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Nucleosides and Nucleotides Volume 6, 1987 - Issue 1-2
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Activation of Nucleoside Hydrogenphosphonates by Use of Aryl Sulfonyl Chlorides

Per J. Garegg Department of Organic Chemistry, Arrhenius Laboratory, University of Stockholm, S-106 91, Stockholm, Sweden
,
Jacek Stawinski Department of Organic Chemistry, Arrhenius Laboratory, University of Stockholm, S-106 91, Stockholm, Sweden
&
Roger Strömberg Department of Organic Chemistry, Arrhenius Laboratory, University of Stockholm, S-106 91, Stockholm, Sweden
Pages 425-427 | Published online: 05 Dec 2006
 
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Abstract

The reaction of nucleoside 3′-hydrogenphosphonates with 2,4,6-triisopropylbenzenesulfonyl chloride (TPS-CI) has been studied using P NMR spectroscopy, and a general scheme of transformations occuring during this activation process is proposed.

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