Brunel , D. , Fajula , F. , Nagy , J. B. , Deroide , B. , Verhoef , M. J. , Veum , L. , Peters , J. A. and Van Bekkum , H. 2001 . Comparison of two MCM‐41 grafted TEMPO catalysts in selective alcohol oxidation . Appl. Catal. A , 213 : 73 – 82 .
   Web of Science ®Google Scholar
• Corma , A. and Kumar , D. 1998 . Stud. Surf. Sci. Catal. , 117 : 201
   Google Scholar
• Van Bekkum , H. and Kloetstra , K. R. 1998 . Stud. Surf. Sci. Catal. , 117 : 171
   Google Scholar
• Velu , S. , Suzuki , K. , Okazaki , M. , Kapoor , M. P. , Osaki , T. and Ohashi , F. 2000 . Oxidative steam reforming of methane over CuZnAl(Zr)‐oxide catalyst for the selective production of hydrogen for fuel cells: Catalyst characterization and performance evaluation . J. Catal. , 194 ( 2 ) : 373 – 384 .
   Web of Science ®Google Scholar
• Wu , J. and Saito , M. 2000 . Improvement of stability of a Cu/ZnO/Al2O3 catalyst for the CO shift reaction . J. Catal. , 195 : 420 – 422 .
   Web of Science ®Google Scholar
• Karakassides , M. A. , Bourlnos , A. , Petridis , D. , Coche‐ Guerente , L. and Labbe , P. 2000 . Synthesis and characterization of Cu containing mesoporous silicas . J. Mater. Chem. , 10 ( 2 ) : 403 – 408 .
   Web of Science ®Google Scholar
• Xu , J. , Yu , J. , Lee , S. J. , Kim , B. Y. and Kevan , L. 2000 . Electron spin resonance and electron spin echo modulation studies of adsorbate interactions with cupric ion on the Al content in Cu‐Al‐MCM‐41 materials . J. Phys. Chem. , B104 ( 6 ) : 1307 – 1314 .
   Google Scholar
• Velu , S. , Wang , L. , Okasaki , M. and Tomura , S. 2002 . Characterization of MCM‐41 mesoporous molecular sieves containing copper and zinc and their catalytic performance in the selective oxidation of alcohols to aldehydes . Micropor. Mesopor. Mater. , 54 : 113 – 126 .
   Web of Science ®Google Scholar
• Corma , A. , Navarro , M. T. and Perez‐Periente , J. 1994 . J. Chem. Soc. Chem. Commun. , : 147
   Google Scholar
• Kan , Q. , Bi , Y. , Ying , Z. , Wu , T. and Zhen , K. 2001 . Catalytic oxidation of α‐eicosanol into eicosanic acid in the presence of Ti‐MCM‐41 or active component supported Ti‐MCM‐41 catalysts . Micropor. Mesopor. Mater. , 44 : 609 – 617 .
   Web of Science ®Google Scholar
• Curuntt , G. L. US Patent 4,625,044 . 1986 . Dow Chemical Company
   Google Scholar
• Curuntt , G. L. US Patent 5,004,827 . 1991 . Dow Chemical Company
   Google Scholar
• Curuntt , G. L. and Harley , D. C. 1988 . Oxygen Complexes and Oxygen Activation by Transition Metals 215 New York : Plenum Press .
   Google Scholar
• Wang , Y. J. , Zhao , X. Q. , Yuan , B. G. , Zhang , B. C. and Cong , J. S. 1998 . Synthesis of dimethyl carbonate by gas‐phase oxidative carbonylation of methanol on the supported solid catalyst I. Catalyst preparation and catalytic properties . Appl. Catal. A: Gen. , 171 : 255 – 260 .
   Web of Science ®Google Scholar
• King , S. T. 1996 . Reaction mechanism of oxidative carbonylation of methanol to dimethyl carbonate in Cu‐Y zeolite . J. Catal. , 161 : 530 – 538 .
