Biodiesel from alternative oilseed feedstocks: camelina and field pennycress

• Knothe G. ‘Designer’ biodiesel: optimizing fatty ester composition to improve fuel properties. Energy Fuels22,1358–1364 (2008).
   Web of Science ®Google Scholar
• Moser BR. Biodiesel production, properties, and feedstocks. In vitroCell Dev. Biol. Plant45,229–266 (2009).
   Web of Science ®Google Scholar
• Pradham A, Shrestha DS, McAloon A et al.Energy Life-Cycle Assessment of Soybean Biodiesel. US Department of Agriculture, Washington, DC, USA (2009).
   Google Scholar
• US EPA. EPA Finalizes Regulations for the National Renewable Fuel Standard Program for 2010 and Beyond. US EPA, Washington, DC, USA (2010).
   Google Scholar
• Moser BR, Cermak SC, Isbell TA. Evaluation of castor and lesquerella oil derivatives as additives in biodiesel and ultra low sulfur diesel fuel. Energy Fuels22,1349–1352 (2008).
   Web of Science ®Google Scholar
• Moser BR, Erhan SZ. Branched chain derivatives of alkyl oleates: tribological, rheological, oxidation, and low temperature properties. Fuel87,2253–2257 (2008).
   Google Scholar
• Soares VLP, Nascimento RSV, Albinante SR. Ester-additives as inhibitors of the gelification of soybean oil methyl esters in biodiesel. J. Therm. Anal. Calorim.97,621–626 (2009).
   Google Scholar
• Dunn RO. Antioxidants for improving storage stability of biodiesel. Biofuels Bioprod. Bioref.2,304–318 (2008).
   Web of Science ®Google Scholar
• Moser BR. Efficacy of myricetin as an antioxidant additive in methyl esters of soybean oil. Eur. J. Lipid Sci. Technol.110,1167–1174 (2008).
   Web of Science ®Google Scholar
• Tang H, Wang A, Salley SO, Ng KYS. The effect of natural and synthetic antioxidants on the oxidative stability of biodiesel. J. Am. Oil Chem. Soc.85,373–382 (2008).
   Web of Science ®Google Scholar
• Dinkov R, Hristov G, Sratiev D, Aldayri VB. Effect of commercially available antioxidants over biodiesel/diesel blends stability. Fuel88,732–737 (2009).
   Web of Science ®Google Scholar
• Moser BR, Vaughn SF. Evaluation of alkyl esters from Camelina sativa oil as biodiesel and as blend components in ultra low sulfur diesel fuel. Bioresour. Technol.101,646–653 (2010).
   PubMed Web of Science ®Google Scholar
• McCormick RL, Westbrook SR. Storage stability of biodiesel and biodiesel blends. Energy Fuels24,690–698 (2010).
   Web of Science ®Google Scholar
• Bondioli P, Gasparoli A, Bella LD, Tagliabue S, Toso G. Biodiesel stability under commercial storage conditions over one year. Eur. J. Lipid Sci. Technol.105,735–741 (2003).
   Web of Science ®Google Scholar
• Moser BR. Influence of extended storage on fuel properties of methyl esters prepared from canola, palm, soybean and sunflower oils. Renew. Energ.36,1221–1226 (2011).
   Web of Science ®Google Scholar
• Dunn RO. Crystallization behavior of fatty acid methyl esters. J. Am. Oil Chem. Soc.85,961–972 (2008).
   Web of Science ®Google Scholar
• Lee I, Johnson LA, Hammond EG. Reducing the crystallization temperature of biodiesel by winterizing methyl soyate. J. Am. Oil Chem. Soc.73,631–636 (1996).
   Web of Science ®Google Scholar
• Lee I, Johnson LA, Hammond EG. Use of branched-chain esters to reduce the crystallization temperature of biodiesel. J. Am. Oil Chem. Soc.72,1155–1160 (1995).
