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Articles

The chemistry of sodium dithionite and its use in conservation

  • Weil, E.D., Sandler, S.R., and Gernon, M., ‘Sulfur compounds’, in Kirk-Othmer Encyclopedia of Chemical Technology, Vol. 23, 5th edn, John Wiley & Sons, New York (2007) 621-701.
  • Dunlop, A.K., ‘Corrosion inhibition in secondary recovery’, in Corrosion Inhibitors, ed. C.C. Nathan, National Association of Corrosion Engineers, Houston, Texas (1973) 76-88.
  • Stambolov, T., ‘Notes on the removal of iron stains from calcareous stone’, Studies in Conservation 13 (1968) 45­47.
  • Hawley, J.K., Kawai, E.A., and Sergeant, C., ‘The removal of rust stains from arctic tin can labels using sodium hydrosulfite’, Journal of the International Institute for Conservation - Canadian Group 6 (1981) 17–24.
  • Feniak, C.J., ‘Treatment of a parasol using a reductive bleach’, Journal of the International Institute for Conservation - Canadian Group 6 (1981) 31–33.
  • Waller, R., ‘A rust removal method for mineral specimens’, The Mineralogical Record 11 (1980) 109–110.
  • Godfrey, I., Kasi, K., and Richards, V, ‘Iron removal from waterlogged leather and rope recovered from shipwreck sites’, in Proceedings of the 8th ICOM Group on Wet Organic Archaeological Materials Conference, Stockholm, Sweden, 11-15 June 2001, ed. P. Hoffmann, J.A. Spriggs, T. Grant, C. Cook and A. Recht, ICOM-CC Working Group on Wet Organic Archaeological Materials, Bremerhaven (2002) 439-470.
  • AIC Book and Paper Group, ‘Chapter 13: Foxing’, in Paper Conservation Catalog, 9th edn, American Institute for Conservation of Historic and Artistic Works, Washington, DC (1994) 39 pgs.
  • Burgess, H., ‘The use of chelating agents in conservation treatments’, The Paper Conservator 15 (1991) 36–44.
  • Bede, D., ‘Conservation of the Wright Flyer III: Serendipity and substantiation’, in Strengthening the Bond: Science and Textiles. North American Textile Conservation Conference 2002, Philadelphia, 5-6 April 2002: Preprints, Philadelphia Museum of Art, Philadelphia (2002) 15-24.
  • Potter, J., ‘Experiments in rust removal on a painted Indian chintz’, in Dust, Sweat and Tears: Recent Advances in Cleaning Techniques, ed. L. Dawson and M. Berkouwer, UKIC Textile Section, London (2003) 39-55.
  • MacLeod, I.D., Brooke, P, and Richards, V, ‘Iron corrosion products and their interactions with waterlogged wood and PEG’, in Proceedings of the 4th ICOM Group on Wet Organic Archaeological Materials Conference, Bremerhaven 20-24 August 1990, ed. P Hoffmann, ICOM-CC Working Group on Wet Organic Archaeological Materials, Bremerhaven (1991) 119-132.
  • MacLeod, I.D., Mardikian, P., and Richards, V.L., ‘Observations on the extraction of iron and chloride from composite materials’, in Proceedings of the 5th ICOM Group on Wet Organic Archaeological Materials Conference, Portland, Maine, 16-20 August 1993, ed. P Hoffmann, ICOM-CC Working Group on Wet Organic Archaeological Materials, Bremerhaven (1994) 199-211.
  • MacLeod, I.D., and North, N.A., ‘Conservation of corroded silver’, Studies in Conservation 24 (1979) 165–170.
  • Ganiaris, H., ‘Reduction with gain: the treatment of excavated silver coins with alkaline dithionite’, in Look After the Pennies: Numismatics and Conservation in the 1990s, ed. D. Goodburn-Brown and J. Jones, Archetype Publications, London (1998) 29-34.
  • MacLeod, I.D., ‘Conservation of corroded copper alloys: a comparison of new and traditional methods for removing chloride ions’, Studies in Conservation 32 (1987) 25–40.
  • Fox, G.L., ‘A note on the use of alkaline dithionite for treating ancient bronze artifacts’, Studies in Conservation 40 (1995) 139–142.
