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Mineral Processing and Extractive Metallurgy
Transactions of the Institutions of Mining and Metallurgy: Section C
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Review

Processing of copper electrorefining anode slime: a review

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Pages 240-252 | Published online: 18 Jul 2013

References

  • A. M. Amer: Processing of copper anode-slimes for extraction of metal values', Physicochem. Problems Miner. Process., 2002, 36, 123–134.
  • A. M. Amer: ‘Processing of copper anodic-slimes for extraction of valuable metals’, Waste Manag., 2003, 23, 763–770.
  • K. Arai, S. Sanuki, M. Minami and S. Sunada: ‘Silver recovery from the oxidative leaching residue of copper anode slime’, Mater. Trans. JIM, 1989, 30, (3), 165–174.
  • G. G. Barbante, D. R. Swinbourne and W. J. Rankin: Pyrometallurgical treatment of copper tank house slimes', Proc. Conf. on Pyrometallurgy for complex materials and wastes', 319-337; 1994, Warrendale, PA, TMS.
  • I. Bayraktar and F. A. Garner: ‘Hydrometallurgical processing of secondary copper anode slimes for metals recovery’, Proc. Int. Symp. on ‘Recycle and secondary recovery of metals’, (ed. P. R. Taylor et al), 547-562; 1985, Warrendale, PA, AIME.
  • J.Bertha: ‘Hydrometallurgical process for recovering silver from copper — electrolysis anode sludge’, US patent no. 4666514, 1986.
  • J. Bertha: ‘Hydrometallurgical process for recovering silver from electrolytic copper refinery slimes and from similar raw materials’, Patent no. EP0266337, 1987a.
  • J. Bertha: ‘Hydrometallurgical process for the recovery of silver from copper electrolysis anode sludge’, US patent no. 4874429, 1987b.
  • E. A. Buketov, Y. D. Burdakov, L. D. Kirr, Z. S. Klyacheva and V. P. Malyshev: ‘Shaft furnace sintering of electrolytic copper slimes’, Tsvetn. Met., 1965, 38, (4), 28–31.
  • B. Bunyamin, F. Sevim and S. Colak: ‘A study on recovery of gold from decopperized anode slime’, Chem. Eng. Technot, 2001, 24, 91–95.
  • A. Butts: ‘Copper: the science and technology of the metal, its alloys and compounds’, American Chemical Society monograph series; 1954, New York, American Chemical Society.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterization of anode slimes — II. Raw anode slimes from Inco's copper cliff copper refinery’, Can. Metall. Q., 1988a, 27, (2), 97–105.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterisation of anode slimes — I. Anode copper from Inco's copper cliff copper refinery’, Can. Metall. Q., 1988b, 27, (2), 91–96.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterisation of anode slimes — III. Sulphation reactor slimes from Inco's copper cliff copper refinery’, Can. Metall. Q., 1988c, 27, (2), 107–116.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical study of the deportment and reaction of silver during copper electrorefining’, Met. Trans. B, 1989a, 20B, 345–361.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterisation of anode slimes — IV. Copper—nickel—antimony oxide (`Kupferglimmer’) in CCR anodes and anode slime', Can. Metall. Q., 1989b, 28, 127–134.
  • T. T. Chen and J. E. Dutrizac: ‘The mineralogy of copper electrorefining’, JOM, 1990a, 42, (8), 39–44.
  • T. T. Chen and J. E. Dutrizac: ‘Practical mineralogical techniques for the characterization of hydrometallurgical products’, in ‘Process mineralogy IX’, (ed. W. Petruk and R. D. Hagni), 289-309; 1990b, Warrendale, PA, TMS.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterisation of anode slimes: part 6 — pressure leached slimes from the CCR division of Noranda Minerals Inc.’, Can. Metall. Q., 1990c, 29, 293–305.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterisation of anode slimes: part 5 — nickel rich copper anodes from the CCR division of Noranda Minerals Inc.’, Can. Metall. Q., 1990d, 29, 27–37.