   Web of Science ®Google Scholar
• King , S. T. 1997 . Oxidative carbonylation of methanol to dimethyl carbonate by solid‐state ion‐exchanged CuY catalysts . Catal. Today , 33 : 173 – 182 .
   Web of Science ®Google Scholar
• Mokaya , R. , Jones , W. , Luan , Z. H. , Alba , M. D. and Klinowski , J. 1996 . Acidity and catalytic activity of the mesoporous aluminosilicate molecular sieve MCM‐41 . Catal. Lett. , 37 ( 1,2 ) : 113 – 120 .
   Web of Science ®Google Scholar
• Li , Z. , Xie , K. and Slade , R. C.T. 2001 . High selective catalyst CuCl/MCM‐41 for oxidative carbonylation of methanol to dimethyl carbonate . Appl. Catal. A , 205 : 85 – 92 .
   Web of Science ®Google Scholar
• Pitchai , R. and Klier , K. 2001 . Catal. Rev. Sci. Eng. , 28 : 13
   Google Scholar
• Brown , M. J. and Parkyns , N. D. 1991 . Progress in the partial oxidation of methane to methanol and formaldehyde . Catal. Today , 8 : 305 – 335 .
   Google Scholar
• Herman , G. , Sun , Q. , Shi , C. , Klier , K. , Wang , C.‐B. , Hu , H. , Wachs , I. E. and Bhasin , M. 1997 . Development of active oxide catalysts for the direct oxidation of methane to formaldehyde . Catal. Today , 37 : 1 – 14 .
   Web of Science ®Google Scholar
• Parmaliana , A. , Frusteri , F. , Mezzapica , A. , Miceli , D. , Scurrell , M. S. and Giordano , N. J. 1993 . A basic approach to evaluate methane partial oxidation catalysts . Catal. , 143 : 262 – 274 .
   Web of Science ®Google Scholar
• Parmaliana , A. and Arena , F. 1997 . Working mechanism of oxide catalysts in the partial oxidation of methane to formaldehyde. I. Catalytic behaviour of SiO2, MoO3/SiO2, V2O5/SiO2, TiO2, and V2O5/TiO2 systems . J. Catal. , 167 : 57 – 65 .
   Web of Science ®Google Scholar
• Cardoso , J. H. , Bañares , M. A. , Correa Bueno , J. M. and Fierro , J. L.G. 1998 . Partial oxidation of methane on silica supported vanadia catalyst. The relevance of catalyst BET area and gas phase activation . Collect. Czech. Chem. Commun. , 63 ( 11 ) : 1743 – 1754 .
   Google Scholar
• Koranne , M. M. , Goodwin , J. G. Jr. and Marcelin , G. 1994 . Oxygen involvement in the partial oxidation of methane on supported and unsupported V2O5 . J. Catal. , 148 : 369 378 – 387 .
   Web of Science ®Google Scholar
• Sexton , A. W. , Coda , E. M.G. and Hodnett , B. K. 1998 . A comparison of the performances of selected catalysts for the partial oxidation of methane to formaldehyde at elevated pressures . Catal. Today , 46 : 127 – 136 .
   Web of Science ®Google Scholar
• Parmaliana , A. , Sokolovskii , V. , Miceli , D. , Arena , F. and Goirdano , N. 1994 . On the nature of the catalytic activity of silica‐based oxide catalysts in the partial oxidation of methane to formaldehyde with O2 . J. Catal. , 148 : 514 – 523 .
   Web of Science ®Google Scholar
• Kartheuser , B. , Hodnett , B. K. , Zanthoff , H. and Baerns , M. 1993 . Catal. Lett. , 21 : 209
   Web of Science ®Google Scholar
• Bernt , H. , Martin , A. , Bruckner , A. , Schreier , E. , Muller , D. , Kosslick , H. , Wolf , G.‐U. and Lucke , B. 2000 . Structure and catalytic properties of VOx/MCM materials for the partial oxidation of methane to formaldehyde . J. Catal. , 191 : 384 – 400 .
