Photocatalytic degradation of cephalexin by g-C₃N₄/Zn doped Fe₃O₄ under visible light

ABSTRACT

In this work, we reported synthesis of a novel magnetically separable g-C₃N₄/Zn doped Fe₃O₄ composite (g-CN/ZnFe) by a simple polyol thermal method. The characteristics of the as-prepared composite was checked by XRD, SEM, TEM, XPS, PL technologies. The optimized weight ratio of g-C₃N₄ and Zn doped Fe₃O₄ was investigated. In addition, the photocatalytic activities of the composite products were checked by degradation of Cephalexin (CEX) under visible light. The results showed that g-CN/ZnFe composite with an added 20% g-C₃N₄ exhibited the highest photocatalytic activity for cephalexin under visible light irradiation. The improved photocatalytic activity of 20% g-CN/ZnFe can be ascribed to the low combination rate of photoinduced electron/hole pairs. Especially, g-CN/ZnFe can be recovered easily by using an external magnetic field and has the high stability after six runs. These properties of the g-CN/ZnFe as-prepared composite could be a promising photocatalyst for the degradation of pharmaceutical contaminants.

GRAPHICAL ABSTRACT

KEYWORDS:

• G-C₃N₄/Zn doped Fe₃O₄ composite
• photocatalytic degradation
• cephalexin
• the low combination rate
• magnetically separable

Disclosure statement

No potential conflict of interest was reported by the authors.