Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 44, 2014 - Issue 9
Submit an article Journal homepage
87
Views
0
CrossRef citations to date
0
Altmetric
Original Articles

Crystal Structure, Quantum Chemical Investigation, and Thermal Behavior of Acyl Hydrazones C10H10N2O4·2H2O

Feng-Ying ChenCollege of Chemistry and Material Science, Northwest University and Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Xi’an, P. R. China;Department of Chemistry & Chemical Engineering, Shangluo University, Shangluo, P. R. China
,
Wang-Ting WuCollege of Chemistry and Material Science, Northwest University and Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Xi’an, P. R. China;Capital Museum, Beijing, P. R. China
,
Shui-Yang HeCollege of Chemistry and Material Science, Northwest University and Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Xi’an, P. R. ChinaCorrespondence[email protected]
&
Zhen-Yi WenCollege of Chemistry and Material Science, Northwest University and Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Xi’an, P. R. China
Pages 1345-1348 | Received 10 Mar 2013, Accepted 27 May 2013, Published online: 17 Apr 2014
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

N-(2-(propionic acid)-salicyloyl hydrazone C10H10N2O4·2H2O (H3L) was synthesized by refluxing the aroylhydrazine and pyruvic acid in nonaqueous ethanol. Single crystals of H3L suitable for X-ray measurement were obtained by methanol-water (V/V = 1:1). The theoretical studies on the title compound were carried out at HF/6–31+G(d) and B3LYP/6–31+G(d) levels. The res-ults indicated that HF/6–31+G(d) gave better structural optimization data than B3LYP/6–31+G(d) method. In addition, the thermal stability had been tested by TG-DTG under a nitrogen atmosphere.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Synthesis, characterization and spectra of lanthanide(III) hydrazone complexes: The X-ray molecular structures of the erbium(III) complex and the ligand
Source: Elsevier BV
The preparation and coordination chemistry of 2,6-diacetylpyridine bis(6-chloro-2-pyridylhydrazone)
Source: Elsevier BV
Synthesis and characterization of novel pentagonal bipyramidal complexes of iron(II), cobalt(II), and zinc(II)
Source: American Chemical Society (ACS)
Electronic structure calculations of copper (II) complexes of [Cu(C10H8N2O4)(H2O)2] and [Cu(C10H8N2O4)(CH3OH)(H2O)]
Source: Elsevier BV
Crystal Structure and Bioactivity of Complex [Gd(C10H9N2O4)(C10H8N2O4)(H2O)3]2·phen·4H2O
Source: Wiley
Synthesis, spectral studies and structure of 2-hydroxyacetophenone nicotinic acid hydrazone
Source: Elsevier BV
CCDC 623328: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Three coordination modes of the pentadentate ligand 2,6-diacetylpyridinedisemicarbazone
Source: Elsevier BV

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.