   Web of Science ®Google Scholar
• Dai , L.‐X. , Teng , Y.‐H. , Tabata , K. , Suzuki , E. and Tatsumi , T. 2001 . Catalytic application of Mo‐incorporated SBA‐1 mesoporous molecular sieves to partial oxidation of methane . Micro. Meso. Mater. , 44 : 5573 – 5580 .
   Web of Science ®Google Scholar
• Raja , H. P. , Poladi , R. and Landry , C. C. 2002 . Oxidation of octane and cyclohexane using a new porous substrate, Ti‐MMM‐1 . Micro. Meso. Mater. , 52 : 11 – 18 .
   Web of Science ®Google Scholar
• Beck , J. S. , Vartuli , J. C. , Roth , W. J. , Leonowicz , M. E. , Kresge , C. T. , Schmitt , K. D. , Chu , C. T.‐W. , Olson , D. H. , Sheppard , E. W. , McCullen , S. B. , Higgins , J. B. and Schlenker , J. L. 1992 . J. Am. Chem. Soc. , 114 : 108 – 134 .
   Web of Science ®Google Scholar
• Sakthivel , A. and Selvam , P. 2002 . Mesoporous (Cr)MCM‐41: A mild and efficient heterogeneous catalyst for selective oxidation of cyclohexane . J. Catal. , 211 : 134 – 143 .
   Web of Science ®Google Scholar
• Mamedov , E. A. and Cortés Corberán , V. 1995 . Oxidative dehydrogenation of lower alkanes on vanadium oxide‐based catalysts. The present state of the art and outlooks . Appl. Catal. A , 127 : 1 – 40 .
   Web of Science ®Google Scholar
• Bettahar , M. M. , Costentin , G. , Savary , L. and Lavalley , J. C. 1996 . On the partial oxidation of propane and propylene on mixed metal oxide catalysts . Appl. Catal. A , 145 : 1 – 48 .
   Web of Science ®Google Scholar
• Peña , M. L. , Dejoz , A. , Fornés , V. , Reya , F. , Vázquez , M. I. and López Nieto , J. M. 2001 . V‐containing MCM‐41 and MCM‐48 catalysts for the selective oxidation of propane in gas phase . Appl. Catal. A , 209 : 155 – 164 .
   Web of Science ®Google Scholar
• Sulikowski , B. , Olejniczak , Z. , Woch , E. , Rakoczy , J. , Valenzuela , R. X. and Cortés Corberán , V. 2002 . Oxidative dehydrogenation of isobutane on MCM‐41 mesoporous molecular sieves . Appl. Catal. A , 232 : 189 – 202 .
   Web of Science ®Google Scholar
• Nojiri , N. , Sakai , Y. and Watanabe , Y. 1995 . Two catalytic technologies of much influence on progress in chemical process development in Japan . Catal. Rev.‐Sci. Eng. , 37 ( 1 ) : 145 – 178 .
   Web of Science ®Google Scholar
• Liu , Y. , Murata , K. , Inaba , M. and Mimura , N. 2003 . Selective oxidation of propylene to acetone by molecular oxygen over Mx/2H5‐x[PMo10 V2O40]/HMS . Catal. Commun. , 4 ( 6 ) : 281 – 285 .
   Web of Science ®Google Scholar
• Murata , K. and Kiyozumi , Y. 2001 . Oxidation of propene by molecular oxygen over titanium modified silicalite catalysts . Chem. Commun. , : 1356 – 1357 .
   Web of Science ®Google Scholar
• Xu , X. and Friend , C. M. 1991 . J. Am. Chem. Soc. , 113 : 6779
   Web of Science ®Google Scholar
• McCoy , M. 1998 . Chem. Eng. News , 14 : 19
   Google Scholar
• Ainsworth , S. J. 1992 . Chem. Eng. News , 2 : 9
   Google Scholar
• Kalvachev , Y. A. , Hayashi , T. , Tsubota , S. and Haruta , M. 1997 . Stud. Surf. Sci. Catal. , 110 : 965
   Google Scholar
• Hayashi , T. , Tanaka , K. and Haruta , M. 1998 . Selective vapor‐phase epoxidation of propylene over Au/TiO2 Catalysts in the presence of oxygen and hydrogen . J. Catal. , 178 : 566 – 575 .
