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Original Articles

THERMODYNAMICS OF THE EXTRACTION OF METAL IONS BY DIALKYL-SUBSTITUTED DIPHOSPHONIC ACIDS. II. THE U(VI) AND Sr(II) CASE

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Pages 1017-1036 | Received 15 Jun 2001, Published online: 15 Feb 2007

REFERENCES

  • Otu , E. O. and Chiarizia , R. in press . Temperature Effects in the Extraction of Metal Ions by Dialkyl-Substituted Diphosphonic Acids. Part I: The Am(III) Case . Solv. Extr. Ion Exch. ,
  • Horwitz , E. P. , Chiarizia , R and Dietz , M. L. DIPEX: A New Extraction Chromatographic Material for the Separation and Preconcentration of Actinides from Aqueous Solutions. React. Funct. Polym. 1997,33, 25–36; and Method for the Chromatographic Separation of Cations from Aqueous Samples . US Patent 5,651,883 . July 29, 1997 .
  • Chiarizia , R , Horwitz , E. P. , Alexandratos , S. D. and Gula , M. J. 1997 . Diphonix Resin: A Review of its Properties and Applications . Sep. Sci. Technol. , 32 : 1 – 35 .
  • Chiarizia , R. , Horwitz , E. P. , Rickert , P. G. and Herlinger , A. W. 1996 . Metal Extraction by Alkyl Substituted Diphosphonic Acids. Part 1: P,P′-Di(2-ethylhexyl) Methanediphosphonic Acid . Solv. Extr. Ion Exch. , 14 : 773 – 792 .
  • Chiarizia , R. , Herlinger , A. W. and Horwitz , E. P. 1997 . Metal Extraction by Alkyl Substituted Diphosphonic Acids. Part 3: P,P′-Di(2-ethylhexyl) Ethanediphosphonic Acid Solvent Extraction Study . Solv. Extr. Ion Exch. , 15 : 417 – 432 .
  • Chiarizia , R. , Herlinger , A. W. , Cheng , Y. D. , Ferraro , J. R. , Rickert , P. G. and Horwitz , E. P. 1998 . Metal Extraction by Alkyl Substituted Diphosphonic Acids. Part 4: P,P′-Di(2-ethylhexyl) Butanediphosphonic Acid . Solv. Extr. Ion Exch. , 16 : 505 – 526 .
  • Herlinger , A. W. , Ferraro , J. R. , Chiarizia , R. and Horwitz , E. P. 1997 . An Investigation of P,P′-Di(2-ethylhexyl) Methanediphosphonic Acid and Some of its Metal Complexes . Polyhedron , 16 : 1843 – 1854 .
  • Herlinger , A. W. , Chiarizia , R. , Ferraro , J. R. , Rickert , P. G. and Horwitz , E. P. 1997 . Metal Extraction by Alkyl Substituted Diphosphonic Acids. Part 2: P,P′-Di(2-ethylhexyl) Ethanediphosphonic Acid Aggregation and IR Study . Solv. Extr. Ion Exch. , 15 : 401 – 416 .
  • Chiarizia , R. , Barrans , R. E. , Ferraro , J. R. , Herlinger , A. W. and McAlister , D. R. 2001 . Aggregation of Dialkyl-Substituted Diphosphonic Acids and its Effect on Metal Ion Extraction . Sep. Sci. Technol. , 36 ( 5&6 ) : 687 – 708 .
  • Chiarizia , R. , Urban , V. , Thiyagarajan , P. and Herlinger , A. W. 1999 . Aggregation of Complexes Formed in the Extraction of Selected Metal Cations by P,P′-Di(2-ethylhexyl) Methanediphosphonic Acid . Solv. Extr. Ion Exch. , 17 : 113 – 132 .
  • Chiarizia , R. , Urban , V. , Thiyagarajan , P. and Herlinger , A. W. 1999 . SANS Study of Aggregation of Complexes Formed in the Extraction of Selected Metal Cations by P,P′-di(2-ethylhexyl) Ethane- and Butane-Diphosphonic Acids . Solv. Extr. Ion Exch. , 17 : 1171 – 1194 .
  • Högfeldt , E. , Chiarizia , R. , Danesi , P. R. and Soldatov , V. S. 1981 . Structure and Ion Exchange Properties of Dinonylnaphthalenesulfonic Acid and its Salts . Chem. Sci. , 18 : 13 – 44 .