   Web of Science ®Google Scholar
• Foglia TA, Nelson LA, Dunn RO, Marmer WN. Low-temperature properties of alkyl esters of tallow and grease. J. Am. Oil Chem. Soc.74,951–955 (1997).
   Web of Science ®Google Scholar
• Soltic P, Edenhauser D, Thurnheer T, Schreiber D, Sankowski A. Experimental investigation of mineral diesel fuel, GTL fuel, RME and neat soybean and rapeseed oil combustion in a heavy duty on-road engine with exhaust gas after treatment. Fuel88,1–8 (2009).
   Google Scholar
• Fernando S, Hall C, Jha S. NOx reduction from biodiesel fuels. Energy Fuels20,376–382 (2006).
   Web of Science ®Google Scholar
• Lopez JM, Jimenez F, Aparicio F, Flores N. On-road emissions from urban buses with SCR + urea and EGR + DPF systems using diesel and biodiesel. Transportation Res. D14,1–5 (2009).
   Web of Science ®Google Scholar
• West AH, Posarac D, Ellis N. Assessment of four biodiesel production processes using HYSY. Plant Bioresour. Technol.99,6587–6601 (2008).
   PubMed Web of Science ®Google Scholar
• Haas MJ, McAloon AJ, Yee WC, Foglia TA. A process model to estimate biodiesel production costs. Bioresour. Technol.97,671–678 (2006).
   PubMed Web of Science ®Google Scholar
• You YD, Shie JL, Chang CY et al. Economic cost analysis of biodiesel production: case in soybean oil. Energy Fuels22,182–189 (2007).
   Web of Science ®Google Scholar
• Canacki M, Sanli H. Biodiesel production from various feedstocks and their effects on the fuel properties. J. Ind. Microbiol. Biot.35,431–441 (2008).
   Google Scholar
• Angarita EEY, Lora EES, da Casta RE, Torres EA. The energy balance in the palm oil-derived methyl ester (PME) life cycle for the cases in Brazil and Columbia. Renew. Energ.34,2905–2913 (2009).
   Web of Science ®Google Scholar
• Kallivroussis L, Natsis A, Papadakis G. The energy balance of sunflower production for biodiesel in Greece. Biosystems Eng.81,347–354 (2002).
   Web of Science ®Google Scholar
• Pimentel D, Patzek TW. Ethanol production using corn, switchgrass, and wood; biodiesel production using soybean and sunflower. Nat. Resour. Res.14,65–76 (2005).
   Google Scholar
• Hill J, Nelson E, Tilman D, Polasky S, Tiffany D. Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels. Proc. Natl Acad. Sci. USA103,11206–11210 (2006).
   PubMed Web of Science ®Google Scholar
• Sheehan J, Camobrecco V, Duffied J, Grabowski M, Shapouri H. Life Cycle Inventory of Biodiesel and Petroleum Diesel for Use in an Urban Bus. NREL Final Report SR-580–24089. National Renewable Energy Laboratory, Goldon, CO, USA (1998).
   Google Scholar
• Pradhan A, Shrestha DS, Van Gerpen J, Duffied J. The energy balance of soybean oil biodiesel production: a review of past studies. Trans. ASABE51,185–194 (2008).
   Web of Science ®Google Scholar
• Van Gerpen J. Biodiesel processing and production. Fuel Process. Technol.86,1097–1107 (2005).
   Web of Science ®Google Scholar
• O’Brien RD. Fats and oils. In: Formulating and Processing for Applications (3rd Edition). CRC Press, Boca Raton, FL, USA, 8–196 (2009).
   Google Scholar
• Freedman B, Pryde EH, Mounts TL. Variables affecting the yields of fatty esters from transesterified vegetable oils. J. Am. Oil Chem. Soc.61,1638–1643 (1984).
   Web of Science ®Google Scholar
• Rashid U, Anwar F. Production of biodiesel through optimized alkaline-catalyzed transesterification of rapeseed oil. Fuel87,265–273 (2008).
