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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 14
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Original Articles

Clay Supported Ammonium Nitrate “Clayan”: A New Reagent for Selective Nitration of Arenes

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Pages 2497-2503 | Received 14 Nov 2002, Published online: 20 Aug 2006

References

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  • Clayan is prepared following the earlier procedure: To a solution of ammonium nitrate (5 g) in distilled water (70 mL) was added montmorillonite K10 (Aldrich Chemical Co.) 5 g in portions at room temperature and the suspension stirred for 1 h. water is removed using rotary evaporator at 50–60°C under reduced pressure and thew resulting solid was dried under vacuum at 40°C for 2 h and the reagent stored in a stoppered bottle. Detailed experimental procedure may be obtained from the Indian patent No: 56/Del/99
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