  • T. T. Chen and J. E. Dutrizac: ‘A mineralogical overview of the behavior of nickel during copper electrorefining’, Met. Trans. B, 1990e, 21B, 229–239.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterization of anode slimes: part 7 — copper anodes and anode slimes from the Chuquicamata Division of Codelco-Chile’, Can. Metall. Q., 1991a, 30, (2), 95–106.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterisation of anode slimes: part 8 — Silica in copper anode and anode slimes’, Can. Metall. Q., 1991b, 30, 173–185.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical changes occurring during the decopperizing and deleading of Kidd Creek Copper Refinery anode slimes’, Proc. the Paul E. Queneau Int. Symp. on ‘Extractive metallurgy of copper, nickel and cobalt’, Vol. I, ‘Fundamental aspects’, (ed. R. G. Reddy), 377-401; 1993a, Weizenbach, TMS.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterization of anode slimes: part 9. The reactor of Kidd Creek anode slimes with lixiviants’, Can. Metall. Q., 1993b, 32, 267–279.
  • T. T. Chen and J. E. Dutrizac: ‘Mineralogical characterization of anode slimes: part 10. Tellurium in raw anode slimes’, Can. Metall. Q., 1996, 35, 337–351.
  • T. T. Chen and J. E. Dutrizac: ‘A mineralogical study of the deportment of impurities during the electrorefining of secondary copper anodes’, Proc. Int. Conf. Copper ‘99, Vol. III, 'Electrorefining and electrowinning of copper’, (ed. J. E. Dutrizac et al), 437; 1999, Warrendale, PA, TMS.
  • G. Cifuentes, S. Hernandez, P. Navarro, J. Simpson, C. Reyes, A. Naranjo and L. Tapia: ‘Anodic slimes characteristics and behaviour in copper refining’, Proc. Int. Conf. Copper ‘99, Vol. III, 'Electrorefining and electrowinning of copper’, (ed. J. E. Dutrizac et al), 427-435; 1999, Warrendale, PA, TMS.
  • W. C. Cooper: ‘A review of processes for the treatment of copper refinery anode slimes with particular reference to selenium behaviour and recovery’, Final report on project no. 169/02/87, CANMET, Ottawa, Canada, 1989.
  • W. C. Cooper: ‘The treatment of copper refinery anode slimes’, JOM, 1990, 42, (8), 45–49.
  • T. Decker and A. Peteghem: ‘Leaching of copper refinery slimes’, Proc. 1976 AIME Ann. Meet., Las Vegas, NV, USA, February 1976, AIME.
  • C. P. Dixon: ‘Gold and silver refining at electrolytic refining and smelting company of Australia Ltd. Port Kembla, N.S.W.’, in ‘Mining and metallurgical practices in Australasia’, (The Sir Mourice Mawley Memorial Volume) monograph series no. 10, (ed. J. T. Woodcock), 519-521; 1980a, Parkville, Vic., The Australasian Institute of Mining and Metallurgy.
  • C. P. Dixon: ‘Selenium recovery at the electrolytic refining and smelting company of Australia Ltd., Port Kembla, N.S.W.’, in ‘Mining and metallurgical practices in Australasia’, (The Sir Mourice Mawley Memorial Volume) monograph series no. 10, (ed. J. T. Woodcock), 628-629; 1980b, Parkville, Vic., The Australasian Institute of Mining and Metallurgy.
  • B. Donmez, C. Celik, S. Colak and A. Yartasi: ‘Dissolution optimisation of copper from anode slime in H2504 solutions’, Ind. Eng. Chem. Res., 1998, 37, (8), 3382–3387.
  • O. Forsen and M. H. Tikkanen: ‘On the dissolution of copper anodes in electrolytic refining. Part II: the behaviour of antimony in nickel—oxygen-bearing anodes’, Scand J. Metall., 1982, 11, 72-78.
