Conversion of Alkynes into α,α-Dichloro Ketones and α,α-Dichlorodimethyl Ketals Using Trichloroisocyanuric Acid

Prof. Gene A. Hiegel Department of Chemistry and Biochemistry, California State University, Fullerton, California, USACorrespondence[email protected]

Christopher D. Bayne Department of Chemistry and Biochemistry, California State University, Fullerton, California, USA

Brendt Ridley Department of Chemistry and Biochemistry, California State University, Fullerton, California, USA

References

Kim , K.K. , Kim , J.N. , Kim , K.M. , Kim , H.R. and Ryu , E.K. 1992 . One-pot synthesis of α,α-dichloroketones with alkynes using the N,N-dimethylformamide/hydrogen chloride/potassium monoperoxysulfate system . Chemistry Letters , : 603 – 604 . and references therein for other less effective methods
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Reed , S.F. Jr. 1965 . The preparation of α,α-dichloroketones . J. Org. Chem. , 30 ( 7 ) : 2195 – 2198 .
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Hiegel , G.A. 1995 . “ Trichloroisocyanuric acid ” . In Encyclopedia of Reagents for Organic Synthesis Edited by: Paquette , L.A. Vol. 7 , 5072 – 5073 . Chichester, Sussex, , England : Wiley . For synthetic applications of 1 see
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Wet iodide-starch test paper was used to test for the presence of oxidizing power
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Reported m.p. 66–67.5°C, Ref. [2]
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Conversion of Alkynes into α,α-Dichloro Ketones and α,α-Dichlorodimethyl Ketals Using Trichloroisocyanuric Acid

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Conversion of Alkynes into α,α-Dichloro Ketones and α,α-Dichlorodimethyl Ketals Using Trichloroisocyanuric Acid

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