  • Neevel, J.G., and Reißland, B., ‘Bathophenanthroline indicator paper: development of a new test for iron ions’, PapierRestaurierung 6 (2005) 28–36.
  • Cornell, R.M., and Schwertmann, U., The Iron Oxides: Structure, Properties, Reactions, Occurrence and Uses, 2nd edn, VCH Publishers, Weinheim (2003).
  • Duncan, S.J., and Ganiaris, H., ‘Some sulphide corrosion products on copper alloys and lead alloys from London waterfront sites’, in Recent Advances in the Conservation and Analysis of Artifacts, Summer Schools Press, London (1987) 109-118.
  • Matthiesen, H., Hilbert, L.R., and Gregory, D.J., ‘Siderite as a corrosion product on archaeological iron from a waterlogged environment’, Studies in Conservation 48 (2003) 183-194.
  • Grattan, D.W., ‘The oxidative degradation of organic materials and its importance in deterioration of artifacts’, Journal of the International Institute for Conservation - Canadian Group 4 (1978) 17–26.
  • Daniels, V., ‘Factors affecting the deterioration of the cellulosic fibres in black-dyed New Zealand flax (Phormium tenax)’, Studies in Conservation 44 (1999) 73–85.
  • Hofenk de Graaff, J.H., ‘Dyeing and writing; A comparison of the use and degradation of iron-gall complexes on textiles and paper’, in Contributions to Conservation, ed. J.A. Mosk and N.H. Tennent, James & James, London (2002) 34-41.
  • Emery, J.A., and Schroeder, H.A., ‘Iron-catalyzed oxidation of wood carbohydrates’, Wood Science and Technology 8 (1974) 123–137.
  • Graf, E., Mahoney, J.R., Bryant, R.G., and Eaton, J.W, ‘Iron-catalyzed hydroxyl radical formation’, The Journal of Biological Chemistry 259 (1984) 3620-3624.
  • Strlic, M., and Kolar, J., ‘Degradation and stabilisation of cellulosic materials’, in Scientific Analysis of Ancient and Historic Textiles: Informing Preservation, Display and Interpretation, 1st Annual Conference, 13-15 July 2004, ed. R. Janaway and P. Wyeth, Archetype Publications, London (2004) 33-37.
  • Rueda, E.H., Ballesteros, M.C., Grassi, R.L., and Blesa, M.A., ‘Dithionite as a dissolving reagent for goethite in the presence of EDTA and citrate: application to soil analysis’, Clays and Clay Minerals 40 (1992) 575–585.
  • Poulton, S.W, and Canfield, D.E., ‘Development of a sequential extraction procedure for iron: implications for iron partitioning in continentally derived particulates’, Chemical Geology 214 (2005) 209–221.
  • Dwyer, F.P., and Mellor, D.P, (ed.), Chelating Agents and Metal Chelates, Academic Press, New York, 1964.
  • Mehra, O.P., and Jackson, M.L., ‘Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate’, in Clays and Clay Minerals: Proceedings of the Seventh National Conference on Clays and Clay Minerals, University of Wisconsin, Madison (1960) 317-327.
  • Rabin, PM., A Study of Iron Stain Removal from Marble using Various Chelating Agents, Art Conservation Program, Queens University, Kingston (1983) unpublished report.
  • Barov, Z., ‘An effective cleaner for organic stains on stone’, in ICOM Committee for Conservation, 8th Triennial Meeting, Sydney, Australia, 6-11 September 1987: Preprints, ed. K. Grimstad, Getty Conservation Institute, Marina del Rey (1987) Vol. II, 465-468.
  • Baker, W, Investigation into the Use of Chelating Agents for the Removal of Iron Contaminants from Paper, Art Conservation Program, Queens University, Kingston (1982) unpublished report.
  • Lockwood, K., ‘The effectiveness of selected chelate-reducing agent systems in the removal of iron stains from paper’, in Art Conservation Training Programs Conference, Harvard University Art Museums, Cambridge (1984) 87-100.
  • Prytulak, G., Optimum Conditions for the Removal of Iron Stains from Marble, Paper and Wool Using the Sodium Dithionite: Sodium Tripolyphosphate System, Art Conservation Program, Queens University, Kingston (1985) unpublished report.
  • MacKay, A., The Effectiveness of Selected Chelating Agents and Sodium Dithionite in the Removal of Rust Stains from Cotton, Art Conservation Program, Queens University, Kingston (1992) unpublished report.