  • Lumetta , G. J. , Moyer , B. A. , Johnson , P. A. and Wilson , N. M. 1991 . Extraction of Zn(II) Ion by Didodecylnaphthalene Sulfonic Acid (HDNNS) in Carbon Tetrachloride: the Role of Aggregation . Solv. Extr. Ion Exch. , 9 : 155 – 176 .
  • Moyer , B. A. , Baes , C. F. Jr. , Case , G. N. , Lumetta , G. J. and Wilson , N. M. 1993 . Equilibrium Analysis of Aggregation Behavior in the Solvent Extraction of Cu(II) from Sulfuric Acid by Didodecylnaphthalene Sulfonic Acid . Sep. Sci. Technol. , 28 : 81 – 113 .
  • Peppard , D. F. , Mason , G. W. , Driscoll , W. J. and Sironen , R. J. 1958 . Acidic Esters of Orthophosphoric Acid as Selective Extractants for Metallic Cations. Tracer Studies . J. Inorg. Nucl. Chem. , 7 : 276 – 285 .
  • Rao , G. S. , Mason , G. W. and Peppard , D. F. 1966 . Extraction of Selected Metallic Cations by Di-acidic Phosphorus-Based Extractants, XPO(OH)2, in a Ketone Diluent . J. Inorg. Nucl. Chem. , 28 : 887 – 897 .
  • Mason , G. W. , McCarty , S. and Peppard , D. F. 1962 . Synergistic Effects in the Extraction of Selected Metallic Cations by Mono(2-ethylhexyl) Phosphoric Acid . J. Inorg. Nucl. Chem. , 24 : 967 – 977 .
  • Chiarizia , R. , Gatrone , R. C. and Horwitz , E. P. 1995 . Am(III) and Eu(III) Extraction by Aliquat 336 and Benzyl Substituted Quaternary Ammonium Salts from Nitrate and Thiocyanate Solutions . Solv. Extr. Ion Exch. , 13 : 615 – 645 .
  • Kotrlý , S. and Šůcha , L. 1985 . Handbook of Chemical Equilibria in Analytical Chemistry 116 – 117 . New York : J. Wiley & Sons .
  • Kusik , C. L. and Meissner , H. P. 1978 . Electrolyte Activity Coefficients in Inorganic Processing, in Fundamental aspects of Hydrometallurgical Processes , AIChE Symposium Series 173 14 – 20 .
  • Westland , A. D. and Otu , E. O. 1991 . The Thermodynamics of Extraction of Some Lanthanides and Other Ions by 2-Ethylhexylhydrogen-P-phenylphosphonate . Solv. Extr. Ion Exch. , 9 : 607 – 621 .
  • Otu , E. O. and Westland , A. D. 1990 . The Thermodynamics of Extraction of Some Lanthanides and Other Ions by Dinonylnaphthalenesulphonic Acid . Solv. Extr. Ion Exch. , 8 : 827 – 842 .
  • Otu , E. O. 1998 . The Effect of Temperature on the Synergistic Extraction of Thorium(IV) and Uranium(VI) by 2-Ethylhexyl Phenylphosphonic Acid and Micelles of Dinonylnaphthalenesulphonic Acid . Solv. Extr. Ion Exch. , 16 : 1161 – 1176 .
  • Otu , E. O. 1999 . The Thermodynamics of Synergistic Extraction of Bismuth by 2-Ethylhexyl Phenylphosphonic Acid and Micelles of Dinonylnaphtalenesulfonic Acid . Thermochimica Acta , 329 : 117 – 121 .
  • Marcus , Y. and Kertes , S. 1969 . Extraction by Compound Formation, in Ion Exchange and Solvent Extraction of Metal Complexes 545 New York : J. Wiley & Sons .
  • McAlister , D. R. , Dietz , M. L. , Chiarizia , R. , Zalupski , P. R. and Herlinger , A. W. in press . Metal Extraction by Silyl-Substituted Diphosphonic Acids. Part 2. Effect of Alkylene Bridge Length on Aggregation and Metal Ion Extraction Behavior . Sep. Sci. Technol. ,
  • Choppin , G. R. and Morgenstern , A. 2000 . Thermodynamics of Solvent Extraction . Solv. Extr. Ion Exch. , 18 : 1029 – 1049 .
  • Danesi , P. R. , Chiarizia , R. , Raieh , M. A. and Scibona , G. 1975 . Enthalpy and Entropy Variations in the Liquid Cation Exchange of Some Lanthanide Ions by Dinonylnaphthalenesulfonic Acid (HD) and Bis(2-ethylhexyl) Phosphoric Acid (HDEHP) . J. Inorg. Nucl. Chem. , 37 : 1489 – 1493 .

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