64
Views
1
CrossRef citations to date
0
Altmetric
Original Articles

Volumetric Properties of Poly (Vinyl Alcohol, Vinyl Sulfate Ester Salt) Polyelectrolytes in Salt Free Aqueous Solutions

, , &
Pages 43-51 | Received 01 Feb 2002, Accepted 31 Aug 2002, Published online: 06 Feb 2007

References

  • Finch , C. A. 1973 . Polyvinyl Alcohol, Properties and Applications Edited by: Finch , C. A. London : John Wiley & Sons .
  • Rudakova , N. B. , Kalontarova , E. Y. , Yakubov , K. M. , Bakhus , E. N. and Bobritskaya , L. S. 1987 . Acid‐base properties of sulfur‐containing and phosphorus‐containing polymeric ligands based on polyvinyl‐alcohol polyacrylonitrile copolymer . J. Applied Chem. USSR , 60 ( 3 ) : 647 – 650 .
  • Finch , C. A. 1968 . Properties of Polyvinyl Alcohol London : Society of Chemical Industry . Monograph No. 30
  • Dunn , A. S. 1980 . The Peculiarities of polyvinyl‐alcohol . Chemistry & Industry , 20 : 801 – 806 .
  • Kiselgof , G. V. , Arkhangelskii , L. K. and Korolkov , S. V. 1985 . Interaction of boric‐acid with water‐soluble polyvinyl alcohol . J. Appl. Chem. USSR , 58 ( 12 ) : 2524 – 2526 .
  • Sabet , V. M. , Zourab , S. M. , El‐Sayed , M. M. and Kotb , S. M. 1984 . Interaction of polyvinyl‐alcohol with protein at air water and oil‐water interfaces and its effect on emulsion stability . Indian J Chem.‐A , 23 ( 5 ) : 372 – 374 .
  • Shirahama , K. , Oh‐Ishi , M. and Takisawa , N. 1989 . Interaction between cationic surfactants and poly(vinyl‐alcohol) . Colloid. Surface. , 40 ( 3–4 ) : 261 – 266 .
  • Gotze , T. and Sonntag , H. 1987 . The effect of solvent quality on the interaction between 2 layers of adsorbed polyvinyl‐alcohol (PVA) . Colloid. Surface. , 25 ( 1 ) : 77 – 90 .
  • Okaya , T. , Suzuki , A. and Kikuchi , K. 1999 . Importance of grafting in the emulsion polymerization of MMA using PVA as a protective colloid . Effect of initiators. Colloid. Surface. A , 153 ( 1–3 ) : 123 – 125 .
  • Sabet , V. M. , Zourab , S. M. and Said , W. 1982 . Interaction of polyvinyl‐alcohol with lecithin at the air‐water and oil–water interfaces and its effect on emulsion stability . J. Disper. Sci. , 3 ( 4 ) : 419 – 433 .
  • Eagland , D. and Crowther , N. J. 1982 . Hydrophobic interactions in dilute‐solutions of polyvinyl‐alcohol . Faraday Symp. Chem. S. , 17 : 141 – 160 .
  • Wardlaw , G. C. , Humphery , S. and Eaglad , D. 1977 . Implication of solvent structure in interaction of poly(vinyl‐alcohol) and short chain monohydric alcohols . Br. Polym. J. , 9 ( 4 ) : 278 – 283 .
  • Eagland , D. , Wardlaw , G. C. and Thorn , I. 1978 . Particle‐ macromolecule interactions in aqueous‐solutions. 1. Solution and flow behavior of polyvinylalcohol in an aqueous‐medium . Coll. Polym. Sci. , 256 ( 11 ) : 1073 – 1078 .
  • Crowther , N. J. and Eagland , D. 1986 . The volumetric behavior of polyvinyl‐alcohol in aqueous‐solution . J. Chem. Soc. Faraday Trans. I , 82 ( 9 ) : 2791 – 2799 .
  • Crowther , N. J. and Eagland , D. 1988 . Light‐scattering‐studies of aggregation in aqueous‐solutions of polyvinyl‐alcohol co‐vinyl acetate copolymer . Chem. Soc. Faraday Trans. I , 84 ( 4 ) : 1211 – 1221 .
  • Ermakov , V. I. , Mamedova , A. Y. , Mosin , Y. M. and Krivoshchepov , A. F. 1995 . Structure of aqueous‐solutions of polyvinyl‐alcohol and AMIFLOC according to the data of high‐resolution NMR‐spectroscopy . Colloid. J. , 57 ( 5 ) : 631 – 635 .