  • Cripps, C., A Comparison of Various Chelating Agents and their Effectiveness in Removing Iron Stains from Linen and Cotton, Art Conservation Program, Queens University, Kingston (1994) unpublished report.
  • Smith, B.L., A Study of Iron Stain Removal using Two Selected Chelating Agents (EDTA and STPP) and Sodium Dithionite, Art Conservation Program, Queens University, Kingston (1994) unpublished report.
  • Fredette, T., The Identification and Removal of Iron Stains from Historic White Cotton, MSc thesis, University of Rhode Island (1998).
  • Suryawanshi, D.G., and Bisaria, S.K., ‘Removing metallic stains from paper objects using chelating agent EDTA’, Restaurator 26 (2005) 276-285.
  • Gent, M., and Rees, J., ‘A conservation treatment to remove residual iron from platinum prints’, The Paper Conservator 18 (1994) 90–95.
  • Owen, A., ‘Conservation and curatorial changes to David Smith’s drawing ‘Untitled”, in Modern Works, Modern Problems? Conference Papers, ed. A. Richmond, Institute of Paper Conservation, Leigh, England (1994) 100-105.
  • Herrenschmidt, F., Moinot, M., Pennec, S.L., MacLeod, I., and Chahine, C., ‘Une lieue sous la mer, le Titanic: traitement des papiers’, in ICOM Committee for Conservation, 11th Triennial Meeting, Edinburgh, Scotland, 1-6 September 1996: Preprints, ed. J. Bridgland, James & James, London (1996) Vol. II, 517-522.
  • Chaberek, S., and Martell, A.E., ‘Metal-ligand equilibrium constant data’, in Organic Sequestering Agents: A Discussion of the Chemical Behavior and Applications of Metal Chelate Compounds in Aqueous Systems, John Wiley & Sons, New York (1959) 513-585.
  • Maclaren, J.A., and Milligan, B., Wool Science: The Chemical Reactivity of the Wool Fibre, Science Press, Marrickville, Australia (1981).
  • Robbins, C.R., Chemical and Physical Behavior of Human Hair, 4th edn, Springer, New York (2002).
  • Newton, C.L., ‘Chemical cleaning of wet leather’, Journal of the International Institute for Conservation - Canadian Group 12 (1987) 3-8.
  • Godfrey, I.M., Kasi, K., Schneider, S., and Williams, E., ‘Iron removal from waterlogged ivory and bone’, in Proceedings of the 8th ICOM Group on Wet Organic Archaeological Materials Conference, Stockholm, Sweden, 11-15 June 2001, ed. P Hoffmann, J.A. Spriggs, T. Grant, C. Cook and A. Recht, ICOM-CC Working Group on Wet Organic Archaeological Materials, Bremerhaven (2002) 527-552.
  • Hodges, H.WM., ‘The conservation treatment of ceramics in the field’, in In Situ Archaeological Conservation: Proceedings of Meetings, Mexico, 6-13 April 1986, ed. H.WM. Hodges, Instituto Nacional de Antropologia e Historia de Mexico, Mexico City (1987) 144-149.
  • Beaton, D., Parks Canada (retired), personal communication (9 September 2008).
  • Gasteiger, S., and Eggert, G., ‘How to compare reduction methods for corroded silver finds’, in Metal 2001:Proceedings of the International Conference on Metals Conservation, ed. I.D. MacLeod, J.M. Theile and C. Degrigny, Western Australian Museum, Perth (2004) 320-324.
  • Thickett, D., and Enderly, C., ‘The cleaning of coin hoards: the benefits of a collaborative approach’, in The Interface Between Science and Conservation, British Museum Occasional Paper No. 116, ed. S. Bradley, British Museum Publications Ltd, London (1997) 183-192.
  • MacLeod, I.D., ‘Stabilization of corroded copper alloys: a study of corrosion and desalination mechanisms’, in ICOM Committee for Conservation, 8th Triennial Meeting, Sydney, Australia, 6-11 September 1987: Preprints, ed. K. Grimstad, Getty Conservation Institute, Marina del Rey, California (1987) Vol. III, 1079-1085.
  • Greenwood, N.N., and Earnshaw, A., Chemistry of the Elements, Pergamon Press, Oxford (1984).