   Web of Science ®Google Scholar
• Rashid U, Anwar F, Arif M. Optimization of base catalytic methanolysis of sunflower (Helianthus annus) seed oil for biodiesel production by using response surface methodology. Ind. Eng. Chem. Res.48,1719–1726 (2009).
   Web of Science ®Google Scholar
• Lotero E, Liu Y, Lopez DE, Suwannakarn K, Bruce DA, Goodwin JG Jr. Synthesis of biodiesel via acid catalysis. Ind. Eng. Chem. Res.44,5353–5363 (2005).
   Web of Science ®Google Scholar
• Narasimharao K, Lee A, Wilson K. Catalysts in production of biodiesel: a review. J. Biobased Mat. Bioenerg.1,19–30 (2007).
   Web of Science ®Google Scholar
• Canacki M, Van Gerpen J. Biodiesel production via acid catalysis. Trans. ASAE42,1203–1210 (1999).
   Google Scholar
• Canacki M, Van Gerpen J. A pilot plant to produce biodiesel from high free fatty acid feedstocks. Trans. ASAE46,945–954 (2003).
   Google Scholar
• Kwiecien J, Hajek M, Skopal F. Combined effect of water and KOH on rapeseed oil methanolysis. Bioresour. Technol.101,3121–3125 (2010).
   Google Scholar
• Naik M, Meher LC, Naik SN, Das LM. Production of biodiesel from high free fatty acid Karanja (Pongamia pinnata) oil. Biomass Bioenerg.32,354–357 (2008).
   Web of Science ®Google Scholar
• Haas MJ. Improving the economics of biodiesel production through the use of low value lipids as feedstocks: vegetable oil soapstock. Fuel Process Technol.86,1087–1096 (2005).
   Web of Science ®Google Scholar
• Sanli H, Canakci M. Effects of different alcohol and catalyst usage on biodiesel production from different vegetable oils. Energy Fuels22,2713–2719 (2008).
   Web of Science ®Google Scholar
• Frőhlich A, Rice B. Sources of methyl ester yield reduction in methanolysis of recycled vegetable oil. J. Am. Oil Chem. Soc.86,269–275 (2009).
   Google Scholar
• Frőhlich A, Rice B, Vicente G. The conversion of low grade tallow into biodiesel-grade methyl ester. J. Am. Oil Chem. Soc.87,825–833 (2010).
   Web of Science ®Google Scholar
• Moser BR, Knothe G, Vaughn SF, Isbell TA. Production and evaluation of biodiesel from field pennycress (Thlaspi arvense L.) oil. Energy Fuels23,4149–4155 (2009).
   Web of Science ®Google Scholar
• Moser BR, Vaughn SF. Coriander seed oil methyl esters as biodiesel fuel: unique fatty acid composition and excellent oxidative stability. Biomass Bioenerg.34,550–558 (2010).
   Web of Science ®Google Scholar
• Sharma YC, Singh B, Korstad J. High yield and conversion of biodiesel from a nonedible feedstock (Pongamia pinnata). J. Agric. Food Chem.58,242–247 (2010).
   PubMedGoogle Scholar
• Rashid U, Anwar F, Moser BR, Knothe G. Moringa oleifera oil: a possible source of biodiesel. Bioresour. Technol.99,8175–8179 (2008).
   PubMed Web of Science ®Google Scholar
• Zhou W, Boocock DBG. Phase behavior of the base-catalyzed transesterification of soybean oil. J. Am. Oil Chem. Soc.83,1041–1045 (2006).
   Web of Science ®Google Scholar
• Zhou W, Boocock DBG. Phase distribution of alcohol, glycerol, and catalyst in the transesterification of soybean oil. J. Am. Oil Chem. Soc.83,1047–1052 (2006).
   Web of Science ®Google Scholar
• Boocock DGB, Konar SK, Mao V, Sidi H. Fast one-phase oil-rich processes for the preparation of vegetable oil methyl esters. Biomass Bioenerg.11,43–50 (1996).
