56
Views
1
CrossRef citations to date
0
Altmetric
Technical Paper

Studies on Separation of Minor Actinides from Lanthanides from High Level Waste by Extraction Chromatography Using 2,6-Bistriazinyl Pyridine

, , &
Pages 407-416 | Published online: 20 Mar 2017

References

  • Mathur J. N., Murali M. S., and Nash K. L., “Actinide Partitioning—A Review,” Solvent Extr. Ion Exch., 19, 3, 357 (2001).
  • Madic C., Lecomte M., Baron P., and Boullis B., “Separation of Long-Lived Radionuclides from High Active Nuclear Waste,” C. R. Physique, 3, 797 (2002).
  • Paiva A. P. and Malik P., “Recent Advances on the Chemistry of Solvent Extraction Applied to the Reprocessing of Spent Nuclear Fuels and Radioactive Wastes,” J. Radioanal. Nucl. Chem., 261, 2, 485 (2004).
  • Musikas C., “Actinide-Lanthanide Group Separation Using Sulfur and Nitrogen Donor Extractants,” Proc. Int. Symp. Actinide/Lanthanide Separations, Honolulu, Hawaii, USA, December 16–22, 1984.
  • Dam H. H., Reinhoudt D. N., and Verboom W., “Multicoordinate Ligands for Actinide/Lanthanide Separations,” Chem. Soc. Rev., 36, 367 (2007).
  • Kolarik Z., Mullich U., and Gassner F., “Selective Extraction of Am (III) over Eu (III) by 2,6-ditriazolyl-and 2,6-ditriazinylpyridines,” Solv. Extr. Ion Exch., 17, 23 (1999).
  • Kolarik Z., Mullich U., and Gassner F., “Extraction of Am (III) and Eu (III) Nitrates by 2,6-di-(5,6-dipropyl1,2,4-triazin-3-yl)pyridines,” Solv. Extr. Ion Exch., 17, 1155 (1999).
  • Drew M. G. B., Guillaneux D., Hudson M. J., Iveson P. B., Russell M. L., and Madic C., “Lanthanide (III) Complexes of a Highly Efficient Actinide(III) Extracting Agent: 2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine,” Inorg. Chem. Commun., 4, 12 (2001).
  • Drew M. G. B, Guillaneux D., Hudson M. J., Iveson P. B., and Madic C., “Unusual Complexes Formed by the Early Lanthanides with 2,6-bis(5,6-dialkyl-1,2,4-triazin-3yl)-pyridines,” Inorg. Chem. Commun., 4, 462 (2001).
  • Iveson P. B., Riviere C., Guillaneux D., Nierlich M., Thuery P., Ephritikhine M., and Madic C., “Selective Complexation of Uranium (III) over Cerium (III) by 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)pyridines: 1H NMR and X-Ray Crystallography Studies,” Chem. Commun., 1512 (2001).
  • Hill C., Berthon L., Bros P., Dancausse J.-P., and Guillaneux D., “Sanex-BTP Process Development Studies,” J. Nucl. Sci. Tech., 3, 309 (2002).
  • Geist A., Weigl M., and Gompper K., “Small-Scale Actinide (III) Partitioning Processes in Miniature Hollow Fibre Modules,” Radiochim. Acta, 93, 197 (2005).
  • Weigl M., Geist A., Mullich U., and Gompper K., “Kinetics of Americium (III) Extraction and Back Extraction with BTP,” Solv. Extr. Ion Exch., 24, 845 (2006).
  • Nilsson M., Andersson S., Ekberg C., Foreman M. R. S., Hudson M. J., and Skarnemark G., “Inhibiting Radiolysis of BTP Molecules by Addition of Nitrobenzene,” Radiochim. Acta, 94, 103 (2006).
  • Drew M. G. B., Foreman M. R. St. J., Geist A., Hudson M. J., Marken F., Norman V., and Weigl M., “Synthesis, Structure, and Redox States of Homoleptic d-Block Metal Complexes with bis-1,2,4-triazin-3-yl-pyridine and 1,2,4-triazin-3-ylbipyridine Extractants,” Polyhedron, 25, 889 (2006).
  • Denecke M. A., Rossberg A., Panak P. J., Weigl M., Schimmelpgfennig B., and Geist A., “Characterisation and Comparison of Cm (III) and Eu (III) Complexed with 2,6-di(5,6-dipropyl-1,2,4-triazin-3-yl) pyridine Using EXAFS, TRFLS, and Quantum-Chemical Methods,” Inorg. Chem., 44, 8418 (2005).
  • Denecke M. A. et al., “A Comparative Spectroscopic Study of U(III)/Am(III) and Ln(III) Complexed with N-Donor Ligands,” C. R. Chimie, 10, 872 (2007).
  • Kolarik Z., “Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions,” Chem. Rev., 108, 4208 (2008).
  • Wei Y.-Z., Sabharwal K. N., Kumagai M., Asakura T., Uchiyama G., and Fujine S., “Preparation of Novel Silica-Based Nitrogen Donor Extraction Resins and Their Adsorption Performance for Trivalent Americium and Lanthanides,” J. Nucl. Sci. Technol., 37, 1108 (2000).
  • Wei Y.-Z., Hoshi H., Kumagai M., Asakura T., and Morita Y., “Separation of Am(III) and Cm(III) from Trivalent Lanthanides by 2,6-bistriazinylpyridine Extraction Chromatography for Radioactive Waste Management,” J. Alloys Comp., 374, 447 (2004).
  • Hoshi H., Wei Y.-Z., Kumagai M., Asakura T., and Morita Y.. “Separation of Trivalent Actinides from Lanthanides by Using R-BTP Resins and Stability of R-BTP Resin,” J. Alloys Comp., 408–412, 1274 (2006).
  • Usuda S., Liu R., Wei Y., Xu Y., Yamazaki H., and Wakui Y., “Evaluation Study on Properties of a Novel R-BTP Extraction Resin—From a Viewpoint of Simple Separation of Minor Actinides,” J. Ion Exchange, 21, 35 (2010).
  • Case F. H., “The Preparation of 2,4 and 2,6-Bis-Triazinyl and Triazolinyl Derivatives of Pyridine,” J. Heterocyclic Chem., 8, 1043 (1971).
  • Sharpless K. B., Lauer R. F., Repič O., Teranishi A. Y., and Williams D. R., “Permanganate in Acetic Anhydride: a-Diketones Directly from Olefins,” J. Amer. Chem. Soc., 93, 3303 (1971).
  • Antony M. P. et al., “Development of a CMPO Based Extraction Process for Partitioning of Minor Actinides and Demonstration with Genuine Fast Reactor Fuel Solution (155 GWd0 Te),” Radiochim. Acta, 99, 207 (2011).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.