51
Views
2
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis, Characterization, and Fluorescent Properties of Ln(III), Ln(III)–Zn(II) (Ln = Gd, Eu), and Eu(III)–Cu(II) Cryptates

, &
Pages 1701-1715 | Received 12 Sep 2002, Accepted 09 Jun 2003, Published online: 15 Feb 2007

References

  • Alexander , V. 1995 . Design and synthesis of macrocyclic ligands and their complexes of lanthanides and actinides . Chem. Rev. , 95 : 237 – 342 .
  • Bunzli , J. C.G. and Piguet , C. 1999 . Lanthanide‐containing molecular and supermolecular polymetallic functional assemblies . Chem. Soc. Rev. , 28 : 347 – 358 .
  • Alpha , B. and Lehn , J. M. 1987 . Energy transfer luminescence of europium(III) and terbium(III) cryptates of macrobicyclic polypyridine ligands . Angew. Chem. Int., Ed. Engl. , 26 ( 3 ) : 266 – 267 .
  • Piguet , C. , Edder , C. , Rigault , S. , Bernardinelli , G. , Bunzli , J.‐C. G. and Hopfgartner , G. 2000 . Isolated d–f pairs in superamolecular complexes with tunable structural and electronic properties . J. Chem. Soc., Dalton Trans. , 22 : 3999 – 4008 .
  • Hamacek , J. , Blanc , S. , Elhabiri , M. , Leize , E. , Dorsselaer , A. V. , Piguet , C. and Albrecht‐Gary , A.‐M. 2003 . Self‐assembly mechanism of a bimetallic europium triple‐stranded helicate . J. Am. Chem. Soc. , 125 : 1541 – 1550 .
  • Rodriguez‐Cortnas , R. , Avecilla , F. , Platas‐Iglesias , C. , Imbert , D. , Bunzli , J. C.G. , Blas , A. D. and Rodriguez‐Blas , T. 2002 . Structure and photophysical properties of heterobimetallic 4f‐Zn iminophenolate cryptates . Inorg. Chem. , 41 : 5336 – 5349 .
  • Tsang , J. S.W. , Neverov , A. A. and Brown , R. S. 2003 . La3 +‐catalyzed methanolysis of hydroxypropyl‐p‐nitrophenyl phosphate as a model for the RNA transesterification reaction . J. Am. Chem. Soc. , 125 : 1159 – 1566 .
  • Aime , S. , Batta , M. , Fasano , M. and Terreno , E. 1998 . Lanthanide(III) chelates for NMR biomedical application . Chem. Soc. Rev. , 27 : 19 – 30 .
  • Nikolov , P. and Timtcheva , I. 2002 . Photophysical properties of some derivatives of 3‐arylmethylene‐1‐(3H)‐isobenzofuranone indication of intermolecular hydrogen‐bond formation in the singlet excited state . J. Photochem. Photobio, A Chem. , 131 : 23 – 26 .
  • Parker , D. , Dickins , R. S. , Puschmann , H. , Crossland , C. and Howard , J. A.K. 2002 . Being excited by lanthanide coordination complexes: aqua species, chirality, excited‐state chemistry and exchange dynamics . Chem. Rev. , 102 : 1977 – 2010 .
  • Ghosh , P. , Bharadwaj , P. K. , Ghosh , J. and Roy , S. 1997 . Transition metal(II)/(III), Eu(III) and Tb(III) ions induced molecular photonic OR gates using trianthryl cryptands of varying cavity dimension . J. Am. Chem Soc. , 118 : 11903 – 11909 .
  • Archer , R. D. and Chen , H. 1998 . Synthesis, characterization, and luminescence of europium(III) Schiff base complexes . Inorg. Chem. , 37 : 2089 – 2095 .
  • Sabbatini , N. and Guardigi , M. 1993 . Luminescent lanthanide complexes as photochemical supramolecular devices . Coord. Chem. Rev. , 123 : 201 – 245 .
  • Petoud , S. , Bunzli , J.‐C. G. , Ganzman , T. , Piguet , C. , Xiang , Q. and Thummel , P. R. 1999 . Influence of charge‐transfer states on the Eu(III) luminescence in mononuclear triplet helical complexes with tridentate aromatic ligands . J. Lumin. , 82 : 69 – 76 .
  • Chen , Q. Y. , Luo , J. H. , Fu , D. G. and Wang , Z. L. 2002 . A study on the heterodinuclear cryptates [LnCuL(DMF)](ClO4)2(MeCN (Ln = Gd, Eu, Tb, Dy, Y)—synthesis, characterization, magnetic and electrochemical properties . J. Chem. Soc., Dalton Trans. , 14 : 2873 – 2878 .
  • Wang , S.‐X. , Luo , J.‐H. , Zhou , X.‐X. and Zeng , Z.‐Z. 1993 . Synthesis, characterization and luminescence properties of lanthanide(III) complexes with 2,6‐bis(benzimidazol‐2′‐yl′)pyridine . Polyhedron , 12 : 1939 – 1945 .
  • Bazzicalupi , C. , Bencini , A. , Bianchi , A. , Giorgi , C. , Fusi , V. , Masotti , A. , Valtancoli , B. , Rogue , A. and Pina , F. J. 2000 . pH modulation of the luminescence emission of a new europium cryptate complex . J. Chem. Soc., Chem. Commun. , 7 : 561 – 562 .