   Web of Science ®Google Scholar
• Di Felice R, De Faveri D, De Andreis P, Ottonello P. Component distribution between light and heavy phases in biodiesel processes. Ind. Eng. Chem. Res.47,7862–7867 (2008).
   Google Scholar
• Knothe G. Improving biodiesel fuel properties by modifying fatty ester composition. Energ. Environ. Sci.2,759–766 (2009).
   Web of Science ®Google Scholar
• Jham GN, Moser BR, Shah SN et al. Wild Brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel. J. Am. Oil Chem. Soc.86,917–926 (2009).
   Web of Science ®Google Scholar
• Knothe G, Cermak SC, Evangelista RL. Cuphea oil as a source of biodiesel with improved fuel properties caused by high content of methyl decanoate. Energy Fuels23,1743–1747 (2009).
   Web of Science ®Google Scholar
• Schober S, Steidl I, Mittelbach M. Ester content evaluation in biodiesel from animal fats and lauric oils. Eur. J. Lipid Sci. Technol.108,309–314 (2006).
   Google Scholar
• da Silva RB, Neto AFL, dos Santos LSS et al. Catalysts of Cu(II) and Co(II) ions adsorbed in chitosan used in transesterification of soy bean and babassu oils – a new route for biodiesel synthesis. Bioresour. Technol.99,6793–6798 (2008).
   PubMed Web of Science ®Google Scholar
• Moser BR, Cermak SC, Knothe G. Biodiesel from meadowfoam (Limnanthes alba L.) seed oil: oxidative stability and unusual fatty acid composition. Energy Environ. Sci.3,318–327 (2010).
   Google Scholar
• Knothe G. Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters. Fuel Process Technol.86,1059–1070 (2005).
   Web of Science ®Google Scholar
• Kinney AJ, Clemente TE. Modifying soybean oil for enhanced performance in biodiesel blends. Fuel Process Technol.86,1137–1147 (2005).
   Web of Science ®Google Scholar
• Bondioli P. Nature of some insoluble materials recovered from biodiesel samples. Eur. J. Lipid Sci. Technol.111,814–821 (2009).
   Google Scholar
• Gunstone FD, Harwood JL. Occurrence and characterization of oils and fats. In: The Lipid Handbook (3rd Edition). Gunstone FD, Harwood JL, Dijkstra AJ (Eds). CRC Press, Boca Raton, FL, USA, 37–142 (2007).
   Google Scholar
• Knothe G, Dunn RO. A comprehensive evaluation of the melting points of fatty acids and esters determined by differential scanning calorimetry. J. Am. Oil Chem. Soc.86,843–856 (2009).
   Web of Science ®Google Scholar
• Moser BR, Haas MJ, Winkler JK et al. Evaluation of partially hydrogenated methyl esters of soybean oil as biodiesel. Eur. J. Lipid Sci. Technol.109,17–24 (2007).
   Web of Science ®Google Scholar
• Bouriazos A, Sotiriou, S, Vangelis C, Papadogianakis G. Catalytic conversions in aqueous media. Part 4. Selective hydrogenation of polyunsaturated methyl esters of vegetable oils for upgrading biodiesel. J. Organomet. Chem.695,327–337 (2010).
   Google Scholar
• Holman RT, Elmer OC. The rates of oxidation of unsaturated fatty acids and esters. J. Am. Oil Chem. Soc.24,127–129 (1947).
   Web of Science ®Google Scholar
• Gunstone FD. The Chemistry of Oils and Fats. Sources, Composition, Properties and Uses. CRC Press, Boca Raton, FL, USA, 150–168 (2004).
   Google Scholar
• Moser BR. Comparative oxidative stability of fatty acid alkyl esters by accelerated methods. J. Am. Oil Chem. Soc.86,699–706 (2009).
   Google Scholar
• Porter NA, Caldwell SE, Mills KA. Mechanisms of free radical oxidation of unsaturated lipids. Lipids30,277–290 (1995).
