SYNTHESIS, CHARACTERISATION, CATALYTIC, AND BIOCIDAL STUDIES OF RUTHENIUM(III) COMPLEXES WITH THIOSEMICARBAZONES OF β-DIKETOESTERS

REFERENCES

• Fletcher , S.R. and Skapski , A.C. 1972 . Crystal and Molecular Structure of Bis- (pyridine-2-thiolato)bis(triphenylphosphine)ruthenium(II) . J. Chem. Soc. Dalton. Trans. , : 635 – 639 .
   Google Scholar
• Koch , S.A. 1983 . Ruthenium and Osmium Thiolate Compounds . J. Am. Chem. Soc. , 105 : 3362 – 3363 .
   Google Scholar
• Mahapatra , A.K. , Datta , S. , Goswami , S. , Mukherjee , M. , Mukherjee , A.K. and Chakravorty , A. 1986 . Ruthenium Complexes of NS- and C,N,S-Coordinating Azo Ligands Synthesis: Reactions and Structure . Inorg. Chem. , 25 : 1715 – 1721 .
   Google Scholar
• Greaney , M.A. , Coyle , C.L. , Harmer , M.A. , Jordan , A. and Stiefel , E.I. 1989 . Synthesis and Characterisation of Mononuclear and Dinuclear Bis(2,2′-bipyridine)ruthenium(II) Complexes Containing Sulfur-Donor Ligands . Inorg. Chem. , 28 : 912 – 920 .
   Google Scholar
• Chattopadhyay , S.K. and Ghosh , S. 1987 . A Study of Ruthenium(II) Complexes of Some Selected N-S Donors . Inorg. Chim. Acta , 131 : 15 – 20 .
   Google Scholar
• Kruger , H.-J. and Holm , R.H. 1989 . Chemical and Electrochemical Reactivity of Nickel(II,I) Thiolate Complexes: Examples of Ligand-Based Oxidation and Metal-Centered Oxidative Addition . Inorg. Chem. , 28 : 1148 – 1155 .
   Google Scholar
• Dearling , J.L. , Blower , J. and Philip , J. 1998 . Redox-Active Metal Complexes for Imaging Hypoxic Tissues: Structure-Activity Relationships in Copper(II) Bis(thiosemicarbazone) Complexes . Chem. Commun. , 22 : 2531 – 2532 .
   Google Scholar
• West , D.X. , Bain , G.A. , Butcher , R.J. , Jasinski , J.P. , Li , Y. , Pozdniakiv , R.Y. , Toscano , R.A. and Ortega , S.H. 1996 . Structural Studies of Three Isomeric Forms of Heterocyclic N-(4)-Substituted Thiosemicarbazones of Nickel(II) Complexes . Polyhedron , 15 : 665 – 674 .
   Google Scholar
• Garcia-Tojal , J. , Lezama , L , Pizarro , J , Insausti , M , Arriortua , M.I. and Rojo , T. 1999 . Spectroscopic and Magnetic Properties of Copper(II) Complexes Derived From Pyridine-2-carbaldehyde Thiosemicarbazone. Structures of [Cu(NO3)(C7H8N4S)(H2O)]NO3 and [Cu(NCS)(C7H8-N4S)2] . Polyhedron , 18 ( 27 ) : 3703 – 3711 .
   Google Scholar
• Bindu , P. , Kurup , M.R.P. and Satyakeerty , T. R. 1999 . EPR, Cyclic Voltammetric and Biological Activities of Copper(II) Complexes of Salicylaldehyde N-(4)-Substituted Thiosemicarbazone and Heterocyclic Bases . Polyhedron , 18 : 321 – 331 .
   Google Scholar
• Ferrari , M.B. , Capacchi , S. , Pelosi , G. , Reffo , G. , Tarasconi , P. , Albertini , R. , Pinelli , S. and Lunghi , P. 1999 . Synthesis Structural Characterisation and Biological Activity of Helicin Thiosemicarbazone Monohydrate and a Copper(II) Complex of Salicylaldehyde Thiosemicarbazone . Inorg. Chim. Acta , 286 : 134 – 141 .
   Google Scholar
• El-Fetoh , S.H.A. , Eid , A.E. , Abd El-Kareem , A.I. and Wassel , M.A. 2000 . Synthesis Analytical and Biological Studies of 2-Hydroxy-1-naphthaldehyde Thiosemicarbazone Complexes . Synth. React. Inorg. Met.–Org. Chem. , 30 : 513 – 532 .
