Assessing the elastic properties and ductility of Fe–Cr–Al alloys from ab initio calculations

Abstract

Fe–Al is one of the best corrosion resistant alloys at high temperatures. The flip side of Al addition to Fe is the deterioration of the mechanical properties. This problem can be solved by adding a suitable amount of third alloying component. In the present work, we use ab initio calculations based on density functional theory to study the elastic properties of FeCrAl alloys for Al and Cr contents up to 20 at.%. We assess the ductility as a function of chemistry by making use of the semi-empirical correlations between the elastic parameters and mechanical properties. In particular, we derive the bulk modulus to shear modulus ratio and the Cauchy pressure and monitor their trends in terms of chemical composition. The present findings are contrasted with the previously established oxidation resistance of Fe–Cr–Al alloys.

Keywords:

• ab initio
• Fe–Cr–Al
• alloys
• ductility
• mechanical properties
• elasticity

Acknowledgements

The computer resources of the Finnish IT Center for science and FGI project are acknowledged.

Notes

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was supported by Graduate School of Materials Research (GSMR); National Doctoral Programme in Nanoscience (NGS-NANO); Swedish Research Council; the Hungarian Scientific Research Fund [research project OTKA 84078], [research project 109570]; the Carl Tryggers Foundation.