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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 16-17
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Original Articles

A New Synthesis of α-Cyano Substituted Vinyl Sulfides Using Cyano(methylthio)Methyltrimethylsilane

Dong Il Han Department of Chemistry, Korea Advanced Institute of Science and Technology, P.O. Box 150 Cheongyangni, Seoul, 131, Korea
&
Dong Young Oh Department of Chemistry, Korea Advanced Institute of Science and Technology, P.O. Box 150 Cheongyangni, Seoul, 131, Korea
Pages 2111-2116 | Published online: 05 Dec 2006
 
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Abstract

A new general synthesis of α-cyano substituted vinyl sulfides which involves the reaction of carbonyl compounds with cyano(methylthio)methyltrimethylsilane is described, which is extended with success to readily enolizable carbonyl compounds.

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