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Original Articles

A Thermodynamic Model for Liquid-Liquid Chromatography with a Binary Mobile Phase

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Pages 23-29 | Published online: 05 Dec 2006

References

  • loCke , D. C. and Martire , D. E. 1967 . Theory of Solute Retention in Liquid-Liquid Chromatography . Anal. Chem. , 39 : 921
  • loCke , D. C. 1967 . Thermodynamic Study of Liquid-Liquid Chromatography . J. Gas Chromatog. , 5 : 202
  • Acree , W. E. Jr. and Bertrand , G. L. 1979 . Thermochemical Investigations of Nearly Ideal Binary Solvents. 4. Gas-Liquid Partition Coefficients in Complexing and Noncomplexing Systems . J. Phys. Chem. , 83 : 2355
  • Harbison , M. W. P. , Laub , R. J. , Martire , D. E. , Purnell , J. H. and Williams , P. S. 1979 . Solute Infinite-Dilution Partition Coefficients with Mixtures of Squalane and Dinonyl Phthalate Solvents at 30.0° C . J. Phys. Chem. , 83 : 1262
  • Littlewood , A. B. , Phillips , C. S. G. and Price , D. T. 1955 . The Chromatography of Gases and Vapours. Part V. Partition Analyses with Columns of Silicone 702 and of Tritolyl Phosphate . J. Chem. Soc. , : 1480
  • Burchfield , T. E. and Bertrand , G. L. 1974 . Thermochemical Investigations of Nearly Ideal Binary Solvents. II. Standard Heats of Solution in Systems of Nonspecific Interactions . J. Solution Chem. , 4 : 205
  • Acree , W. E. Jr. and Bertrand , G. L. 1977 . Thermochemical Investigations of Nearly Ideal Binary Solvents. 3. Solubility in Systems of Nonspecific Interactions . J. Phys. Chem. , 81 : 1170
  • Acree , W. E. Jr. and Bertrand , G. L. manuscript in preparation
  • Many of the requirements of the model system are identical to those imposed in the derivation of equation (2)
  • Buchowski , H. and Teperek , J. 1971 . Thermodynamics of Solutions in Mixed Solvents and Synergic Effects . Roczniki Chemii Ann. Soc. Chim. Polonorum , 45 : 1329

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