Regiospecipic Synthesis of a New Cross-Linked Dinucleoside : 1-(N⁶-Deoxyadenyl)-2-(o⁴-Thymidyl)-Ethane

M. Nogueras Colegio Univeraitario Santo Reino, Universidad de Granada, Química Orgánica, 23071, Jaen, Spain

M. Lucas Université des Sciences et Techniques du Languedoc, Laboratoire de Chimie Bio-Organique, UA 488 au CNRS, 34060, Montpellier Cedex, Prance

J-L. Imbach Université des Sciences et Techniques du Languedoc, Laboratoire de Chimie Bio-Organique, UA 488 au CNRS, 34060, Montpellier Cedex, Prance

Abstract

The bridged dinucleoside 1-(N⁶-deoxyadenyl) 2-(O⁴-thymidyl)-ethane was prepared from the nucleophilic substitution of a O⁴-triazo-lyl thymidine by a N⁶-(2-hydroxyethyl) deoxyadenosine derivative via the corresponding 6-halogeno hypoxanthine in ribose and deoxyribose series.

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Regiospecipic Synthesis of a New Cross-Linked Dinucleoside : 1-(N⁶-Deoxyadenyl)-2-(o⁴-Thymidyl)-Ethane

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Regiospecipic Synthesis of a New Cross-Linked Dinucleoside : 1-(N6-Deoxyadenyl)-2-(o4-Thymidyl)-Ethane

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Regiospecipic Synthesis of a New Cross-Linked Dinucleoside : 1-(N⁶-Deoxyadenyl)-2-(o⁴-Thymidyl)-Ethane