Electrophoretic deposition of hydroxyapatite coating on biodegradable Mg–4Zn–4Sn–0.6Ca–0.5Mn alloy

ABSTRACT

Aluminium-free Mg–4Zn–4Sn–0.6Ca–0.5Mn alloys, with similar mechanical properties to natural bone, were produced and used as substrates for electrophoretic deposition (EPD) of hydroxyapatite (HA) powder. HA powder was deposited at three levels of DC voltage (50, 100 and 150 V) at different times. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) were used for phase characterization. Cavities appeared in coated specimens with a coating thickness of more than 70 µm and micro-cracks appeared in a coating thickness of more than 100 µm. The maximum adhesion strength of coatings was 2.8 ± 1.1 MPa for 150 V–5 s. Electrochemical impedance spectroscopy (EIS) test showed that coating resistance and charge transfer resistance increased in the coated samples of 100 V–5 s and 150 V–5 s, respectively.

KEYWORDS:

• Electrophoretic deposition
• biodegradation
• Mg alloy
• hydroxyapatite

Acknowledgements

The authors would like to thank from the ‘Clinical Research Development Center of Baqiyatallah hospital’ for their kindly cooperation.

Disclosure statement

No potential conflict of interest was reported by the authors.