SYNTHESIS AND CHARACTERIZATION OF METAL COMPLEXES OF P,P′-DI[3-(TRIMETHYLSILYL)-1-PROPYL] METHYLENEDIPHOSPHONIC ACID

REFERENCES

• Rizkalla , E.N. 1983 . Metal Chelates of Phosphonate-Containing Ligands . Rev. Inorg. Chem. , 5 : 223 – 304 .
   Google Scholar
• Nash , K.L. 1994 . Actinide-Phosphonate Complexes in Aqueous Solutions . J. Alloys Compd. , 213 : 300 – 304 .
   Google Scholar
• Nash , K.L. , Rao , L.F. and Choppin , G.R. 1995 . Calorimetric and Laser-Induced Fluorescence Investigation of the Complexation Geometry of Selected Europium-Gem-Diphosphonate Complexes in Acid Solutions . Inorg. Chem. , 34 : 2753 – 2758 .
   Google Scholar
• Hines , J.J. , Diamond , H. , Young , J.E. , Malac , W. , Chiarizia , R. and Horwitz , E.P. 1995 . Decontamination of Waste Solution From Davies-Gray Analyses in a Pilot-Facility for Process Development . Separation Sci. & Tech. , 30 : 1373 – 1384 .
   Google Scholar
• Chiarizia , R. , Horwitz , E.P. , Alexandratos , S.D. and Gula , M.J. 1995 . Diphonix® Resin: A Review of its Properties and Applications . Separation Sci. & Tech. , 32 : 1 – 35 .
   Google Scholar
• Chiarizia , R. , Horwitz , E.P. , Rickert , P.R. and Herlinger , A.W. 1996 . Metal Extraction by Alkyl-Substituted Diphosphonic Acids. Part 1. P,P′-Di(2-ethylhexyl) Methanediphosphonic Acid . Solv. Extr. Ion Exch. , 14 : 773 – 792 .
   Google Scholar
• Chiarizia , R. , Herlinger , A.W. and Horwitz , E.P. 1997 . Metal Extraction by Alkyl-Substituted Diphosphonic Acids. Part 3. P,P′-Di(2-ethylhexyl) Ethanediphosphonic Acid Solvent Extraction Study . Solv. Extr. Ion Exch. , 15 : 417 – 431 .
   Google Scholar
• Chiarizia , R. , Herlinger , A.W. , Cheng , Y.D. , Ferraro , J.R. , Rickert , P.G. and Horwitz , E.P. 1998 . Metal Extraction by Alkyl-Substituted Diphosphonic Acids. Part 4. P,P′-Di(2-ethylhexyl) Butanediphosphonic Acid . Solv. Extr. Ion Exch. , 16 : 505 – 526 .
   Google Scholar
• Stepinski , D. and Herlinger , A.W. 2002 . A Facile and High Yield Synthesis of Symmetric Dialkyl-Substituted Methylenebisphosphonic Acids . Synth. Commun. , 32 in press
   Google Scholar
• Desimone , J.M. , Maury , E.E. , Menceloglu , Y.Z. , McClain , J.B. , Romack , T.J. and Combes , J.R. 1994 . Dispersion Polymerizations in Supercritical Carbon Dioxide . Science , 265 : 356 – 359 .
   Google Scholar
• Phelps , C.L. , Smart , N.G. and Wai , C.M. 1996 . Past, Present and Possible Future Applications of Supercritical Fluid Technology . J. Chem. Ed. , 73 : 1163 – 1168 .
   Google Scholar
• McAlister , D.R. , Dietz , M.L. , Chiarizia , R. and Herlinger , A.W. 2001 . Metal Ion Extraction by Silyl-Substituted Diphosphonic Acids. Part 1. P,P′-Di[3-(trimethylsilyl)-1-propylene] Methylene- and Ethylene-Diphosphonic Acids Separation Sci. & Tech. , in press
   Google Scholar
• Herlinger , A.W. , Ferraro , J.R. , Chiarizia , R. and Horwitz , E.P. 1997 . An Investigation of P,P′-Di(2-ethylhexyl) Methanediphosphonic Acid and Some of Its Metal Complexes . Polyhedron , 16 : 1843 – 1854 .