  • Huque , M. and Sandulescu , D. 1984 . Studies on aqueous‐electrolytes and nonelectrolytes. 2. Effects of electro‐lytes on ultrasonic velocity, adiabatic compressibility and structure of aqueous‐solutions of polyvinyl‐alcohol (PVA) . Revue Romanie Chimie , 29 ( 5 ) : 415 – 421 .
  • Nikolaev , A. F. , Belogorodskaya , K. V. , Yukha , Y. S. and Domnicheva , N. A. 1987 . Properties of polyvinyl‐alcohol of different molecular‐weights and its solutions . J. Appl. Chem. USSR , 60 ( 10 ) : 2133 – 2137 .
  • Ise , N. 1998 . On the solution viscosity of ionic polymers and their conformation in solutions . P. Jpn. Acad. B‐Phys. , 74 ( 8 ) : 192 – 200 .
  • Wandrey , C. , Bartkowiak , A. and Hunkeler , D. 1999 . Partial molar and specific volumes of polyelectrolytes: comparison of experimental and predicted values in salt‐free solutions . Langmuir , 15 ( 12 ) : 4062 – 4068 .
  • Wandrey , C. 1999 . Concentration regimes in polyelectrolyte solutions . Langmuir , 15 ( 12 ) : 4069 – 4075 .
  • Hunkeler , D. and Wandrey , C. 2001 . Polyelectrolytes: research, development, and applications . Chimia , 55 ( 3 ) : 223 – 227 .
  • Wandrey , C. , Hunkeler , D. , Wendler , U. and Jaeger , W. 2000 . Counterion activity of highly charged strong polyelectrolytes . Macromolecules , 33 ( 19 ) : 7136 – 7143 .
  • Raju , B. B. , Winnik , F. M. and Morishima , Y. 2001 . A Look at the thermodynamics of the association of amphi‐philic polyelectrolytes in aqueous solutions: Strengths and limitations of isothermal titration calorimetry . Langmuir , 17 ( 14 ) : 4416 – 4421 .
  • Hiraoka , K. and Yokoyama , T. 1986 . Volumetric properties of water poly(acrylic acid) salt systems from the pure solid to highly concentrated‐solutions . J. Polym. Sci. B.‐Polym. Phys. , 24 ( 4 ) : 769 – 778 .
  • Hiraoka , K. , Shin , H. and Yokoyama , T. 1982 . Density‐measurements of poly(acrylic acid) sodium‐salts . Polym. Bull. , 8 ( 7–8 ) : 303 – 309 .
  • Lepori , L. and Mollica , V. 1978 . Volumetric properties of dilute aqueous‐solutions of poly(ethylene glycols) . J. Polym. Sci. Polym. Phys. , 16 ( 6 ) : 1123 – 1134 .
  • Roy‐Chowdhury , P. 1987 . Adiabatic compressibility and apparent molar volume of ionic monomers, polymers, and copolymers in aqueous and nonaqueous solutions . J. Macromol. Sci. R. M. C. , 27 ( 2 ) : 219 – 252 .
  • Gianni , P. and Lepori , L. 1996 . Group contributions to the partial molar volume of ionic organic solutes in aqueous‐solution . J. Solution Chem. , 25 ( 1 ) : 1 – 42 .
  • Barrettgultepe , M. A. , Gultepe , M. E. and Yeager , E. B. 1983 . Compressibility of colloids. 1. Compressibility studies of aqueous‐solutions of amphiphilic polymers and their adsorbed state on polystyrene latex dispersions by ultrasonic velocity‐measurements . J. Phys. Chem. , 87 ( 6 ) : 1039 – 1045 .
  • Hoiland , H. , Gjerde , M. I. , Mo , C. and Lie , E. 2001 . Solubilization of alcohols in SDS and TTAB from isentropic partial molar compressibilities and Solubilities . Colloid. Surface. A , 183 : 651 – 660 .
  • Hakin , A. W. , Hoiland , H. and Hedwig , G. R. 2000 . Volumetric properties of some oligopeptides in aqueous solution: Partial molar expansibilities and isothermal compressibilities at 298.15 K for the peptides of sequence Ala(gly)(n), n = 1–4 . Phys. Chem. Chem. Phys. , 2 ( 21 ) : 4850 – 4857 .
  • Blandamer , M. J. and Hoiland , H. 1999 . Volumetric properties of solutions: A novel method of data analysis yielding partial molar volumes and partial molar expansions of solutes . Phys. Chem. Chem. Phys. , 1 ( 8 ) : 1873 – 1875 .
