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Original Articles

Binary miscible blends of poly(methyl methacrylate)/poly(α-methyl styrene-co-acrylonitrile): II. rheological behavior during phase-separation

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Pages 271-287 | Received 15 Jun 2001, Accepted 26 Jul 2001, Published online: 19 Aug 2006

REFERENCES

  • Graebling , D. , Muller , R. and Palierne , J.F. 1993 . Linear Viscoelastic Behavior of Some Incompatible Polymer Blends in the Melt. Interpretation of Data with a Model of Emulsion of Viscoelastic Liquids . Macromolecules , 26 : 320 – 329 .
  • Graebling , D. and Muller , R. 1990 . Rheological Behavior of Poly(Dimethyl Siloxane)/Polyoxyethylene Blends in the Melt. Emulsion Model of Two Viscoealstic Liquids . J. Rheol. , 34 : 193 – 205 .
  • Lacroix , C. , Grmela , M. and Garreau , P.J. 1998 . Relationships Between Rheology and Morphology for Immiscible Copolymer Under Shear Flow . J. Rheol. , 42 : 41 – 62 .
  • Lee , H.M. and Park , O.O. 1994 . Rheology and Dynamics of Immiscible Polymer Blends . J. Rheol. , 38 : 1405 – 1425 .
  • Grizzuti , N. and Bifulco , O. 1997 . Linear Viscoelastic Behavior of Molten Polymer Blends: A Comparative Study of the Palierne and Lee and Park Models . Rheol. Acta , 36 : 406 – 428 .
  • Yamaguchi , M. , Nitta , K. , Miyata , H. and Masuda , T. 1997 . Rheological Properties for Binary Blends of i-PP and Ethylene-1-Hexene Copolymer . J. Appl. Polym. Sci. , 63 : 467 – 474 .
  • Palierne , J.F. 1990 . Linear Rheology of Viscoelastic Emulsions with Interfacial Tension . Rheol. Acta , 29 : 204 – 214 .
  • Lacroix , C. , Bousmina , M. , Carreau , P.J. , Favis , B.D. and Michel , A. 1996 . Properties of PETG/EVA Blends: I. Viscoelastic, Morphological and Interfacial Properties . Polymer , 14 : 2939 – 2947 .
  • Nassiet , V. , Cassagnau , P. , Allal , A. and Montfort , J.P. 1997 . Thermorheological Behavior of Polypropylene and Polycarbonate Inclusions in an Ethylene Copolymer Matrix . J. Appl. Polym. Sci. , 66 : 179 – 186 .
  • Han , J.H. , Choi-Feng , C. and Li , D.J. 1995 . Effect of Flow Geometry on the Rheology of Dispersed Two-Phase Blends of Polystyrene and Poly(Methyl Methacrylate) . Polymer , 12 : 2451 – 2462 .
  • Min , K. , White , J.L. and Fellers , J.F. 1984 . High Density Polyethylene/Polystyrene Blends: Phase Distribution Morphology, Rheological Measurements, Extrusion, and Melt Spinning Behavior . J. Appl. Polym. Sci. , 29 : 2117 – 2142 .
  • Utracki , L.A. 1991 . Two Phase Polymer Systems Munich : Hanser Publishers .
  • Utracki , L.A. 1989 . Two Phase Alloys and Blends Munich : Hanser Publishers .
  • Olabishi , O. , Robeson , L.M. and Shaw , M.T. 1988 . Polymer–Polymer Miscibility New York : Academic Press .
  • Utraki , L.A. 1989 . Polymer Alloys and Blends New York : Henser Publications .
  • Flory , P. 1971 . Principles of Polymer Chemistry Ithaca, New York : Cornell University .
  • Huggins , M.L. 1942 . Theory of Solution of High Polymers . J. Am. Chem. Soc. , 64 : 1712 – 1718 .
  • Gunton , J.D. , San Miguel , M. and Sahni , P.S. 1983 . Phase Transition and Critical Phenomena London : Academic Press .
  • Bates , F.S. , Muthukumar , M. , Wignall , G.D. and Fetters , L.J. 1988 . Thermodynamics of Isotopic Polymer Mixtures: Significance of Local Structural Symmetry . J. Chem. Phys. , 89 : 535 – 544 .
  • Okada , M. and Han , C.C.J. 1986 . Experimental Study of Thermal Fluctuation in Spinodal Decomposition of a Binary Polymer Mixture . Chem. Phys. , 85 : 5317 – 5327 .
  • Cahn , J.W. and Hilliard , J.E. 1958 . Free Energy of a Non Uniform System: I. Interfacial Free Energy . J. Chem. Phys. , 28 : 258 – 267 .
  • Hashimoto , T. , Itakura , M. and Shimidzu , N. 1986 . Late Stage Spinodal Decomposition of a Binary Polymer Mixture. II. Scaling Analysis on Q m (τ) and I mm (τ) . J. Chem. Phys. , 85 : 6773 – 6786 .
  • Cahn , J.W. 1965 . Phase Separation by Spinodal Decomposition in Isotropic Systems . J. Chem. Phys. , 42 : 93 – 99 .
  • Guo , W. and Higgins , J.S. 1991 . Miscibility and Kinetics pf Phase Separation in Polymer Blends of Tetra(-bisphenol-A polycarbonate) and Polystyrene . Polymer , 31 : 699 – 706 .
  • Binder , K. 1983 . Collective Diffusion, Nucleation, and Spinodal Decomposition in Polymer Mixtures . J. Chem. Phys. , 79 : 6387 – 6409 .