   PubMed Web of Science ®Google Scholar
• Isbell TA, Abbott TP, Carlson KD. Oxidative stability index of vegetable oils in binary mixtures with meadowfoam oil. Ind. Crops Prod.9,115–123 (1999).
   Google Scholar
• Knothe G, Steidley KR. Kinematic viscosity of biodiesel fuel components and related compounds. Influence of compound structure and comparison to petrodiesel fuel components. Fuel84,1059–1065 (2005).
   Web of Science ®Google Scholar
• Krisnangkura K, Yimsuwan T, Pairintra R. An empirical approach in predicting biodiesel viscosity at various temperatures. Fuel85,107–113 (2006).
   Web of Science ®Google Scholar
• Knothe G, Steidley KR. Kinematic viscosity of biodiesel components (fatty acid alkyl esters) and related compounds at low temperatures. Fuel86,2560–2567 (2007).
   Web of Science ®Google Scholar
• Yuan W, Hansen AC, Zhang Q, Tan Z. Temperature-dependent kinematic viscosity of selected biodiesel fuels and blends with diesel fuel. J. Am. Oil Chem. Soc.82,195–199 (2005).
   Web of Science ®Google Scholar
• Joshi RM, Pegg MJ. Flow properties of biodiesel fuel blends at low temperatures. Fuel86,143–151 (2007).
   Web of Science ®Google Scholar
• Knothe G, Matheaus AC, Ryan TW 3rd. Cetane numbers of branched and straight-chain fatty esters determined in an ignition quality tester. Fuel82,971–975 (2003).
   Web of Science ®Google Scholar
• Tilman D, Socolow R, Foley JA et al. Beneficial biofuels – the food, energy, and environment trilemma. Science325,270–271 (2009).
   PubMed Web of Science ®Google Scholar
• Chisti Y. Biodiesel from microalgae. Biotechnol. Adv.25,294–306 (2007).
   PubMed Web of Science ®Google Scholar
• Ahmad AL, Yasin NHM, Derek CJC, Lim JK. Microalgae as a sustainable energy source for biodiesel production: a review. Renew. Sustain. Energ. Rev.15,584–593 (2011).
   Web of Science ®Google Scholar
• Koh MY, Mohd. Ghazi TI. A review of biodiesel production from Jatropha curcas L. oil. Renew. Sustain. Energ. Rev.15,2240–2251 (2011).
   Google Scholar
• Juan JC, Kartika DA, Wu TY, Hin TYY. Biodiesel production from jatropha oil by catalytic and non-catalytic approaches: an overview. Bioresour. Technol.102,452–460 (2011).
   PubMed Web of Science ®Google Scholar
• Franzke A, Lysak MA, Al-Shehbaz IA, Koch MA, Mummenhoff K. Cabbage family affairs: the evolutionary history of the Brassicaceae. Trends Plant Sci.16,108–116 (2011).
   PubMed Web of Science ®Google Scholar
• Haramoto ER, Gallandt ER. Brassica cover cropping for weed management: a review. Renew. Agric. Food Sys.19,187–198 (2004).
   Web of Science ®Google Scholar
• Fahey JW, Zalcmann AT, Talalay P. The chemical diversity and distribution of glucosinolates and isothiocyanates among plants. Phytochemistry56,5–51 (2001).
   PubMed Web of Science ®Google Scholar
• Halkier BA, Gershenzon J. Biology and biochemistry of glucosinolates. Annu. Rev. Plant Biol.57,303–333 (2006).
   PubMed Web of Science ®Google Scholar
• Griffiths DW, Birch ANE, Hillman JR. Antinutritional compounds in the Brassicaceae – analysis, biosynthesis, chemistry and dietary effects. J. Hort. Sci. Biotech.73,1–18 (1998).
   Web of Science ®Google Scholar
• Isbell TA. US effort in the development of new crops (lesquerella, pennycress, coriander and cuphea). Proc. J. Chevreul16,205–210 (2009).
