Phase Transition, Thermal Expansion and Electrical Properties of BNLT-BT Ceramics Near the Morphotropic Phase Boundary

Abstract

Lead-free ceramics based on bismuth sodium lanthanum titanate (Bi_0.4871Na_0.4871La_0.0172TiO₃: BNLT) and barium titanate (BaTiO₃: BT) were prepared by a modified two-step mixed-oxide method. Effects of BT content on the phase transition, thermal expansion behavior, mechanical and electrical properties of lead-free BNLT-BT ceramics were studied. The Burn’s temperature and local polarizations were estimated from the thermal expansion data. Various aspects of understanding the polarization behavior and other effects in this system have also been investigated and discussed. The 0.96BNLT-0.04BT ceramics have shown the d₃₃ value of 135 pC/N. The coercive field (E_c) and remanent polarization (P_r) were found to be 24 kV/cm and 9.0 µC/cm², respectively. This may be useful in the future development of multifunctional lead-free materials in electronic applications.

Keywords:

• Thermal expansion
• dielectric properties
• ferroelectric properties
• electrical properties

Acknowledgments

The authors would like to thank the Faculty of Science, Chiang Mai University, Department of Applied Physics, Faculty of Sciences and Liberal Arts, Rajamangala University of Technology Isan, Thailand for financial support. N. Pisitpipathsin also appreciated the support from the Thailand Research Fund (TRF) (TRG6280011) and Synchrotron Light Research Institute (Public Organization), Nakorn Ratchasima, Thailand. Also, the UTSA acknowledges the support of NSF/INAMM grant #0844081.

Disclosure Statement

No potential conflict of interest was reported by the author(s).