  • M. A. Green: ‘Improved estimates for Te and Se availability from Cu anode slimes and recent price trends’, Frog. Photovolt. Res. ARA, 2006, 14, 743–751.
  • T. N. Greiver: ‘Optimum temperature conditions for the roasting of copper electrolyte slurries’, Chem. Abs., 1974, 81, (172195).
  • J. Hait, R. K. Jana, V. Kumar and S. K. Sanyal: ‘Some studies on sulphuric acid leaching of anode slime with additives’, Ind. Eng. Chem. Res., 2002, 41, 6593–6599.
  • J. Hait, R. K. Jana and S. K. Sanyal: ‘Mineralogical characteristics of copper electrorefining anode slime and its leached residues’, Ind. Eng. Chem. Res., 2004, 43, 2079–2087.
  • J. E. Hoffmann: in ‘Hydrometallurgy '94’, 69-105; 1994, London, Chapman & Hall Ltd.
  • J. E. Hoffmann, P. D. Parker and A. C. Sabo: ‘Extraction and purification of silver from sulphates’, US patent no. 3996046, 1976.
  • J. E. Hoffmann: ‘Processing slimes: the base case and opportunities for improvement’, JOM, 1990, 42, (7), 38.
  • J. E. Hoffmann: ‘Recovery of selenium from electrolytic copper refinery slimes’, in ‘Precious metals: mining, extraction and processing’, (ed. V. Kudryk et al), 495-515; 1984, Warrendale, PA, TMS.
  • J. E. Hoffmann: ‘The wet chlorination of electrolytic refinery slimes’, JOM, 1990, 42, (8), 50–54.
  • Y. C. Hoh, B. D. Lee, T. Ma, W. S. Chuang and W. K. Wang: ‘Treatment of copper refinery anode slime’, US patent no. 4352786, 1982.
  • Y. C. Hoh, C. C. Chang, W. S. Chuang, B. D. Lee, J. J. Tai, W. L. Feng, T. Ma, C. S. Ko and W. L. Chen: `INER process for recovering precious metals from copper refinery anode slime', Proc. Conf. on ‘Hydrometallurgy research, development and plant practice’, (ed. K. Osseo-Asare and J. D. Miller), 151-163; 1983, Warrendale, PA, TMS/AIME.
  • O. Hyvarinen, E. Rosenberg and L. Lindroos: ‘Selenium and precious metals recovery from copper anode slimes at Outokumpu Pori refining’, Proc. AIME Conf. on ‘Precious metals’, 537-548; 1984, Warrendele, PA, TMS/AIME.
  • V. T. Isakov: ‘The electrolytic refining of copper’, 2nd edn; 1970, England, Technicopy Ltd.
  • O. Jarvinen: ‘Outokumpu process for the precious metal refining from copper anode slime’, Proc. EPD Cong. 2000, (ed. P. R. Taylor), 511-514; 2000, Warrendale, PA, TMS.
  • V. Jung, B. Deierling and R. Karl: ‘Recovery of precious metals from materials containing selenium, tellurium, arsenic and anti-mony’, Chem. Abs., 1983, 99, (198566z).
  • A. I. Kholkin, V. V. Belova, A. A. Voshkin, T. I. Zhidkova, V. I. Zhilov and R. K. Jana: ‘Binary extraction agents based on dialkyldithiophosphoric acids in hydrometallurgy’, J Chem. Technot, 2005, 8, 34–43.
  • D. Kunev, Kh. Vasilev, M. Chimbulev and L. Karagozov: ‘Study of the sulphation roasting of electrolytic copper slimes’, Chem. Abs., 1978, 88, (64561).
  • C. Li, J. Zhang and H. Wang: `Chloridizing process gold extraction from silver anode sludge', Proc. 3rd Int. Conf. on ‘Hydrometallurgy’, 609-612; 1998, Beijing, International Academic Publishers.
  • B. M. Ludvigsson and S. R. Larsson: ‘Anode slimes treatment: the Boliden experience’, JOM, 2003, 55, (4), 41–44.
