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Original Articles

The Additive Action of Some Organic Chlorides and Sulfides in the Four-Ball Lubricant Test

Pages 22-31 | Published online: 25 Mar 2008
 

Abstract

When tested by the four-ball extreme-pressure procedure, oil solutions of t-octyl chloride at the 2 percent chlorine level rated approximately equal to oil solutions of di-t-octyl disulfide at the 2 percent sulfur level, and both of these additive blends rated better than n-octyl chloride in oil at the 2 percent chlorine level or di-n-octyl disulfide in oil at the 2 percent sulfur level. n-Octyl chloride and di-n-octyl disulfide in oil at corresponding concentrations of active element were approximately equivalent in additive action. t-Octyl chloride was almost as good at the 1 percent as at the 2 percent chlorine level. Mixtures of di-t-octyl disulfide and t-octyl chloride in oil at the level 1 percent S-1 percent Cl rated approximately twice as well as di-t-octyl disulfide (2 percent S) or t-octyl chloride (2 percent Cl). Some finer points of the action of these additives were investigated by studying time-connected behavior at 50-kg and 100-kg loads. The action of the additives cannot be explained on the basis of their chemical structures only; interactions with the rubbing process in the four-ball machine also must be considered.

Presented as an American Society of Lubrication Engineers paper at the ASME/ASLE International Lubrication Conference held in New York City, October 9–12, 1972

Notes

Presented as an American Society of Lubrication Engineers paper at the ASME/ASLE International Lubrication Conference held in New York City, October 9–12, 1972

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