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Original Articles

Synthesis of Methyl (5Z,9Z,17R)-17-Methylnonadeca-5,9-dienoate, the (R)-Enantiomer of the Structure Proposed for a Metabolite of the Philippine Sponge Plakinastrella sp.

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Pages 2065-2069 | Received 10 Apr 2001, Accepted 02 May 2001, Published online: 22 May 2014

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  • 3) Mori, K., Suguro, T., and Uchida, M., Synthesis of optically active forms of (Z)-14-methylhexadec-8-enal. Tetrahedron, 34, 3119-3123 (1978).
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  • 11) Nakamura, Y. and Mori, K., Pheromone synthesis, CXCVIII. Synthesis of (1S,2S,6S,10R)- and (1S,2R,6R,10R)-1,2,6,10-tetramethyldodecyl propanoate, the components of the sex pheromone of the pine sawfly, Microdiprion pallipes. Eur. J. Org. Chem., 2175-2182 (1999).
  • 12) King, G.G.S., Gries, R., Gries, G., and Slessor, K.N., Optical isomers of 3,13-dimethylheptadecane: sex pheromone components of the western false hemlock looper, Nepytia freemani (Lepidoptera: Geometridae). J. Chem. Ecol., 21, 2027-2045 (1995).
  • 13) Gloor, A., Cadisch, M., Bürgin Schaller, R., Holzgang, H.E., Farkas, M., Kocsis, T., Clerc, J.T., Pretsch, E., Aeschimann, R., Badertscher, M., Brodmeier, T., Fürst, A., Hediger, H.-J., Junghans, M., Kubinyi, H., Munk, M.E., Schriber, H., and Wegmann, D., Spec Tool® Version 2.1, Chemical Concepts GmbH, Weinheim, Germany, 1996.
  • 14) Faulkner, D.J., Personal communication to Mori, K., dated March 13, 2001. He has no idea what the correct structures are and no material to work with. He considers that there can be no excuse for mistakes like this and he has apologized for the error.
  • 15) Qureshi, A., Salvá, J., Harper, M.K., and Faulkner, D.J., Corrections to Vol. 61, page 1541. J. Nat. Prod., 64, 553 (2001).

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