  • Vanysek, P, ‘Electrochemical series’, in CRC Handbook of Chemistry and Physics, 79th edn, CRC Press, Boca Raton (1998) 8-21-8-31.
  • Skoog, D.A., West, D.M., and Holler, F.J., Fundamentals of Analytical Chemistry, 5th edn, Saunders College Publishing, New York (1988).
  • Selwyn, L., and Tse, S., ‘Supplementary information’, Conservation Research Report, Proteus 99677, Canadian Conservation Institute, Ottawa (2008); available on request from the Canadian Conservation Institute.
  • Schmidt, M., and Siebert, W, ‘The chemistry of sulphur’, Comprehensive Inorganic Chemistry, Pergamon Press, New York (1975) 795-933.
  • Pourbaix, M., Atlas of Electrochemical Equilibria in Aqueous Solutions, 2nd edn, National Association of Corrosion Engineers, Houston (1974).
  • Lem, WJ., and Wayman, M., ‘Decomposition of aqueous dithionite. Part I. Kinetics of decomposition of aqueous sodium dithionite’, Canadian Journal of Chemistry 48 (1970) 776–781.
  • Wayman, M., and Lem, WJ., ‘Decomposition of aqueous dithionite. Part II. A reaction mechanism for the decomposition of aqueous sodium dithionite’, Canadian Journal of Chemistry 48 (1970) 782–787.
  • Carter, J.M., ‘Iron stains on textiles: a study to determine their nature and to evaluate current treatments’, in ICOM Committee for Conservation, 7th Triennial Meeting, Copenhagen, Denmark, 10-14 September 1984: Preprints, ed. D. de Froment, ICOM-CC, Paris (1984) 84.9.11­84.9.14.
  • Odegaard, N., Carroll, S., and Zimmt, WS., Material Characterization Tests for Objects of Art and Archaeology, 2nd edn, Archetype Publications, London (2005).
  • Vuori, J., and Tse, S., ‘A preliminary study of the use of bathophenanthroline iron test strips on textiles’, in ICOM Committee for Conservation, 14th Triennial Meeting, The Hague, 12-16 September 2005: Preprints, ed. I. Verger, James & James, London (2005) Vol. II, 989-995.
  • Westbroek, P., Govaert, F., Gasana, E., Temmerman, E., and Kiekens, P., ‘Possibilities to measure the concentration of sodium dithionite in textile applications by means of amperometric sensors’, AUTEX Research Journal 1 (1999) 30-37. http://www.leeds.ac.uk/autex/v1n1/2270_99.pdf (accessed 3 September 2008).
  • Burgess, H.D., ‘Practical considerations for conservation bleaching’, Journal of the International Institute for Conservation - Canadian Group 13 (1988) 11–26.
  • Burgess, H.D., ‘The stabilization of cellulosic fibres by borohydride derivatives’, in ICOM Committee for Conservation, 9th Triennial Meeting, Dresden, 26-31 August 1990: Preprints, ed. K. Grimstad, ICOM-CC, Paris (1990) 447-452.
  • Norville-Day, H., Townsend, J.H., and Johnston, F., ‘A study of the effects of bleaching treatments on nineteenth-century watercolour pigments, with special reference to Turner’s palette’, in IPC Conference Papers London 1997: Proceedings of the 4th International Conference of the Institute of Paper Conservation, 6-9 April 1997, ed. J. Eagan, Institute of Paper Conservation, Leigh, England (1998) 137-149.
  • Torrent, J., Schwertmann, U., and Barron, V, ‘The reductive dissolution of synthetic goethite and hematite in dithionite’, Clay Minerals 22 (1987) 329–337.
  • Selwyn, L., ‘Overview of archaeological iron: the corrosion problem, key factors affecting treatment, and gaps in current knowledge’, in Metal 2004: Proceedings of the International Conference on Metals Conservation, Canberra 4-8 October 2004, ed. J. Ashton and D. Hallam, National Museum of Australia, Canberra (2004) 294-306.
  • Ankersmit, H.A., Timmermans, R., and Weerdenburg, S., ‘Conservation of a work by Soto: treatment of iron corrosion on paint’, in Modern Art, New Museums: Contributions to the IIC Bilbao Congress 13-17 Sept 2004, ed. A. Roy and P. Smith, International Institute for Conservation, London (2004) 59-62.

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