   Google Scholar
• Vaughn SF, Isbell TA, Weisleder D, Berhow MA. Biofumigant compounds released by field pennycress (Thlaspi arvense) seedmeal. J. Chem. Ecol.31,167–177 (2005).
   Google Scholar
• Zubr J. Oil-seed crop: Camelina sativa. Ind. Crops Prod.6,113–119 (1997).
   Web of Science ®Google Scholar
• Moser BR. Camelina (Camelina sativa L.) oil as a biofuels feedstock: golden opportunity or false hope? Lipid Technol.22,270–273 (2010).
   Google Scholar
• Zubr J, Matthaus B. Effects of growth conditions on fatty acids and tocopherols in Camelina sativa oil. Ind. Crops Prod.15,155–162 (2002).
   Web of Science ®Google Scholar
• Frohlich A, Rice B. Evaluation of Camelina sativa oil as a feedstock for biodiesel production. Ind. Crops Prod.21,25–31 (2005).
   Web of Science ®Google Scholar
• Schuster A, Friedt W. Glucosinolate content and composition as parameters of quality of Camelina seed. Ind. Crops Prod.7,297–302 (1998).
   Web of Science ®Google Scholar
• Patil PD, Gude VG, Deng S. Biodiesel production from Jatropha curcas, waste cooking, and Camelina sativa oils. Ind. Eng. Chem. Res.48,10850–10856 (2009).
   Web of Science ®Google Scholar
• Patil PD, Deng S. Transesterification of Camelina sativa oil using heterogeneous metal oxide catalysts. Energy Fuels23,4619–4624 (2009).
   Google Scholar
• Patil PD, Gude VG, Deng S. Transesterification of Camelina sativa oil using supercritical and subcritical methanol with cosolvents. Energy Fuels24,746–751 (2010).
   Google Scholar
• Patil PD, Gude VG, Camacho LM, Deng S. Microwave-assisted catalytic transesterification of Camelina sativa oil. Energy Fuels24,1298–1304 (2010).
   Web of Science ®Google Scholar
• Vaughn SF, Palmquist DE, Duval SM, Berhow MA. Herbicidal activity of glucosinolate-containing seed meals. Weed Sci.54,743–748 (2006).
   Web of Science ®Google Scholar
• Moser BR, Shah SN, Winkler-Moser JK, Vaughn SF, Evangelista RL. Composition and physical properties of cress (Lepidium sativum L.) and field pennycress (Thlaspi arvense L.) oils. Ind. Crops Prod.30,199–205 (2009).
   Google Scholar
• Sharma N, Cram D, Huebert T, Zhou N, Parkin IAP. Exploiting the wild crucifer Thlaspi arvense to identify conserved and novel genes expressed during a plant’s response to cold stress. Plant Mol. Biol.63,171–184 (2007).
   Google Scholar
• Daxenbichler ME, Spencer GF, Carlson DG, Rose BG, Brinker AM, Powell RG. Glucosinolate composition of seeds from 297 species of wild plants. Phytochemistry30,2623–2638 (1991).
   Web of Science ®Google Scholar
• Moyer JR, Hironaka R. Digestible energy and protein content of some annual weeds, alfalfa, bromegrass, and tame oats. Can. J. Plant Sci.73,1305–1308 (1993).
   Web of Science ®Google Scholar
• Ullrich I, Jahn-Deesbach W. Proteingehalt und proteinzusammensetzung verschiedener unkrautarten. Angew. Bot.58,255–266 (1984).
   Google Scholar
• Moser BR. Complementary blending of meadow foam seed oil methyl esters with biodiesel prepared from soybean and waste cooking oils to enhance fuel properties. Energy Environ. Sci.4,2160–2167 (2011).
   Google Scholar

▪ Website

• US EIA. Monthly Energy Review January 2012, Table 10.4 Biodiesel Overview. www.eia.gov/totalenergy/data/monthly/pdf/sec10_8.pdf
   Google Scholar