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Molecular Crystals and Liquid Crystals Volume 76, 1981 - Issue 1-2
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Original Articles

The Effect on Mesomorphic Properties of Substituting a Sulfur for the Ether Oxygen Atom in the Ester Linkage of 4-Alkylphenyl-4′-Alkyl or Alkoxybenzoates

Mary E. Neubert Liquid Crystal Institute, Kent State University, Kent, Ohio, 44242
,
R. E. Cline Liquid Crystal Institute, Kent State University, Kent, Ohio, 44242
,
M. J. Zawaski Liquid Crystal Institute, Kent State University, Kent, Ohio, 44242; Carlon, An Indian Head Company, Aurora, Ohio
,
P. J. Wildman Liquid Crystal Institute, Kent State University, Kent, Ohio, 44242
&
Arun Ekachai Liquid Crystal Institute and Department of Physics; Department of Physics, Prince of Songkla University, Haad Yai, Thailand
Pages 43-77 | Received 24 Oct 1980, Published online: 20 Apr 2011

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Zhiming Fang & Changcheng Wu. (2020) Investigation on thermal behaviour and optical properties of non-symmetric cholesterol-based twin liquid crystals with thioester linkages. Liquid Crystals 47:7, pages 1086-1099.
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AlexanderJ. Seed, KennethJ. Toyne, Michael Hird & JohnW. Goodby. (2012) Synthesis and mesomorphic behaviour of high polarisability materials for non-linear optical applications. Liquid Crystals 39:4, pages 403-414.
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Danuta Bauman, Ewa Mykowska & Anna Zięba. (2008) Study of Orientational Order of in Nematic and Smectic Phases by means of Optical Spectroscopy Methods. Molecular Crystals and Liquid Crystals 494:1, pages 79-92.
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D. Bauman, E. Mykowska, A. ziĘba, E. Chrzumnicka, G. Czechowski & J. JadŻyn. (2007) Orientational order in nematic, smectic A, and smectic C phases of doped with dichroic dye§ . Phase Transitions 80:6-7, pages 599-613.
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M. D. Ossowska-Chruściel, S. Zalewski, A. Rudzki, A. Filiks & J. Chruściel. (2006) The phase behaviour of 4- -pentylphenyl-4′- -heptyloxythiobenzoate. Phase Transitions 79:8, pages 679-690.
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Shune‐Long Wu & Kuan‐Ting Chen. (2006) Synthesis and mesomorphic properties of chiral swallow‐tailed thioester liquid crystals with lateral substituents. Liquid Crystals 33:5, pages 573-579.
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VladimirF. Petrov. (2005) Sulphur as a Structural Element in Calamitic Liquid Crystals: Terminal, Linking and Lateral Substitutions. Molecular Crystals and Liquid Crystals 442:1, pages 63-92.
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Mary E. Neubert, Sandra S. Keast, Julie M. Kim, Aaron G. Norton, Mark J. Whyde, Michael J. Smith, Ryan M. Stayshich, Margaret E. Walsh & David G. Abdallah. (2005) The effect on mesomorphic properties of a triple bond in a terminal chain of 4,4′‐disubstituted phenyl benzoates and phenyl thiobenzoates. Liquid Crystals 32:2, pages 247-266.
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S.-L. Wu$suffix/text()$suffix/text() & S. Senthil. (2004) Synthesis and mesomorphic properties of chiral liquid crystals having thiolactate groups . Liquid Crystals 31:10, pages 1387-1392.
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Y.L. N. Murthy & P. Aruna Sree. (1997) Characterisation of Lupeol (A Tri Terpene) Esters As Liquid Crystals. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 308:1, pages 93-97.
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K.S. Krishnamurthy & R. Balakrishnan. (1997) Mesophases in Long Chain Alkoxy Alcohol/Ortho-Phosphoric Acid Systems. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 301:1, pages 403-409.
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M. Arnaudov, M. Rogojerov & L. Prangova. (1997) IR-Spectral Study of 4′-Substituted Phenylthiolbenzoates in Solution. Spectroscopy Letters 30:1, pages 149-161.
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M.E. Neubert, S.S. Keast, Y. Dixon-polverine, F. Herlinger, M.R. Jirousek, K. Leung, K. Murray & J. Rambler. (1994) The Effect of 2- and 3-Lateral Substituents on the Acid Side of 4,4′-Disubstituted Phenylbenzoates and Phenylthiobenzoates on Mesomorphic Properties. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 250:1, pages 109-123.