   Web of Science ®Google Scholar
• Uphade , B. S. , Akita , T. , Nakamura , T. and Harutal , M. 2002 . Vapor‐phase epoxidation of propene using H2 and O2 over Au/Ti‐MCM‐48 . J. Catal. , 209 : 331 – 340 .
   Web of Science ®Google Scholar
• Uphade , B. S. , Yamada , Y. , Akita , T. , Nakamura , T. and Haruta , M. 2001 . Synthesis and characterization of Ti‐MCM‐41 and vapor‐phase epoxidation of propylene using H2 and O2 over Au/Ti‐MCM‐41 . Appl. Catal. , A215 : 137 – 148 .
   Google Scholar
• Kawi , S. and Te , M. 1998 . MCM‐48 supported chromium catalyst for trichloroethylene oxidation . Catal. Today , 44 : 101 – 109 .
   Web of Science ®Google Scholar
• Kumar , K. R. , Choudary , B. M. , Jamil , Z. and Thyagarajan , G. 1986 . Synthesis of new interlamellar functionalized montmorillonite Pd(II) catalysts: The first example of a truly ‘heterogeneous’ anchored catalyst . J. Chem. Soc., Chem. Commun. , : 130 – 131 .
   Google Scholar
• Barloy , L. , Battioni , P. and Mansuy , D. 1990 . Manganese porphyrin supported on montmorillonite as hydrocarbon mono‐oxygenation catalysts: Particular efficacy for Linear Alkane Hydroxylation . J. Chem. Soc., Chem. Commun. , : 1365 – 1367 .
   Google Scholar
• Choudary , B. M. , Kantam , M. L. , Bharathi , B. , Sreekanth , P. and Figueras , F. 2000 . Epoxidation of olefins catalyzed by new Mn(II) salen immobilized mesoporous materials . J. Mole. Catal. A , 159 ( 2 ) : 417 – 421 .
   Google Scholar
• Reddy , J. S. , Liu , P. and Sayari , A. 1996 . Vanadium containing crystalline mesoporous molecular sieves Leaching of vanadium in liquid phase reactions . Appl. Catal. A , 148 : 7 – 21 .
   Web of Science ®Google Scholar
• Wei , D. , Chueh , W.‐T. and Haller , G. L. 1999 . Catalytic behavior of vanadium substituted mesoporous molecular sieves . Catal. Today , 51 : 501 – 511 .
   Web of Science ®Google Scholar
• Corma , A. , Iglesias , M. and Sanchez , F. 1996 . Large pore Ti zeolites and mesoporous Ti silicalite as catalysts for selective oxidation of organic sulphides . Catal. Lett. , 39 ( 3,4 ) : 153 – 156 .
   Web of Science ®Google Scholar
• Jörgensen , K. A. 1989 . Chem. Rev. , : 431 – 458 .
   Web of Science ®Google Scholar
• Dickman , M. H. and Pope , M. T. 1994 . Chem. Rev. , : 569 – 584 .
   Web of Science ®Google Scholar
• Romao , C. , Kühn , F. E. and Herrmann , W. A. 1997 . Chem. Rev. , : 3197 – 3246 .
   PubMed Web of Science ®Google Scholar
• Carla , D. N. , Martyn , P. , Anabela , A. V. , Joaõ , R. , André , D. L. and Isabel , S. G. 2003 . Dioxomolybdenum(VI)‐Modified Mesoporous MCM‐41 and MCM‐48 materials for the catalytic epoxidation of olefins . Eur. J. Inorg. Chem. , : 3870 – 3877 .
   Web of Science ®Google Scholar
• Arends , I. W.C.E. and Sheldon , R. A. 2001 . Appl. Catal. A , 212 : 175 – 187 .
   Web of Science ®Google Scholar
• Rhee , C. H. and Lee , J. S. 1996 . Thermal and chemical stability of Ti‐substituted MCM‐41 . Catal. Lett. , 40 ( 3,4 ) : 261 – 264 .
