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Original Articles

Thermal Analysis of the Reactions and Kinetics of Green Coffee During Roasting

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Pages 101-111 | Received 14 Feb 2004, Accepted 10 Apr 2004, Published online: 06 Feb 2007
 

Abstract

Green coffee was subjected to thermal study of the reactions evolved during the roasting process. Specific heat, heats of reactions, pressure drop, and permeability of the packed coffee powder were obtained from the measurements. The sample was dried, therefore the thermograms showed no evidence of occluded water present in the coffee. The results showed predominant endothermic reaction in the range of 100 and 245°C mainly due to the formation of phenolic and nitrogen containing heterocyclic compounds. The reactions at temperatures above 245°C exhibited a double trough exotherm related to fracturing of the matrix and formation of cracks as a result of the decomposition of the lignin. The largest pressure build up and consequently lowest permeability was observed in this temperature range. The decomposition reactions were completed at 430°C.

Acknowledgments

The authors would like to acknowledge the input from Breckenridge Coffee Roasters, USA for the initiation and support of this research.

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