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Review Article

The organoboron compounds: their Lewis acidity and catalytic activity

Mikhail M. Shmakova G. K. Boreskov Institute of Catalysis SB RAS, Acad. Lavrentiev Ave. 5, 630090Novosibirsk, RussiaORCID Iconhttps://orcid.org/0000-0002-6069-2614View further author information
ORCID Icon,
Sergey A. Prikhod’koa G. K. Boreskov Institute of Catalysis SB RAS, Acad. Lavrentiev Ave. 5, 630090Novosibirsk, RussiaCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0002-7990-148XView further author information
ORCID Icon,
Valentina N. Panchenkoa G. K. Boreskov Institute of Catalysis SB RAS, Acad. Lavrentiev Ave. 5, 630090Novosibirsk, RussiaView further author information
,
Maria N. Timofeevaa G. K. Boreskov Institute of Catalysis SB RAS, Acad. Lavrentiev Ave. 5, 630090Novosibirsk, RussiaORCID Iconhttps://orcid.org/0000-0003-2848-875XView further author information
ORCID Icon,
Vadim V. Bardinb N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, Acad. Lavrentiev Ave. 9, 630090Novosibirsk, RussiaORCID Iconhttps://orcid.org/0000-0002-6088-2530View further author information
ORCID Icon,
Valentin N. Parmona G. K. Boreskov Institute of Catalysis SB RAS, Acad. Lavrentiev Ave. 5, 630090Novosibirsk, RussiaORCID Iconhttps://orcid.org/0000-0002-8877-7388View further author information
ORCID Icon &
Nicolay Yu. Adonina G. K. Boreskov Institute of Catalysis SB RAS, Acad. Lavrentiev Ave. 5, 630090Novosibirsk, RussiaView further author information
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Received 01 Aug 2023, Accepted 19 Mar 2024, Published online: 03 Apr 2024
 
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ABSTRACT

The review examines and summarizes methods for determining the Lewis acidity of organoboron compounds. Insights into the challenges and future development towards scales of Lewis acidity for boron Lewis acids based on the thermodynamic (global), spectral (effective) and intrinsic methods also are provided. The main challenges arising from the application of data on the Lewis acidity of organoboranes for an explanation of their catalytic behavior are discussed.

Graphical Abstract

List of Abbreviations

Table

Acknowledgments

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental assignment for Boreskov lnstitute of Catalysis (project FWUR-2024-0035).

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation [FWUR-2024-0035].

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