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Original Articles

A Thermodynamic Model for Liquid-Liquid Chromatography with a Binary Mobile Phase

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Pages 23-29 | Published online: 05 Dec 2006
 

Abstract

A simple model which previously led to successful predictive equations for gas-liquid partition coefficients on mixed stationary phases has been slightly modified to include liquid-liquid partitioning. Predictive expressions are developed for distribution coefficients determined from liquid-liquid chromatographic studies using a binary mobile phase. Limitations of the method are briefly discussed.

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