   Google Scholar
• Ortmans , I. , Moucheron , C. and Mesmacker , A.K.-D. 1998 . Ruthenium(II) Polypyridine Complexes with a High Oxidation Power. Comparison between Their Photoelectrochemistry with Transparent SnO2 and Their Photochemistry with Deoxyribonucleic Acids . Coord. Chem. Rev. , 168 : 233 – 272 .
   Google Scholar
• Islam , A. , Ikeda , N. , Nozak , K. , Okamoto , Y. , Gholamkhass , B. , Yoshimura , A. and Ohno , T. 1998 . Non-Radiative Process of Excited CT States of Ru(II) and Pt(II) Compounds and Excited d-d States of Rh(III) Compounds in the Solid State and Higher Temperature . Coord. Chem. Rev. , 171 : 355 – 364 .
   Google Scholar
• Pramanik , Chand N. and Bhattacharya , S. 1999 . Synthesis Characterisation and Redox Properties of Mono- and Bis-β-Diketonate Ruthenium Complexes . Transition Met. Chem. , 24 : 95 – 99 .
   Google Scholar
• Basuli , F. , Das , A.K. , Mostafa , G. , Peng , S.M. and Bhattacharya , S. 2000 . Chemistry of Ruthenium with Some Phenolic Ligands: Synthesis Structure and Redox Properties . Polyhedron , 19 : 1663 – 1672 .
   Google Scholar
• Basuli , F. , Peng , S.M. and Bhattacharya , S. 2000 . Unusual Coordination Mode of Thiosemicarbazone Ligands. A Search for the Origin . Inorg. Chem. , 39 : 1120 – 1127 .
   Google Scholar
• Thangadurai , T.D. and Natarajan , K. 2000 . New Ruthenium(III) Complexes Containing Tetradentate Schiff Bases and Their Antibacterial Activity . Transition Met. Chem. , 25 : 347 – 351 .
   Google Scholar
• Viswanathamurthi , P. , Dharmaraj , N. and Natarajan , K. 2000 . Ruthenium(III) Complexes Containing Monofunctional Bidentate Schiff Bases . Synth. React. Inorg. Met. –Org. Chem. , 30 : 1273 – 1285 .
   Google Scholar
• Dharmaraj , N. , Viswanathamurthi , P. and Natarajan , K. 2001 . Ruthenium(II) Complexes Containing Bidentate Schiff Bases and Their Antifungal Activity . Transition Met. Chem. , 26 : 105 – 109 .
   Google Scholar
• Cogan , D.A. , Liu , G.C. , Kim , K.J. , Backes , B.J. and Ellman , J.A. 1998 . Catalytic Asymmetric Oxidation of Tert-Butyl Disulfide. Synthesis of Tert-Butanesulfinamides Tert-Butyl Sulfoxides and Tert-Butanesulfinimines . J. Am. Chem. Soc. , 120 : 8011 – 8019 .
   Google Scholar
• Liu , G.C. , Cogan , D.A. and Ellman , J.A. 1997 . Catalytic Asymmetric Synthesis of Tert-Butanesulfinamide. Application to the Asymmetric Synthesis . J. Am. Chem. Soc. , 119 : 9913 – 9914 .
   Google Scholar
• Chatt , J. , Leigh , G. , Mingos , D.M.P. and Paske , R.J. 1968 . Complexes of Osmium Ruthenium Rhenium and Indium Halides with Some Tertiary Monophosphines and Monoarsines . J. Chem. Soc. (A) , : 2636 – 2641 .
   Google Scholar
• Thangadurai , T.D. and Natarajan , K. 2001 . Synthesis and Characterisation of New Ruthenium(III) Complexes Containing Tetradentate Schiff Bases . Synth. React. Inorg. Met. –Org. Chem. , 31 : 549 – 568 .
   Google Scholar
• Natarajan , K. , Poddar , R.K. and Agarwala , U. 1977 . Mixed Complexes of Ruthenium(III) and Ruthenium(II) with Triphenylphosphine and Triphenylarsine and Other Ligands . J. Inorg. Nucl Chem. , 39 : 431 – 435 .
   Google Scholar
• Jayasree , S. and Aravindakshan , K.K. 1993 . Structural and Antitumour Studies of Metal Complexes with Thiosemicarbazones of β-Diketoesters . Polyhedron , 12 : 1187 – 1192 .
   Google Scholar
• Vogel , A.I. 1989 . Textbook of Practical Organic Chemistry , 5 London : ELBS .
   Google Scholar
• Deepa , K.P. and Aravindakshan , K.K. 2000 . Synthesis Characterisation and Thermal Studies of Thiosemicarbazones of N-Methyl- and N-Ethyl Acetoacetanilide . Synth. React. Inorg. Met.–Org. Chem. , 30 : 1601 – 1616 .
