Microstructural evolution and mechanical properties of Grades 23 and 24 creep strength enhanced ferritic steels

Abstract

Grades 23 and 24 creep strength enhanced ferritic (CSEF) steels are relatively new materials that have been designed with improved high-temperature strength compared to conventional 2.25Cr–1Mo alloys. These new steels share alloying strategies that were used in the past for CrMo derivatives such as the CrMoV steels. Grades 23 and 24 are often grouped with similar CSEF steels in terms of mechanical properties and fabrication characteristics. However, recent experience indicates that these alloys require more unique care to ensure adequate properties for the intended service in both the base metal and welds. The differences in behaviour between these new steels and more conventional CrMo steels can be attributed to relatively minor variations in composition that lead to rather significant differences in microstructure. This review summarises technical information and practical experience on the manufacture and use of Grades 23 and 24 CSEF steels for power generation applications. Factors that influence the microstructure and strength of base metal are discussed for each alloy along with influences from common fabrication processes such as welding and bending. The results of this review provides manufacturers, fabricators and end users with information that can be applied to help ensure optimal performance of these steels in high-temperature applications associated with power generation.

Keywords:

• Grade 23
• Grade 24
• Creep
• Mechanical properties
• Stress corrosion cracking
• Hydrogen induced cracking
• Reheat cracking
• Welding