Synthesis of Mono‐coordinate Iron(II)‐phen Complex via a Solid State Ligand Exchange Process from Iron(II) Oxalate Dihydrate at Room Temperature under Mechanical Stressing

References

• Adams , D. M. , Long , G. J. and Williams , A. D. 1982 . Spectroscopy at Very High Pressures. 36. An Infrared Study of Spin‐State Equilibria in Some Iron(II) Complexes . Inorg. Chem. , 21 ( 3 ) : 1049 – 1053 .
   Google Scholar
• Avvakumov , E. , Devyathina , E. and Kosova , N. 1994 . Mechanochemical Reactions of Hydrated Oxides . J. Solid State Chem. , 113 ( 2 ) : 379 – 383 .
   Google Scholar
• Balasubramanian , S. 1999 . Synthesis, Spectral Studies, Spin Cross‐over in Mixed Ligand Complexes of Iron(II) and the Influence of Solvent on Magnetic Behaviour . Synth. React. Inorg. Met.‐Org. Chem. , 29 ( 3 ) : 377 – 394 .
   Google Scholar
• Charron , F. F. Jr. , Eisman , G. A. , Wong , H. and Reiff , W. M. 1983 . On The Highly Varied Magnetic Behavior in a Series of Mono(α‐diimine)dichloro‐iron(II) Complexes. Strong High‐temperature One‐dimensional Ferromagnetic Exchange in Fe(phen)Cl2 . Inorg. Chim. Acta. , 68 : 233 – 236 .
   Google Scholar
• Fernández‐Bertrán , J. , Castellanos‐Serra , L. , Yee‐Madeira , H. and Reguera , E. 1999 . Proton Transfer in Solid State: Mechanochemical Reactions of Imidazole with Metallic Oxides . J. Solid State Chem. , 147 ( 2 ) : 561 – 564 .
   Google Scholar
• Hutchinson , B. , Takemoto , J. and Nakamoto , K. 1970 . Metal Isotope Effect on Metal‐ligand Vibrations. II. Tris Complexes of 2,2′‐Bipyridine and 1,10‐Phenanthroline . J. Am. Chem. Soc. , 92 ( 11 ) : 3335 – 3339 .
   Google Scholar
• Huheey , J. E. , Keiter , E. A. and Keiter , R. L. 1993 . Inorganic Chemistry: Principles of Structure and Reactivity , 4th Ed. 405 New York : Harper Collins College Publishers .
   Google Scholar
• Madeja , K. and König , E. 1963 . Zur Frage der Bindungsverhältnisse in Komplexverbindungen des Eisen(II) mit 1,10‐Phnanthrolin . J. Nucl. Chem. , 25 : 377 – 385 .
   Google Scholar
• Ohshita , T. , Nakajima , D. , Tsukamoto , A. , Tsuchiya , N. , Isobe , T. , Senna , M. , Yoshioka , N. and Inoue , H. 2002 . Role of Molecular Strain on The Solid‐State Synthesis of Coordination Compounds from Iron(II) Chloride Tetrahydrate and 1,10‐Phenanthroline under Mechanical Stress . Ann. Chim. Sci. Mat. , 27 ( 6 ) : 91 – 101 .
   Google Scholar
• Ohshita , T. , Tsukamoto , A. and Senna , M. 2004 . Change in The Magnetic Properties of [FeII(phen)3](PF6)2 in the Solid State by Combining Grinding and Annealing . Phys. Stat. Sol. , 201 ( 4 ) : 762 – 768 .
   Google Scholar
• Paneque , A. , Fernández‐Bertrán , J. , Reguera , E. and Yee‐Madeira , H. 2001 . Mechanochemical Synthesis of Hemin‐Imidazole Complexes . Trans. Met. Chem. , 26 ( 1–2 ) : 76 – 80 .
   Google Scholar
• Takemoto , J. and Hutchinson , B. 1972 . Effect of Magnetic Crossover on The Low‐frequency IR Spectrum of [Fe(1,10‐Phenanthroline)2(NCS)2] . Inorg. Nucl. Chem. Lett. , 8 ( 9 ) : 769 – 772 .
   Google Scholar
• Takemoto , J. and Hutchinson , B. 1973 . Low‐frequency Infrared Spectra of Complexes which Exhibit Magnetic Crossover. I. Iron(II) Complexes of 1,l0‐Phenanthroline and 2,2′‐Bipyridine . Inorg. Chem. , 12 ( 3 ) : 705 – 708 .
   Google Scholar
• Tsuchiya , N. , Isobe , T. , Senna , M. , Yoshioka , N. and Inoue , H. 1996 . Mechanochemical Effects on The Structures and Chemical States of [Fe(phen)3](NCS)2 · H2O . Solid State Commun. , 99 ( 8 ) : 525 – 529 .
   Google Scholar
• Tsuchiya , N. , Tsukamoto , A. , Ohshita , T. , Isobe , T. , Senna , M. , Yoshioka , N. and Inoue , H. 2000 . Anomalous Spin Crossover of Mechanically Strained Iron(II) Complexes with 1,10‐Phenanthroline with Their Counterions, NCS− and PF6 − . J. Solid State Chem. , 153 ( 1 ) : 82 – 91 .
   Google Scholar
• Tsuchiya , N. , Tsukamoto , A. , Ohshita , T. , Isobe , T. , Senna , M. , Yoshioka , N. and Inoue , H. 2001 . Stress‐induced Ligand Field Distribution and Consequent Multi‐mode Spin Crossover in FeII(phen)2(NCS)2 and FeII[HB(pz)3]2 . Solid State Sci. , 3 ( 6 ) : 705 – 714 .
   Google Scholar
• Wrobleski , J. T. and Brown , D. B. 1979 . Synthesis, Magnetic Susceptibility, and Spectroscopic Properties of Single‐ and Mixed‐valence Iron Oxalate, Squarate, and Dihydroxybenzoquinone Coordination Polymers . Inorg. Chem. , 18 ( 10 ) : 2738 – 2749 .
   Google Scholar