  • M. Lux, B. Mende and S. Ziegenbalg: ‘Alkaline pressure leaching of anodic sludge from copper electrolysis’, Chem. Abs., 1978, 89, (151963e).
  • M. Zh. Makhmetov, V. P. Malyshev„ K. Zh. Makhmetov, L. G. Gorokhova and V. I. Chuprakov: ‘Complex processing of copper electrolysis slimes’, Chem. Abs., 1980, 92, (165826m).
  • D. B. Mohanty, S. V. S. S. Murty and R. N. Misra: ‘Distribution pattern of tellurium during copper making based on Singhbhum copper belt ore’, Trans. Ind Inst. Met., 1982, 35, (3), 221–226.
  • R. K. Monahan and F. Loewen: ‘Treatment of anode slimes at the INCO Copper Refinery’, Proc. CIM Ann. Conf., August, Halifax, Nova Scotia, 1972, CIM.
  • B. H. Morrison: ‘Recovery of silver and gold from refinery slimes at Canadian Copper Refiners’, in ‘Extractive metallurgy 1985’, 249-269; 1985, London, The Institute of Mining and Metallurgy.
  • B. H. Morrison: ‘Slimes treatment process’, US patent no. 4047939, 1997.
  • B. H. Morrison: ‘The evolution of copper refinery slime processing and precious metal treatment at CCR division — Noranda Minerals’, in ‘Precious metals 1989’, (ed. B. Harris), 403-413; 1989, Allentown, PA, International Precious Metals Institute.
  • B. H. Morrison: ‘The recovery and separation of selenium and tellurium by pressure leaching of copper refinery slime’, Proc. Symp. on ‘Unit processes in hydrometallurgy’, Dallas, TX, USA, February 1963, Metallurgical Society, 227-249.
  • J. Newton and C. L. Wilson: ‘Metallurgy of copper’, 272; 1942, New York/London, Chapman & Hall Ltd.
  • K. K. Nippon Shin Kinzoku: ‘Recovery of tellurium and copper in slime from copper electrorefining’, Chem. Abs., 1981, 96, (207402).
  • F. Noguchi, Y. Iida, T. Nakamura and Y. Ueda: ‘Behaviour of anode impurities in copper electrorefining’, J. Min. Mater. Process. Inst. Jpn, 1991, 107, (8), 569–575.
  • T. Okubo, T. Iio and M. Shuto: ‘New Sumitomo process for gold recovery from copper anode slime’, Proc. AIME Conf. on ‘Precious metals’, 517-536; 1984, Warrendele, PA, TMS/AIME.
  • E. N. Petkova: ‘Microscopic examination of copper electrorefining slimes’, Hydrometallurgy, 1990, 24, 351–359.
  • C. Plitzko: ‘Precious metals at Norddeutsche Affinerie — the new top blown rotary converter process for treating anode slimes at Norddeutsche Affinerie’, Proc. EMC 2001, Friedrichshafen, Germany, September 2001, GDMB, 315-328.
  • H. Razavizadeh and R. Gee: ‘Characterisation of copper anode slimes from Sar-Cheshmeh containing barium sulphate’, Erzmetall, 1989, 42, (12), 560–565.
  • S. C. Sahu, C. M. Shroff and D. B. Mohanty: ‘A new route for the recovery of precious metals from copper anode slimes’, Proc. Int. Conf. on ‘Base metals technology’, Jamshedpur, India, February 1989, Indian Institute of Metals, 245-250.
  • S. Sanuki, N. Minami, K. Arai, T. Izaki and H. Majima: ‘Oxidative leaching treatment of copper anode slime in a nitric acid solution containing sodium chloride’, Mater. Trans. JIM, 1989, 30, (10), 781–788.
  • J. Sato, T. Imamura, M. Hojo and T. Suzuki: ‘New process for copper anode slime treatment at the Hitachi Smelter & Refinery’, in ‘World mining and metals technology’, (ed. A. Weiss), Vol. 2, 585-598; 1976, Warrendale, PA, AIME.
