Nonphosphate Degradation Products of Tributyl Phosphate and Their Reactivities in Purex Media under Extreme Conditions

References

• Science and Technology of Tri-Butyl Phosphate, Vol. 1, p. 20, W. W. SCHULTZ and D. NAVRATIL, Eds., CRC Press, Boca Raton, Florida (1984).
   Google Scholar
• L. L. BURGER, “The Chemistry of Tri-butyl Phosphate a Review,” HW-40910, p. 75, General Electric Company, Hanford (1955).
   Google Scholar
• H. D. HARMON, M. L. HYDER, B. TIFFANY, L. W. GRAY, and P. A. SOLTYS, “Behavior of Tri-Butyl Phosphate in A-Line Processes,” DP1418, p. 19, Du Pont de Nemours and Company (1976).
   Google Scholar
• L. STIEGLITZ and R. BECHER, “Chemical and Radiolytic Solvent Degradation in PUREX Process,” Nukleare Entsor-gung, Vol. 2, p. 332, Verlag Chemie (1984).
   Google Scholar
• G. S. NICHOLS, “Decomposition of the Tri-Butyl Phosphate-Nitrate Complexes,” DP526, DuPont de Nemours and Company (1960).
   Google Scholar
• V. M. ADAMOV, V. L. ANDREW, B. N. BELYAEV, G. S. MARKOV, M. S. POLYAKOV, A. E. RITARI, and A. YU SHHL’NIKOV, “Identification of Decomposition Products of Extraction Systems Based on Tri-n-Butyl Phosphate in Aliphatic Hydrocarbons,” Kerntechnik, 55, 3, 133 (1990).
   Web of Science ®Google Scholar
• K. L. NASH, P. G. RICKERT, and E. P. HORWITZ, “Degradation of TRUEX-Dodecane Process Solvent,” SolventExtr. IonExch., 7, 4, 655 (1989).
   Web of Science ®Google Scholar
• Z. NOWAK, “Radiolytic Degradation of Extractant-Diluent Systems Used in the PUREX Process,” Nucleonika, 22, 2, 155 (1977).
   Web of Science ®Google Scholar
• J. P. HOLLAND, J. F. MERKLIN, and J. RAZVI, “The Radiolysis of Dodecane-Tributyl Phosphate Solutions,” Nucl. Instrum. Methods, 153 (1978).
   Google Scholar
• C. H. FRYDRYCH, R. FRYDRYCH, and G. MARX, “Degradation PUREX-Relevanter Tri-alkyl phosphate-Phasen von Uran, Thorium, Cerium und Zirkonium,” Isotopenpraxies, 28, 193 (1993).
   Web of Science ®Google Scholar
• H. T. HAAN and E. M. VANDER, “Complex Formation in the Dilute Uranyl Nitrate-Nitric Acid-Dibutyl Phosphoric Acid-Tributyl Phosphate-AMSCO System,” J. Inorg. Nucl. Chem., 26, 191 (1964).
   Google Scholar
• A. NAYLOR, “TBP Extraction System-TBP and Diluent Degradation,” KR-126, p. 120, Instituttfor Atomenergi (1967).
   Google Scholar
• A. V. BELLIDO and M. N. RUBENNICH, “Influence of the Diluent on the Radiolytic Degradation of TBP in TBP, 30% (v/v)-Diluent-HNO3 Systems,” Radiochim. Acta, 36, 61 (1984).
   Web of Science ®Google Scholar
• H. SUGAI, K. MUNAKATA, S. MIYACHI, and S. YASU, “Emulsions Stabilized by Precipitates of Zirconium and Tribu-tyl Phosphate Degradation Products,” Nucl. Technol., 98, 188 (1992).
   Web of Science ®Google Scholar
• S. A. PAI, J. P. SHUKLA, and M. S. SURBRAMANIAN, “Extraction Behaviour of Uranium, Zirconium and Ruthenium with Gamma-Irradiated Sulfoxides and Tri-n-Butyl Phosphate,” J.Radioanal. Chem., 74, 7,31 (1982).
   Google Scholar
• L. STIEGLITZ, R. BECHER, H. BAUTZ, and R. WILL, “Properties of Heavy Organic Phases and Their Formation in the PUREX Process,” Proc. of ISEC ’86, Vol. 1, p. 239 (1986).
   Google Scholar
• “Evaluation of Safety Concerns Related to Potential Nitrate-Organic Chemical Hazards at Department of Energy Facilities,” U.S. Department of Energy (1994).
   Google Scholar
• G. NISHIO, T. KOIKE, S. MIYATA, J. TAKADA, and K. WATANABE, “Thermochemical Test of Solvent in Nuclear Fuel Reprocessing Plants,” JAERI-Tech 95-029, Japan Atomic Energy Research Institute (1995).
   Google Scholar
• M. L. HYDER, W. G. LUSSIE, and F. E. WITMER, “Explosion in the Tomsk-7 Reprocessing Plant on April 6, 1993,” Nucl. Saf., 37, 3, 222 (1996).
   Google Scholar
• M. L. HYDER, “The Reaction of Tri-n-Butyl Phosphate with Nitrates,” Nucl. Technol., 116, 327 (1996).
   Web of Science ®Google Scholar
• T. V. HEALY, “Fuel Reprocessing Solvent Tributyl Phosphate,” IAEA-SM-207, Vols. 207 through 223, 201, International Atomic Energy Agency (1976).
   Google Scholar
• Science and Technology of Tributyl Phosphate, Vol. 1, p. 141, W. W. SCHULTZ and D. NAVRATIL, Eds., CRC Press, Boca Raton, Florida (1984).
   Google Scholar
• K. KUNO, S. SATO, J. MASUI, T. KASHIMURA, H. SHIMIZU, and K. KOYAMA, “Chemical Behavior of Degradation Products of Tributylphosphate in PUREX Reprocessing,” Proc. 209th National Mtg., Anaheim, California, April 2–7, 1995, NUCL-117, American Chemical Society (1995).
   Google Scholar
• E. ZIMMER and J. BORCHARDT, “Crud Formation in the PUREX and THOREX Processes,” Nucl. Technol., 75, 332 (1986).
   Web of Science ®Google Scholar