Synthesis, structure and magnetic property of a copper(II)–cobalt(II) heteronuclear complex with Schiff base ligand

Yuye Tana School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, P. R. China; View further author information

Junjie Huanga School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, P. R. China; View further author information

Hui Lua School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, P. R. China; View further author information

Tao Chib College of Information Technology, Shanghai Ocean University, Shanghai, P. R. China; ;c Key Laboratory of Fisheries Information, Ministry of Agriculture, Shanghai, P. R. ChinaView further author information

Jianhua Suna School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, P. R. China; Correspondence[email protected]
View further author information

Abstract

A new heteronuclear complex [LCuCo(NO₃)₂] (1) (H₂L = N,N'-ethylenebis [3-methoxysalicylaldimine]) was synthesized and structurally characterized. The complex consists of a dimer skeleton which composed of a slightly distorted square-planar copper and pentacoordinated cobalt ions. The magnetic properties reveal the presence of antiferromagnetic interactions between the metal centers linked by double phenoxo-bridging.

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This work was supported by the National Natural Science Foundation of China (21373103).

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Synthesis, structure and magnetic property of a copper(II)–cobalt(II) heteronuclear complex with Schiff base ligand

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Synthesis, structure and magnetic property of a copper(II)–cobalt(II) heteronuclear complex with Schiff base ligand

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