Pesticide residues in fresh and processed edible mushrooms from Czech markets

ABSTRACT

The occurrence of pesticide residues, their metabolites and degradation products in 49 edible mushrooms (fresh, dried, canned and frozen) was investigated. Using QuEChERS extraction, followed by liquid and gas chromatography coupled with tandem mass spectrometry, the samples collected from Czech markets were tested for 427 analytes. A total of 21 pesticide residues, their metabolites and pesticide synergists were found in quantifiable concentrations. The most frequently detected pesticide residues included prochloraz and its metabolites, metrafenone and carbendazim. Two mushroom samples were found to be in violation of the maximum residue level. In addition, the fate of 13 pesticides during the processing of fresh mushrooms was investigated. The processing factors calculated from the data ranged from 6.0 to 12.3 for drying and from 0.3 to 1.3 for deep-freezing. The results showed that most of the pesticide residues tested were stable under the conditions of mushroom processing.

KEYWORDS:

• Edible mushrooms
• pesticide residues
• processing factors
• LC–MS/MS
• GC–MS/MS

Disclosure statement

No potential conflict of interest was reported by the author(s).

Supplementary material

Supplemental data for this article can be accessed online at https://doi.org/10.1080/19393210.2023.2259867.

Additional information

Funding

This work was supported by the METROFOOD-CZ research infrastructure project [MEYS Grant No: LM2023064] including access to its facilities; and a specific university research [A1_FPBT_2023_002].