  • Sabbatini , N. , Ciano , M. , Dellonte , S. , Bonazzi , A. , Bolletta , F. and Balzani , V. 1984 . Photopyysical properties of europium(II) cryptates . J. Phys. Chem. , 88 : 1534 – 1537 .
  • Prodi , L. , Maestri , M. and Balzani , V. 1991 . Luminescence properties of cryptate europium(III) complexes incorporating heterocyclic N‐oxide groups . Chem. Phys. , 180 : 45 – 50 .
  • Prodi , L. , Maestri , M. , Ziessi , R. and Balzani , V. 1991 . Luminescent europium(III), terbium(III) and gadonium(III) complexes triazacyclononane ligand containing three 2,2′‐bipyridine units . Inorg. Chem. , 30 : 3798 – 3802 .
  • Sabbatini , N. , Guardigilli , M. , Manet , I. and Bolletta , F. 1994 . Synthesis and luminescence of lanthanide complexes of a branched macrocyclic ligand containing 2,2′‐bipyridine and 9‐methyl‐1,10‐phenanthroline subunits . Inorg. Chem. , 33 : 955 – 959 .
  • Bazzicalupi , C. , Bencini , A. , Bianchi , A. , Giorgi , C. , Fusi , V. , Masotti , A. , Valtancoli , B. , Roque , A. and Pina , F. 2000 . pH modulation of the luminescnece emission of a new europium cryptate complex . Chem. Commun. , 7 : 561 – 562 .
  • Gawryszewska , P. , Jerzykiewicz , L. , Pietraszkiewicz , M. , Legendziewicz , J. and Riehl , J. P. 2000 . Photophysics and crystal structure of a europium(III) cryptate incorporating 3,3′‐Biisoquinoline‐2,2′‐dioxide . Inorg. Chem. , 39 : 5365 – 5372 .
  • Steemer , F. J. , Verboom , W. , Reinhoudt , D. N. , Van Der Tol , E. B. and Verhoeven , J. W. 1995 . New sensitizer‐modified calix [4] arenes enabling near‐UV excitation of complexed luminescent lanthanide ions . J. Am. Chem. Soc. , 117 : 9114 – 9408 .
  • Platas , C. , Avecilla , F. , de Blas , A. , Rodriguez‐Blas , T. , Geraldes , C. F.G.C. , Toth , E. , Merbach , A. E. and Bunzli , J.‐C. G. 2000 . Mono‐ and bimetallic lanthanide(III) phenolic cryptates obtained by template reaction: solid state structure, photophysical properties and relaxivity . J. Chem. Soc., Dalton Trans. , 4 : 611 – 618 .
  • Chen , Q.‐Y. , Feng , C.‐J. , Luo , J.‐H. , Duan , C.‐Y. , Yu , X.‐S. and Liu , D.‐J. 2001 . The syntheses and luminescent properties of Eu(III) and Tb(III) cryptates in solution . Eur. J. Inorg. Chem. , 4 : 1063 – 1069 .
  • Winpenny , R. E.P. 1998 . The structures and magnetic properties of complexes containing 3d and 4f metals . Chem. Soc. Rev. , 27 : 447 – 452 .
  • Edder , C. , Piguet , C. , Bunzli , J.‐C. G. and Hopfgartner , G. 2001 . High‐spin iron(II) as a semitransparent partner for tuning europium(III) luminescence in heterodimetallic d–f complexes . Chem. Eur. J. , 7 : 3014 – 3024 .
  • Chen , Q.‐Y. , Luo , Q.‐H. , Wang , Z.‐L. and Chen , J.‐T. 2000 . Synthesis and crystal structure of the first d–f heterodinuclear Dy(III)–Cu(II) cryptate . J. Chem. Soc., Chem. Commun. , 12 : 1033 – 1034 .
  • Reany , O. , Gunnlaugsson , T. and Parker , D. 2000 . A model system using modulation of lanthanide luminecence to signal Zn2 + in competitive aqueous media . J. Chem. Soc., Perkin Trans., II , 9 : 1819 – 1831 .
  • Sakamoto , M. , Manseki , K. and Okawa , H. 2001 . d–f Heterodinuclear complexes: synthesis, structures and physicochemical aspects . Coord. Chem. Rev. , 219–221 : 379 – 414 .
  • Taniguchi , S. 1984 . Acylating reaction of 4‐methylphenol . Bull. Chem. Soc. Jpn. , 57 : 2683 – 2684 .
  • Kimura , E. , Young , S. and Collman , J. P. 1970 . Research on the preparation of tris(2‐aminoethyl)‐amine . Inorg. Chem. , 9 : 118 – 124 .
  • Miller , R. R. , Brandt , W. W. and Puke , M. 1955 . Metal‐amine coordination compounds. V. The ruthenium‐2,2′‐bipyridine system . J. Chem. Soc. , 11 : 3178 – 3180 .
  • Houten , J. V. and Watts , R. J. 1976 . Temperature dependence of the photophysical and photochemical properties of the tris(2,2′‐bipyridyl)ruthenium(II) ion in aqueous solution . J. Am. Chem. Soc. , 98 : 4853 – 4858 .
  • Eaton , D. F. 1988 . Reference materials for fluorescence measurement . Pure Appl. Chem. , 60 : 1107 – 1114 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.