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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 10
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Original Articles

A GENERAL ALTERNATIVE TO OBTAIN S.S-ACETALS USING TAFF, A BENTONITIC CLAY, AS THE CATALYST*

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Pages 1587-1597 | Received 24 Jul 2000, Published online: 02 Aug 2010

REFERENCES

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  • Miranda , R. , Ríos , H. , Salmón , M. , Cogordán , J. A. and Cabrera , A. 2000 . J. Appl. Cat. , TonsilActisil FF (TAFF), a commercial Mexican bentonitic clay, is easily availablefrom Tonsil Mexicana S.A.de C.V. Mexico City, Mexico at US$ 1.30/kg. Examinedwith x-ray fluorescence, this clay proved to have the following composition(in percent): SiO2, 74.5; Al2O3,9.3; MgO, 0.4; Fe2O3, 1.3; CaO,4.0; K2O, 0.4; TiO2, 0.4; H2O,9.7. When x-ray thermodiffractograms were run, the laminar structure was foundto be unstable above 150°C. Quartz and cristobalite are also importantcomponents in the clay composition as observed by x-ray diffraction. The correspondingBET surface area was 198.718m2g−1and the pore volume and average pore diameter were 32.04×10−2cm3 g−1 and 77.8AÅ, respectively. It is worth mentioning that a detailed characterizationof the clay (29Si and 27AlMAS-NMR, SEM, IR-Py, DTA, and TG, Ho) is under review
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