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Original Articles

Synthesis and Physicochemical Properties of Some β‐Ketoaminato Cobalt(II) Chelates and Their Adducts with 2,2′‐Bipyridine and 1,10‐Phenanthroline

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Pages 1471-1485 | Received 24 Apr 2003, Accepted 08 Apr 2004, Published online: 16 Nov 2010

References

  • Schrock , R. R. , Seidel , S. W. , Schrodi , Y. and Davis , W. R. 1999 . Synthesis of zirconium complexes that contain the diamido phosphine ligands [(Me3SiNCH2CH2)2PPh]2 or [(RNSiMe2CH2)2PPh]2 (R = t‐Bu or 2,6‐Me2C6H3) . Organometallics , 18 : 428 – 437 .
  • Graff , D. D. , Schrock , R. R. , Davis , W. R. and Stumpf , R. 1999 . Synthesis of zirconium complexes containing the tridentate diamido ligands [{t‐Bu‐N‐o‐(C6H4)2S]2 and [(i‐PrN‐o‐(C6H4)2S]2 . Organometallics , 18 : 843 – 852 . [CROSSREF]
  • Guerin , F. , McConville , D. H. , Vittal , J. J. and Yap , G. A. 1998 . Synthesis, structure and reactivity of zirconium alkyl complexes bearing ancillary diamine ligands . Organometallics , 17 : 5772 – 5779 .
  • Lappert , M. F. and Liu , D. S. 1995 . Recent studies on metal and metalloid bis(trimethylsilyl)methyls and the transformation of the bis(trimethylsilyl)methyls into azaalkyl and diketiminates ligands . J. Organomet. Chem. , 500 : 203 – 217 . [CROSSREF]
  • Sato , T. , Takeda , H. , Sakai , K. and Tsubomura , T. 1996 . Two novel types of metal complexes derived from tripod amines and acetylacetone . Inorg. Chim. Acta , 246 : 413 – 421 . [CROSSREF]
  • Hiremath , A. C. , Okaly , J. D. and Halli , M. B. 1989 . Synthesis and structural studies of Cu(II), Ni(II), Co(II), Zn(II), Cd(II), Hg(II) and UO2(II) complexes of Schiff‐base . Proc. Natl. Acad. Sci. Ind. Sect. A. , 68 ( 3 ) : 291 – 294 .
  • Koksal , H. , Tumer , M. and Serin , S. 1996 . Synthesis and characterization of binuclear Cu(II), Ni(II) and Co(II) chelates with tetradentate Schiff base ligands derived from 1,5‐Diaminonapthalene . Synth. React. Inorg. Met.‐Org. Chem. , 26 ( 9 ) : 1577 – 1588 .
  • Ohashi , Y. , Oogo , Y. and Nakamura , M. 1999 . A novel adduct of TCNQ dianion with Schiff base Co(II) complex in N‐bonded coordination mode in DMF solution . Chem. Lett. , 11 : 1187 – 1188 . [CROSSREF]
  • Sailaja , S. , Reddy , M. R. , Raju , K. M. and Reddy , K. H. 1999 . Synthesis and characterization of Co(II) chelates of N,N′‐ethylene bis(salicylaldimine) and related quadridentate ligands . Indian. J. Chem. Sect. A. , 38 ( A(2) : 156 – 160 .
  • Kim , J. , Hwang , J. W. , Kim , Y. , Lee , M. H. , Han , Y. and Do , Y. 2001 . Synthesis, structure and ethylene polymerization behaviour of zirconium complexes with chelating ketoiminate ligands . J. Organomet. Chem. , 620 : 1 – 7 . [CROSSREF]
  • Laine , T. V. , Lappalainen , K. , Liimata , J. , Aitola , E. , Löfgren , B. and Leskelä , M. 1999 . Polymerization of ethylene with new diimine complexes of late transition metals . Macromolecular Rapid. Commun. , 20 ( 9 ) : 487 – 491 . [CROSSREF]
  • Britovsek , G. J.P. , Gibson , V. V. , Mastroianni , S. , Oakes , D. C.H. , Redshaw , C. , Solan , G. A. , White , A. J.P. and Williams , D. J. 2001 . Imine versus amine donor iron‐based ethylene polymerization catalysts . Eur. J. Inorg. Chem. , 2 : 431 – 437 . [CROSSREF]
  • Mecking , S. 1999 . Reactor blending with early/late transition metal catalyst combinations in ethylene polymerization . Macromol. Rapid. Commun. , 20 ( 3 ) : 139 – 143 . [CROSSREF]
  • Britovsek , G. J.P. , Mastroianni , S. , Solan , G. A. , Baugh , S. P.D. , Redshaw , C. , Gibson , V. C. , White , A. J.P. , Williams , D. J. and Elsegood , M. R.J. 2000 . Oligomerization of ethylene by bis(imino)pyridyl iron and cobalt complexes . Chem. Eur. J. , 6 ( 12 ) : 2221 – 2231 . [CROSSREF]