   Web of Science ®Google Scholar
• Chen , L. Y. , Chuah , G. K. and Jaenicke , S. 1998 . Ti‐containing MCM‐41 catalysts for liquid phase oxidation of cyclohexene with aqueous H2O2 and tert‐butyl hydroperoxide . Catal. Lett. , 50 ( 1 ) : 107 – 114 .
   Web of Science ®Google Scholar
• Trukhan , N. N. , Yu. Derevyankin , A. , Shmakov , A. N. , Paukshtis , E. A. , Kholdeeva , O. A. and Romannikov , V. N. 2001 . Alkene and thioether oxidations with H2O2 over Ti‐ and V‐containing mesoporous mesophase catalysts . Micro. Meso. Mater. , 44 : 603 – 608 .
   Web of Science ®Google Scholar
• Kholdeeva , O. A. , Derevyankin , A. Yu. , Shmakov , A. N. , Trukhan , N. N. , Paukshtis , E. A. , Tuel , A. and Romannikov , V. N. 2000 . Alkene and thioether oxidations with H2O2 over Ti‐containing mesoporous mesophase catalysts . J. Mole. Catal. A , 158 : 417 – 421 .
   Google Scholar
• Kochkar , H. and Figueras , F. 1997 . Synthesis of hydrophobic TiO2‐SiO2 Mixed oxides for the epoxidation of cyclohexene . J. Catal. , 171 : 420 – 430 .
   Web of Science ®Google Scholar
• Mlodnicka , T. and James , B. R. 1994 . “ Metalloporphyrin Catalyzed Oxidations ” . Edited by: Monatanari , F. and Casella , L. Dordrecht : Kluwer Academic Publishers .
   Google Scholar
• Liu , C‐J. , Li , S.‐G. , Pang , W.‐Q. and Che , C.‐M. 1997 . Ruthenium porphyrin encapsulated in modified mesoporous molecular sieve MCM‐41 for alkene oxidation . Chem. Commun. , : 65 – 66 .
   Web of Science ®Google Scholar
• Algarra , F. , Esteves , M. A. and Vornes , V. 1998 . Condensation of pyrrole with aldehydes in the presence of Y‐zeolite and mesoporous MCM‐41 aluminosilicate on the encapsulation of porphyrin precursors . New J. Chem. , 22 ( 4 ) : 333 – 338 .
   Web of Science ®Google Scholar
• Liu , C.‐J. , Yu , W.‐Y. , Li , S.‐G. and Che , C.‐M. 1998 . Ruthenium meso‐Tetrakis(2,6‐dichlorophenyl) porphyrin complex immobilized in mesoporous MCM‐41 as a heterogeneous catalyst for selective alkene epoxidations . J. Org. Chem. , 63 : 7364 – 7369 .
   PubMed Web of Science ®Google Scholar
• Kim , G.‐J. and Kim , S.‐H. 1999 . Immobilization of new Mn (salen) complex over MCM‐41 and its activity in asymmetric epoxidation of styrene . Catal. Lett. , 57 : 139 – 143 .
   Web of Science ®Google Scholar
• Zhang , L. , Sun , T. and Ying , J. Y. 1999 . Oxidation catalysts over functionalized metaloporphyrind fixated within ultra large pore transition metal doped silicate supports . Chem. Commun. , : 1103 – 1104 .
   Web of Science ®Google Scholar
• Schünemann , V. , Trautwein , A. X. , Rietjens , I. M.C.M. , Boersma , M. G. , Veeger , C. , Mandon , D. , Weiss , R. , Bahl , K. , Colapietro , C. , Piech , M. and Austin , R. N. 1999 . Characterization of Fe(III) Tetramesitylporphyrin and micro‐peroxidase‐8 incorporated into the molecular sieve MCM‐41 . Inorg. Chem. , 38 ( 1 ) : 4901 – 4905 .
