Corrosion behavior of zirconium alloys in the aqueous environment. Phenomenological aspects. Overview

ABSTRACT

The present work highlights opportunities and open research issues about the phenomena accompanying the Zr corrosion and describes that with both, the generalization of established opinions and the presentation of individual investigations. The overview aimed to lay out the phenomena accompanying Zr corrosion to better understand the restrictions and assumptions of modern process models and reveal perspectives of simulations. The formation and destruction of the protective oxidized cladding were analyzed and summarized in the following groups: chemical composition of the alloy; kinetics of oxide layer formation; electrochemical processes; chemistry of the coolant; hydrogen absorption; irradiation. The physicochemical, electrochemical, and crystallographic processes driving the multi-scale, multi-phase, multi-parametric Zr corrosion are strongly correlated, barely distinguishable, and have combined, and competing impacts that are very comprehensive to the numerical modeling. Despite a boundless number of studies, mostly empirical, Zr corrosion does not still have fundamental analytical descriptions. The noticeable improvement could be achieved by applying modern machine learning technologies allowing the analysis and optimization of multi-parametrical processes. The described groups of phenomena can be included in the clustering of the neural network of the deep learning approach in the integrated expert system for the Zr alloy corrosion.

KEYWORDS:

• word
• Zr alloy
• corrosion
• polarisation curve
• passivation
• transpassivation
• coolant chemistry
• hydrating
• irradiation

Acknowledgments

This work was supported by the Federal Ministry for the Environment, Nature Conservation, Nuclear Safety and Consumer Protection (BMUV) of Germany (Bundesministerium für Umwelt, Naturschutz, nukleare Sicherheit und Verbraucherschutz (BMUV) Deutschlands), Contract-Nr.: 808875-0076.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This work was supported by the the Federal Ministry for the Environment, Nature Conservation, Nuclear Safety and Consumer Protection (BMUV) of Germany (das Bundesministerium für Umwelt, Naturschutz, nukleare Sicherheit und Verbraucherschutz (BMUV) des Deutschlands) [Contract-Nr.: 808875-0076].