   Google Scholar
• Brennecke , J. Department of Chemical Engineering, University of Notre Dame, private communication
   Google Scholar
• Herlinger , A.W. , Ferraro , J.R. , Garcia , J.A. and Chiarizia , R.A . 1998 . Far-Infrared Study and Investigation of the Difference Between the Asymmetric and Symmetric POO− Stretching Frequencies in Metal Diphosphonate Complexes . Polyhedron , 17 : 1471 – 1475 .
   Google Scholar
• Socrates , G. 1994 . Infrared Characteristic Group Frequencies 188 – 193 . New York : John Wiley & Sons . and 219
   Google Scholar
• Ferraro , J.R. , Herlinger , A.W. and Chiarizia , R. 1998 . Correlation of the Asymmetric and Symmetric POO− Frequencies with the Ionic Potential of the Metal Ion in Compounds of Organophosphorus Acid Extractants: A Short Review . Solv. Extr. Ion Exch. , 16 : 775 – 794 .
   Google Scholar
• Thomas , L.C. 1974 . The Identification of Functional Groups in Organophosphorus Compounds 23 – 46 . New York : Academic Press .
   Google Scholar
• Nakamoto , K. 1970 . Infrared Spectra of Inorganic and Coordination Compounds , 2 206 – 207 . New York : John Wiley & Sons: . and 248–249
   Google Scholar
• Cotton , S. 1991 . Lanthanides and Actinides 11 New York : Oxford University Press . and 33–34
   Google Scholar
• Nash , K.L. , Rogers , R.D. , Ferraro , J.R. and Zhang , J. 1998 . Lanthanide Complexes with 1-Hydroxyethane-1,1-diphosphonic Acid: Solvent Organization and Coordination Geometry in Crystalline and Amorphous Solids . Inorg. Chim. Acta , 269 : 211 – 223 .
   Google Scholar
• Chiarizia , R. , Urban , V. , Thiyagarajan , P. and Herlinger , A.W. 1998 . Aggregation of P,P′-Di(2-ethylhexyl) Methanediphosphonic Acid and Its Fe(III) Complexes . Solv. Extr. Ion Exch. , 16 : 1257 – 1278 .
   Google Scholar
• Chiarizia , R. , Urban , V. , Thiyagarajan , P. and Herlinger , A.W. 1999 . SANS Study of the Complexes Formed by Selected Metal Cations and P,P′-Di(2-ethylhexyl) Ethane- and Butanediphosphonic Acids . Solv. Extr. Ion Exch. , 17 : 1171 – 1194 .
   Google Scholar
• Carlin , R.L. 1986 . Magneto Chemistry 3 New York : Springer-Verlag .
   Google Scholar
• Burger , K. 1973 . Coordination Chemistry: Experimental Methods 219 – 226 . Cleveland : CRC Press .
   Google Scholar
• Belanzoni , P. , Re , N. , Rosi , M. , Sgamellotti , A. , Baerends , E.J. and Floriani , C. 1996 . Electronic Structure, Heisenberg Coupling Constants, and Metal-Metal Bond in Dimeric Iron(II) Organometallics with the Metal Centers at Variable Distances: A Density Functional Approach . Inorg. Chem. , 35 : 7776 – 7785 .
   Google Scholar
• Griffith-Dzielawa , J.A. , Barrans , R.E. , McAlister , D.R. , Dietz , M.L. and Herlinger , A.W. 2000 . Synthesis and Characterization of Di[3-(trimethylsilyl)-1-propylene] Alkylenediphosphonic Acids . Synth. Comm. , 30 : 2121 – 2132 .
   Google Scholar