   PubMedGoogle Scholar
• Potowicz , J. , Serwicka , E. M. , Bastardo‐Gonzalez , E. , Jones , W. and Mokaya , R. 2001 . Oxidation of cyclohexene over Mn(TMPyP) porphyrin‐exchanged Al,Si‐mesoporous molecular sieves . Appl. Catal. A , 218 : 211 – 217 .
   Web of Science ®Google Scholar
• Sakthivel , A. , Dapurkar , S. E. and Selvam , P. 2003 . Allylic oxidation of cyclohexene over chromium containing mesoporous molecular sieves . Appl. Catal. A , 246 : 283 – 293 .
   Web of Science ®Google Scholar
• Muzart , J. 1992 . Chem. Rev. , 92 : 113
   Web of Science ®Google Scholar
• Bhaumik , A. and Tatsumi , T. 2000 . Organically modified titanium‐rich TI‐MCM‐41, efficient catalysts for epoxidation reactions . J. Catal. , 189 ( 1 ) : 31 – 39 .
   Web of Science ®Google Scholar
• Dusi Mallat , T. and Baiker , A. 2000 . Catal. Rev. , 42 : 213 – 78 .
   Web of Science ®Google Scholar
• De Vos , D. E. , Dams , M. , Sels , B. F. and Jacobs , P. A. 2003 . Adv. Synth. Catal. , 345 : 457 – 473 .
   Web of Science ®Google Scholar
• Clark , J. H. and Macquarrie , D. J. 1998 . Chem. Commun. , : 853 – 60 .
   Web of Science ®Google Scholar
• Shephard , D. S. , Zhou , W. , Maschmeyer , T. , Matters , J. M. , Roper , C. L. , Parsons , S. , Johnson , B. F.G. and Duer , M. J. 1998 . Angew. Chem., Int. Ed. , 37 : 2719 – 2723 .
   PubMed Web of Science ®Google Scholar
• Anwander , R. 2001 . Chem. Mater. , 13 : 4419 – 4438 .
   Web of Science ®Google Scholar
• Xiang , S. , Zhang , Y. , Xin , Q. and Li , C. 2002 . Angew. Chem., Int. Ed. , 41 : 821 – 824 .
   PubMed Web of Science ®Google Scholar
• Coperet , C. , Chabanas , M. , Saint‐Arroman , R. P. and Basset , J.‐M. 2003 . Angew. Chem., Int. Ed. , 42 : 156 – 181 .
   PubMed Web of Science ®Google Scholar
• Lim , M. H. and Stein , A. 1999 . Chem. Mater. , 11 : 3285 – 3295 .
   Web of Science ®Google Scholar
• Stein , A. , Melde , B. J. and Schroden , R. C. 2000 . Adv. Mater. , 12 : 1403 – 1419 .
   Web of Science ®Google Scholar
• Wight , A. P. and Davis , M. E. 2002 . Chem. Rev. , 102 : 3589 – 3614 .
   PubMed Web of Science ®Google Scholar
• Jia , M. and Thiel , W. R. 2002 . Chem. Commun. , : 2392 – 2393 .
   PubMed Web of Science ®Google Scholar
• Jia , M. , Seifert , A. and Thiel , W. R. 2003 . Mesoporous MCM‐41 materials modified with oxodiperoxo molybdenum complexes: Efficient catalysts for the epoxidation of cyclooctene . Chem. Mater. , 15 : 2174 – 2180 .
   Web of Science ®Google Scholar
• Jia , M. , Seifert , A. , Berger , M. , Giegengack , H. , Schulze , S. and Thiel , W. R. 2004 . Hybrid mesoporous materials with a uniform ligand distribution: synthesis, characterization, and application in epoxidation catalysis . Chem. Mater. , 16 : 877 – 882 .
   Web of Science ®Google Scholar
• Thomas , J. M. , Maschmeyer , T. , Johnson , B. F.G. and Shephard , D. S. 1999 . Constrained chiral catalysts . J. Mol. Catal. A , 141 : 139 – 144 .