   Google Scholar
• Chinnusamy , V. and Natarajan , K. 1993 . Ruthenium(II) and Rhodium(I) Triphenylphosphine Complexes Containing Semicarbazone and Thiosemicarbazone . Synth. React. Inorg. Met.–Org. Chem. , 23 : 889 – 905 .
   Google Scholar
• Ballhausen , C.J. 1962 . Ligand Field Theory New York : McGraw Hill .
   Google Scholar
• Lever , A.B.P. 1984 . “ Electronic Spectra of dn Ions ” . In Inorganic Electronic Spectroscopy , 2 376 – 611 . New York : Elsevier .
   Google Scholar
• Dharmaraj , N. and Natarajan , K. 1997 . Synthesis Characterisation Electrochemistry and Biological Activity of Ruthenium(III) Complexes Containing NS Donor Ligands and Triphenylphosphine or Triphenylarsine . Synth. React. Inorg. Met.–Org. Chem. , 27 : 601 – 618 .
   Google Scholar
• Khan , M.M.T. , Srinivas , D. , Kureshy , R.I. and Khan , N.H. 1990 . Synthesis Characterisation and EPR Studies of Stable Ruthenium(III) Schiff Base Chloro and Carbonyl Complexes . Inorg. Chem. , 29 : 2320 – 2326 .
   Google Scholar
• Medhi , O.K. and Agarwala , U. 1980 . Electron Spin Resonance Studies of Some Ruthenium(III) Complexes . Inorg. Chem. , 19 : 1381 – 1383 .
   Google Scholar
• Hoshino , Y. , Yukawa , Y. , Maruyama , T. , Endo , A. , Shimizu , K. and Sato , G.P. 1990 . Preparation Characterisation and Electrochemical Properties of Mixed-Ligand Ruthenium(III) and Ruthenium(II) Complexes with Two Kinds of β-Diketones . Inorg. Chim. Acta , 174 : 41 – 51 .
   Google Scholar
• Heinze , J. 1984 . Cyclic Voltammetry–“Electrochemical Spectroscopy” . Angew. Chem. Int. Ed. Engl. , 23 : 831 – 847 .
   Google Scholar
• Wallace , A.W. , Murphy , W.R. Jr. and Peterson , J.D. 1989 . Electrochemical and Photophysical Properties of Mono- and Bimetallic Ruthenium(II) Complexes . Inorg. Chim. Acta , 166 : 47 – 54 .
   Google Scholar
• Bond , A.M. , Colton , R. and Mann , D.R. 1990 . Comparison of the [MIV(RR′dtc)3]+/MIII(RR′dtc)3 and [MIV(Et2dsc)3]+/MIII(Et2dsc)3 (M=Co, Rh, Ir; dtc=Dithiocarbamate dsc=Diselenocarbamate) Redox Couples and the Reactivity of the Oxidation State IV Complexes in Solution and in the Gas Phase as Studied by Electrochemical and Mass Spectrometric Techniques . Inorg. Chem. , 29 : 4665 – 4671 .
   Google Scholar
• Basu , A. , Kasar , T.G. and Sapre , N.Y. 1988 . Synthesis Spectral and Electrochemical Properties of Di-2-pyridyl Ketone Complexes of Ruthenium and their Reactions . Inorg. Chem. , 27 : 4539 – 4542 .
   Google Scholar
• Viswanathamurthi , P. and Natarajan , K. 1998 . Synthesis and Characterisation of Ruthenium(III) Complexes Containing Triphenylphosphine/Arsine and Schiff Bases . Synth. React. Inorg. Met.–Org. Chem. , 28 : 437 – 447 .
   Google Scholar
• El-Hendawy , A.M. , Al-Kubaisi , A.H. and Al-Madfa , H.A. 1997 . Ruthenium(II) and Ruthenium(III) Bipyridine Complexes and Their Catalytic Oxidation Properties for Organic Compounds . Polyhedron , 16 : 3039 – 3045 .
   Google Scholar
• Chatterjeea , D. , Mitra , A. and Roy , B.C. 2000 . Oxidation of Organic Substrates Catalysed by a Novel Mixed-Ligand Ruthenium(III) Complex . J. Mol. Cat. , 161 : 17 – 21 .
   Google Scholar
• Kim , J.-Y. , Jun , M.-J. and Lee , W.-Y. 1996 . Catalytic Activities of New Arsine-Dihydrido Ruthenium(II) Complexes in the Homogeneous Hydrogenation of Aldehyde . Polyhedron , 15 : 3787 – 3793 .
   Google Scholar
• Colins , C.H. and Lyne , P.M. 1970 . Microbial Methods 422 Baltimore : University Park Press .
   Google Scholar