  • Horvath‐Szabo , G. and Hoiland , H. 1998 . Apparent molar volume of adsorbed‐state sodium dodecyl sulfate on the polystyrene/water interface . Langmuir , 14 ( 19 ) : 5539 – 5545 .
  • Buwalda , R. , Engberts , J. B.F.N. , Hoiland , H. and Blandamer , M. J. 1998 . Volumetric properties and compressibilities of alkyltrimethylammonium bromides and sodium alkylsulphates in aqueous solution . J. Phys. Org. Chem. , 11 ( 1 ) : 59 – 62 .
  • Hedwig , G. R. , Hoiland , H. and Hogseth , E. 1996 . Thermodynamic properties of peptide solutions. 15. Partial molar isentropic compressibilities of some glycyl dipeptides in aqueous‐solution at 15 and 35‐degrees‐C . J. Solution Chem. , 25 ( 11 ) : 1041 – 1053 .
  • Douheret , G. , Davis , M. I. , Fjellanger , I. J. and Hoiland , H. 1997 . Ultrasonic speeds and volumetric properties of binary mixtures of water with poly(ethylene glycol)s at 298.15 K . J. Chem. Soc. Faraday T. , 93 ( 10 ) : 1943 – 1949 .
  • Cabani , S. , Gianni , P. , Mollica , V. and Lepori , L. 1981 . Group contributions to the thermodynamic properties of non‐ionic organic solutes in dilute aqueous‐solution . J. Solution Chem. , 10 ( 8 ) : 563 – 595 .
  • Desnoyers , J. E. and Perron , G. 1997 . “ Thermodynamic properties of surfactant solutions ” . In Handbook of Surface and Colloid Chemistry Edited by: Birdi , K. S. 119 – 156 . New York : CRC Press .
  • Franks , F. and Reid , D. S. 1973 . A Comprehensive Treatise Edited by: Franks , F. Vol. 2 , New York : Plenum Press .
  • Csomor , K. , Karpati , E. , Nagy , M. , Gyorgyiedelenyi , J. and Machovich , R. 1994 . Blood‐coagulation is inhibited by sulfated copolymers of vinyl alcohol and acrylic‐acid under in‐vitro as well as in‐vivo conditions . Thromb. Res. , 74 ( 4 ) : 389 – 398 .
  • Nakanishi , K. and Kurata , M. 1960 . Density Measurement in dilute aqueous solution of polyvinyl alcohol . Bull. Chem. Soc. Japan , 33 ( 2 ) : 152 – 157 .
  • Nagy , M. 1992 . Vizsgalatok Polielektrolit Geleken, I. Poli(vinilalkohol, vinilszulfateszter so) Kopolimerek Kimeletes Szintezise es Analizise . Magy. Kem. Foly. , 98 : 18 – 24 .
  • Nagy , M. 2000 . A comparative and systematic thermodynamic study of aqueous solutions and hydrogels of homo‐ and copolymers of poly(vinyl alcohol) . Phys. Chem. Chem. Phys. , 2 ( 18 ) : 4265 – 4265 .
  • Matsumoto , M. and Ohyanagi , J. 1960 . J. Chem. High Polym. Jpn. , 17 : 17
  • Horvath‐Szabo , G. , Hoiland , H. and Hoghseth , E. 1994 . An automated apparatus for ultrasound velocity‐meas‐urements improving the pulse‐echo‐overlap method to a precision better than 0.5 ppm in liquids . Rev. Sci. Instrum. , 65 ( 5 ) : 1644 – 1648 .
  • Eisenberg , H. 1976 . Biological Macromolecules and Polyelectrolytes in Solution Oxford : Clarendron Press .
  • Durchschlag , H. 1986 . Thermodynamic Data for Biochemistry and Biotechnology Edited by: Hinz , H. J. 45 – 50 . Berlin : Springer .
  • Lewis , G. N. , Randall , M. , revised by Pitzer , K. S. and Brewer , L. 1961 . Thermodynamics New York : McGraw‐Hill Book Company, Inc .
  • Vikingstad , E. , Skauge , A. and Hoiland , H. 1979 . Effect of pres‐sure and temperature on the partial molal volume and compressibility of sodium decanoate micelles . J. Colloid Interface Sci. , 72 ( 1 ) : 59 – 67 .
  • Wu , C. S.C. and Yang , J. T. 1990 . Thermal unfolding of helices of a C‐peptide analog of ribonuclease‐A in sodium dodecyl‐sulfate solution . Biopolymers , 30 ( 3–4 ) : 381 – 388 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.