   Google Scholar
• Schwab , G. M. and Rudolf , L. 1932 . Naturwiss , 20 : 362
   Google Scholar
• Langham , C. , Bethell , D. , Lee , D. F. , McMorn , P. , Page , P. C.B. , Willock , D. J. , Sly , C. , Hancock , F. E. , King , F. and Hutchings , G. J. 1999 . Heterogeneous aziridination of alkenes using Cu2+ exchanged zeolites . Appl. Catal. A , 182 : 85 – 89 .
   Web of Science ®Google Scholar
• Iwamoto , M. , Tanaka , Y. , Hirosumi , J. , Kita , N. and Triwahyono , S. 2001 . Enantioselective oxidation of sulfide to sulfoxide on Ti‐containing mesoporous silica prepared by a template‐ion exchange method . Micro. Meso. Mater. , 48 : 271 – 277 .
   Web of Science ®Google Scholar
• Iwamoto , M. and Tanaka , Y. 2001 . Catal. Surveys fron Jpn. , 5 : 25
   Google Scholar
• Wingen , W. , Anastasievic , N. , Hollnagel , A. , Wener , D. and Schuth , F. 2000 . Fe–MCM‐41 as a catalyst for sulfur dioxide oxidation in highly concentrated gases . J. Catal. , 193 : 248 – 254 .
   Web of Science ®Google Scholar
• Panov , G. , Kharitonov , A. S. and Sobolev , V. I. 1993 . Oxidative hydroxylation using dinitrogen monoxide: a possible route for organic synthesis over zeolites . Appl. Catal. A: Gen. , 98 : 11 – 20 .
   Web of Science ®Google Scholar
• Pophal , C. , Yogo , T. , Yamada , K. and Segawa , K. 1998 . Selective catalytic reduction of nitrous oxide over Fe‐MFI in the presence of propene as reductant . Appl. Catal. B: Environ. , 16 ( 2 ) : 177 – 186 .
   Web of Science ®Google Scholar
• Grubert , G. , Hudson , M. J. , Joyner , R. W. and Stockenhuber , M. 2000 . The room temperature, stoichiometric conversion of N2O to adsorbed NO by Fe‐MCM‐41 and Fe‐ZSM‐5 . J. of Catal. , 196 : 126 – 133 .
   Web of Science ®Google Scholar
• Bartl , P. , Schindler , G. P. and Holderich , W. F. 1998 . Oxidative cleavage of cyclohexane derivatives over titanium‐containing Y zeolites . Appl. Catal. A , 166 : 267 – 279 .
   Web of Science ®Google Scholar
• Sheldon , R. A. and Dakka , J. 1992 . Proceedings of the DGMK‐Conference “Selective Oxidations in Petrochemistry” Edited by: Baerns , M. and Weitkamp , J. 215 Goslar, , Germany
   Google Scholar
• Martýnez Velarde , A. , Bartl , P. , Nießen , T. E.W. and Hoelderich , W. F. 2000 . Hydrogen peroxide oxidation of D‐glucose with titanium‐containing zeolites as catalysts . J. Mole. Catal. A , 157 : 225 – 236 .
   Google Scholar
• Nießen , T. E.W. , Niederer , J. P.M. , Gjervan , T. and Holderich , W. F. 1998 . Synthesis and characterisation of titanium‐containing MCM‐41 using (NH4)3[Ti(O2)F5] as the titanium source . Micro‐ and Meso. Mater. , 21 : 67 – 74 .
   Web of Science ®Google Scholar
• Clerici , M. G. 2000 . Zeolites for fine chemical production . Topics Catal. , 13 ( 4 ) : 373 – 386 .
   Web of Science ®Google Scholar
• Arends , I. W.C.E. and Sheldon , R. A. 2001 . Activities and stabilities of heterogeneous catalysts in selective liquid phase oxidations: recent developments . Appl. Catal. A , 212 : 175 – 187 .
   Web of Science ®Google Scholar
• Hutter , R. , Mallat , T. and Baiker , A. 1995 . Titania silica mixed oxides: II. Catalytic behavior in olefin epoxidation . J. Catal. , : 177 – 189 .
   Google Scholar