  • Hashimoto , T. , Kumaki , J. and Kawai , H. 1983 . Time-Resolved Light Scattering Studies on Kinetics of Phase Separation and Phase Dissolution of Polymer Blends. I. Kinetics of Phase Separation of a Binary Mixture of Polystyrene and Poly(Vinyl Methyl Ether) . Macromolecules , 16 : 641 – 648 .
  • Snyder , H.L. , Meakin , P. and Reich , S. 1983 . Dynamical Aspects of Phase Separation in Polymer Blends . Macromolecules , 16 : 757 – 762 .
  • Ajji , A. , Choplin , L. and Prud'Homme , R.E. 1988 . Rheology and Phase Separation in Polystyrene/Poly(Vinyl Methyl Ether) Blends . J. Polym. Sci. Part B—Phys. , 26 : 2279 – 2289 .
  • Ajji , A. , Choplin , L. and Prud'Homme , R.E. 1991 . Rheology of Polystyrene/Poly(Vinyl Methyl Ether) Blends Near the Phase Transition . J. Polym. Sci. Part B—Phys. , 29 : 1573 – 1578 .
  • Mani , S. , Malone , M.F. and Winter , H.H. 1992 . Influence of Phase Separation on the Linear Viscoelastic Behavior of a Miscible Polymer Blends . J. Rheol. , 36 : 1625 – 1649 .
  • Nesarikar , A.R. 1995 . Rheology of Polymer Blend Liquid–Liquid Phase Separation . Macrmolecules , 28 : 7202 – 7207 .
  • Vlassopoulos , D. 1996 . Rheology of Critical LCST Polymer Blends: Poly(Styrene-co-Maleic Anhydrite)/Poly(Methyl Methacrylate) . Rheol. Acta , 35 : 556 – 566 .
  • Madbouly , S.A. and Ougizawa , T. 2002 . Binary Miscible Blends of Poly(Methyl Methacrylate)/Poly(α-methyl styrene-co-acrylonitrile): I. Rheological Behavior . J. Macro. Sci. part B—Phys. , 41 : 255 – 269 .
  • Cross , M.M. 1979 . Relation Between Viscoelasticity and Shear-Thinking Behavior in Liquids . Rheol. Acta , 18 : 609 – 614 .
  • Bates , F.S. 1984 . Block Copolymers near the Microphase Separation Transition. 2. Linear Dynamic Mechanical Properties . Macromolecules , 17 : 2607 – 2613 .
  • Rosedale , J.H. and Bates , F.S. 1990 . Rheology of Order and Disorder Symmetric Poly(Ethylene Propylene)/Poly(Ethyl Ethylene) Diblock Copolymer . Macromolecules , 23 : 2329 – 2338 .
  • Fredrickson , G.H. and Larson , R.G. 1987 . Viscometric Properties of Block Polymer near a Critical Point . Macromolecules , 20 : 1897 – 1900 .
  • Fredrickson , G.H. 1986 . Non-equilibrium Structure of the Homogeneous Phase of Block Copolymers Under Steady Flow . J. Chem. Phys. , 85 : 5306 – 5313 .
  • Han , C.D. and Yang , H.H. 1987 . Rheological Behavior of Compatible Polymer Blends. I. Blends of Poly(Styrene-co-acrylonitrile) and Poly(ε-caprolactone) . J. Appl. Polym. Sci. , 33 : 1199 – 1220 .
  • Han , C.D. and Chuang , H.K. 1985 . Criteria for Rheological Compatibility of Polymer Blends . J. Appl. Polym. Sci. , 30 : 4431 – 4454 .
  • Chee , K.K. 1974 . Aspects of Polymer Melt Rheology . Abs. Int. B , 34 : 59378
  • Ajji , A. and Choplin , L. 1991 . Rheology and Dynamics Near Phase Separation in a Polymer Blends: Model and Scaling Analysis . Macromolecules , 24 : 5221 – 5223 .
  • Fredrickson , G.H. and Larson , R.G. 1987 . Viscoelasticity of Homogeneous Polymer Melts near a Critical Point . J. Chem. Phys. , 86 : 1553 – 1560 .
  • Kapnistos , M. , Hinichs , A. , Vlassopoulos , D. , Anastasiadis , S.H. , Stammer , A. and Wolf , B.A. 1996 . Rheology of a Lower Critical Solution Temperature Binary Polymer Blend in the Homogeneous, Phase-Separated, and Transitional Regimes . Macromolecules , 29 : 7155 – 7163 .
  • Vlassopoulos , D. , Koumoutsakos , A. and Anastasiadis , S.H. 1997 . Rheology and Phase Separation in a Model Upper Critical Solution Temperature Polymer Blends . J. Rheol. , 41 : 739 – 755 .
  • de Gennes , P.G. 1980 . Dynamics of Fluctuations and Spinodal decomposition in Polymer Blend . J. Chem. Phys. , 72 : 4756 – 4763 .
  • Furukawa , H. 1985 . A Dynamic Scaling Assumption for Phase Separation . Adv. Phys. , 34 : 703 – 750 .
  • Komura , S. , Osamura , K. , Fuji , H. and Takeda , T. 1985 . Time Evaluation of the Structure Function of Quenched Al–Zn and Al–Zn–Mg Alloys . Phys. Rev. B , 31 : 1278 – 1301 .
  • in press .
  • Sato , T. and Han , C.C. 1988 . Dynamics of Concentration Fluctuation in a Polymer Blend on Both Sides of the Phase Boundary . J. Chem. Phys. , 88 : 2057 – 2065 .
  • Mansour , A.A. 1995 . Dielectric Method for Detection of Phase Separation and Its Kinetics in TMPC/PS . Colloid Polym. Sci. , 273 : 524 – 532 .

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