  • Ruiz‐Molina , D. , Veciana , J. , Wurst , K. , Hendrickson , D. N. and Rovira , C. 2000 . Redox‐tunable valence tautomerism in a cobalt Schiff base complex . Inorg. Chem. , 39 : 617 – 619 . [CROSSREF]
  • Chae , H. and Choi , Y. 1988 . Synthesis of tridentate Schiff base Co(II) complexes and their electrochemical properties . J. Korean Chem. Soc. , 42 : 422 – 431 .
  • Hirotsu , M. , Kojima , M. , Nakajima , K. , Kashino , S. and Yoshikawa , Y. 1996 . Stereochemistry and electrochemistry of Co(II) and Cu(II) complexes containing optically active tetradentate Schiff base ligands . Bull. Chem. Soc. Jpn. , 69 ( 9 ) : 2549 – 2557 .
  • Parihari , R. K. and Patel , R. N. 1999 . Syntheses and characterization of Schiff base complexes of Mn(II), Co(II) and Zn(II) . Asian. J. Chem. , 11 ( 2 ) : 450 – 452 .
  • Osowole , A. A. , Woods , J. A.O. and Odunola , O. A. 2002 . Physicochemical properties of some nickel(II) 3‐chloro‐β‐ketoamines and their adducts with 2,2‐bipyridyl and 1,10‐phenanthroline . Int. J. Chem. , 12 ( 1 ) : 47 – 56 .
  • Osowole , A. A. , Woods , J. A.O. and Odunola , O. A. 2002 . Synthesis and characterisation of some nickel(II) β‐ketoamines and their adducts with 2,2′ bipyridine and 1,10‐phenanthroline . Synth. React. Inorg. Met.‐Org. Chem. , 32 ( 4 ) : 783 – 799 . [CROSSREF]
  • Osowole , A. A. , Woods , J. A.O. and Odunola , O. A. 2003 . Synthesis and physicochemical properties of some copper(II) β‐ketoamines and their adducts with 2,2′‐bipyridine and 1,10‐phenanthroline . Synth. React. Inorg. Met.‐Org. Chem. , 33 ( 2 ) : 167 – 182 . [CROSSREF]
  • Furniss , B. S. , Hamford , A. J. , Rogers , V. R. , Smith , P. W.G. and Tatchell , A. R. 1984 . Vogel's Textbook of Organic Chemistry , 4th Ed. 15 – 20 . Longman .
  • Bassett , J. , Denney , R. C. , Jeffery , G. H. and Mendham , J. 1978 . Vogel's Textbook of Qualitative Inorganic Analysis , 4th Ed. 316 – 325 . ELBS .
  • Earnshaw , A. 1968 . The Introduction to Magnetochemistry 80 – 86 . London, New York : Academic Press .
  • Fackler , J. P. Jr. 1966 . “ Metal β‐ketoenolates complexes ” . In Prog. Inorg. Chem. Edited by: Cotton , F. A. Vol. 7 , 361 – 425 . Wiley Interscience .
  • Geary , W. J. 1971 . Characterization of coordination compounds . Coord. Chem. Rev. , 7 : 81 – 122 . [CROSSREF]
  • Forster , L. S. 1964 . The acetylacetonate anion: M.O. Calculations in the Hückel and self‐consistent field approximations . J. Amer. Chem. Soc. , 86 : 3001 – 3004 .
  • Lever , A. B.P. 1986 . Inorganic Electronic Spectroscopy , 4th Ed. 481 – 579 . London : Elsevier .
  • Silverstein , R. M. and Webster , F. X. 1998 . Spectrometric Identification of Organic Compounds , 6th Ed. 73 – 109 . John Wiley and Sons Inc .
  • Kwiatkowski , M. and Bandoli , G. 1992 . Nickel(II) complexes with unsymmetrical quadridentate Schiff bases having a pendant N‐acyl substituent . J. Chem. Soc. Dalton Trans. , : 379 – 384 . [CROSSREF]
  • Kwiatkowski , M. , Kwiatkowski , A. , Olechnowicz , A. , Ho , D. M. and Deutsch , E. A. 1990 . New nickel(II) and palladium(II) complexes with unsymmetrical quadridentate Schiff bases derived from 8‐amino‐4‐methyl‐5‐azaoct‐3‐en‐2‐one. Crystal and molecular structure of [4,10‐dimethyl‐3‐(nitroso‐xN)‐5,9‐diaza‐x 2N)‐trideca‐3,10‐diene‐2,12‐(dionato‐xO)(2‐)]nickel(II) . J. Chem. Soc. Dalton Trans. , : 2497 – 2502 . [CROSSREF]
  • Ueno , K. and Martell , A. E. 1956 . Infrared study of metal chelates of ketoamines . J. Phys. Chem. , 59 : 998 – 999 .
  • Jørgenson , M. J. and Heathcock , C. N. 1965 . Existence of planar ↔ tetrahedral equilibrium in solutions of cobalt(II) complexes . J. Amer. Chem. Soc. , 87 ( 22 ) : 5266 – 5267 .

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