  • V. M. Savin: ‘Selecting the most efficient method of treating slimes obtained during electrolytic copper refining’, Chem. Abs., 1965, 63, (14437).
  • F. Shijun and W. Youzheng: ‘Treatment of copper anode slime in DAYE Smelter and its technical improvements’, Proc. 3rd Int. Conf. on ‘Hydrometallurgy’, 616-619; 1998, Beijing, International Academic Publishers.
  • V. G. Shkodin, V. P. Malyshev, 0. V. Evtyukhova, V. E. Malkov and S. A. Galimova: ‘Roasting-sintering of anode slimes with soda in shaft furnaces’, Chem. Abs., 1970, 72, (114078).
  • K. N. Subramanian, M. C. E. Bell, J. A. Thomas and N. C. Nissen: ‘Recovery of metal values from anode slime’, US patent no. 4229270, 1980.
  • K. G. Tan and P. L. Bedard: ‘Ammonia leach process for the treatment of copper refinery anode slimes containing high lead and low nickel’, Can. Metall. Q., 1989, 28, (3), 199–210.
  • K. G. Tan and P. L. Bedard: ‘Selective ammoniacle pressure leaching of noble metal concentrates’, Canadian patent no. 5556372, 1988.
  • K. G. Tan: ‘Fulminating gold and silver’, CIM Bull, 1987, 80, (903), 96–97.
  • A. A. Tishchenko: ‘Extraction of selenium and tellurium from copper electrolytic slimes’, Chem. Abs., 1964, 61, (3955).
  • A. B. Titarenko, T. N. Breiver, A. I. Poluboyarinov and A. F. Astakhov: ‘Reconstruction of the slimes department of the Pyshma Electrolytic Copper Plant,’ Chem. Abs., 1976, 85, (8591).
  • A. Toraiwa and Y. Abe: ‘New hydrometallurgical process of copper anode slimes at Saganoseki Smelter and Refinery’, Proc. 2nd Int. Conf. on ‘Processing materials for properties’, San Francisco, CA, USA, November 2000, 999-1004.
  • G. S. Victorovich, M. C. Bell, R. Sridhar and J. Raskauskar: `Novel soda ash process for the recovery of selenium from anode slimes', Proc. 109th AIME Ann. Meet., Las Vegas, NV, USA, February 1980, AIME.
  • S. A. Vzorodov, L. D. Sheveleva, I. A. Kakovskii, Sh. R. Navasardyan and E. G. Kremko: ‘Ways to remove difficultly soluble compounds of copper and nickel from copper — electrolysis slimes’, Chem. Abs., 1982, 96, (126878).
  • K. K. Wang, Y.-C. Hoh, W.-S. Chuang and I.-S. Shaw: ‘Hydrometallurgical process for recovering precious metals from anode slime’, US patent no. 4293332, 1980.
  • W. K. Wang, Y. C. Hoh, W. S. Chuang and I. S. Shaw: ‘Hydrometallurgical process for recovering precious metals from anode slime’, US patent no. 5926874, 1981.
  • O. Yavuz and R. Ziyadanogullari: ‘Recovery of gold and silver from copper anode slime’, Separat. Sci. Technol., 2000, 35, (1), 133-141.
  • G. Yildirim and F. Y. Bor: ‘Hydrometallurgical treatment of a copper refinery slime rich in selenium and tellurium’, Erzmetall, 1985, 38, (4), 196–199.
  • G. Zarate and F. Gonzalez: ‘Process definition for anode slimes treatment’, in ‘Hydrometallurgy and electrometallurgy of copper’, (ed. W. C. Cooper et al), 499-524; 1988, Santiago, Santia University of Chile.
  • T.-L. Thou, J. L. Montoya-Jurado, B. L. Shrestha, R. Luo and N. M. Rice: ‘Characterisation and leaching of copper refinery anode slimes’, Leeds University, 1998, 63-74.

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