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K. Lipiński, T. Lipiński, J. Chruściel, A. Suszko-purzycka & A. Rykowski. (1994) Synthesis and Mesomorphic Properties of Deuterated 4-n-Pentylphenyl-4′-n-Alkoxythiobenzoates 7S5-d26 and 8S5-d28 . Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 239:1, pages 87-93.
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H.T. Nguyen, C. Destrade, H. Allouchi, J.P. Bideau, M. Cotrait, D. Guillon, P. Weber & J. Malthěte. (1993) Phasmid and biforked mesogens with thiobenzoate end groups. Liquid Crystals 15:4, pages 435-449.
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J. Chruściel, H. Kresse & S. Urban. (1992) Megahertz dielectric relaxation process in the nematic and smectic phases of two thiol esters (9S5 and 10S5). Liquid Crystals 11:5, pages 711-718.
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M.E. Neubert & I.G. Shenouda. (1991) The Synthesis and Mesomorphic Properties of 4-Methyl-Pentyloxyphenylthio-4′-Substituted Benzoatest. Molecular Crystals and Liquid Crystals 205:1, pages 29-45.
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M.E. Neubert, R.B. Sharma, C. Citano, M.R. Jirousek & J.L. Paulin. (1991) The Effect of Carbonyl Containing Substituents in the Terminal Chains on Mesomorphic Properties in Some Aromatic Esters and Thioesters 7. α-Keto Group on the Acid End of Phenylbenzoates and Thiobenzoates. Molecular Crystals and Liquid Crystals 196:1, pages 145-155.
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H.T. Nguyen, C. Destrade, R.J. Twieg & K. Betterton. (1990) Reentrant phenomenon in cyanoaryl alkylthioxybenzoates and cyanobenzoyloxyphenyl alkylthiobenzoates. Liquid Crystals 8:3, pages 419-427.
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J. Chruściel, S. Wróbel, H. Kresse, S. Urban & W. Otowski. (1990) Odd-Even Effect in the Homologous Series of Thioesters. Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 192:1, pages 107-112.
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M.E. Neubert, D. Leonhardt & S. Sabol-keast. (1989) The Effect of Methyl Group Position in Branched Alkyl Chains on the Phenolic End of 4,4′-Disubstituted Phenylbenzoates on Mesomorphic Properties and Some Optically Active Analogs as Ferroelectric Liquid Crystals. Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 172:1, pages 227-248.
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R.J. Twieg, K. Betterton, H.T. Nguyen, W. Tang & W. Hinsberg. (1989) Ferroelectric α-chloroester thiobenzoate liquid crystals. Ferroelectrics 91:1, pages 243-265.
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MaryE. Neubert, Ktherine Leung, StanleyJ. Laskos$suffix/text()$suffix/text(), MatthewC. Ezenyilimba, M.R. Jirousek, Darrin Leonhardt, BrianA. Williams & Barbara Ziemnicka-merchant. (1989) The Effect of Methyl Group Position in Branched Alkyl Chains on the Thiolic End of 4,4′-Disubstituted Thiophenylbenzoates on Mesomorphic Properties and Some Optically Active Analogs as New Ferroelectric Liquid Crystals. Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 166:1, pages 181-230.
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MaryE. Neubert, Barbara Ziemnicka-merchant, MichaelR. Jirousek, StanleyJ. Laskos$suffix/text()$suffix/text(), Darrin Leonhardt & RamB. Sharma. (1988) The Effect of Two Terminal Alkoxy Groups on the Mesomorphic Properties of 4, 4′-Disubstituted Phenylthiobenzoates. Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 154:1, pages 209-239.
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MaryE. Neubert, Cynthia Colby, MatthewC. Ezenyilimba, MichaelR. Jirousek, Darrin Leonhardt & Katherine Leung. (1988) The Effect of Carbonyl Containing Substituents in the Terminal Chains on Mesomorphic Properties in Some Aromatic Esters and Thioesters. 3. Acyloxy Groups on the Acid End. Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 154:1, pages 127-149.
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MaryE. Neubert, PatriciaJ. Wildman, MichaelJ. Zawaski, CarolA. Hanlon, TheresaL. Benyo & Adriaan De Vries. (1987) The effect of Carbonyl Containing Substituents in the Terminal chains on Mesomorophic Progerties in Aromatic Esters and Thioesters, 2. Acyloxy Groups on the Phenolic End. Molecular Crystals and Liquid Crystals 145:1, pages 111-157.
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MaryE. Neubert & Adriaan De Vries. (1987) Microscopic Textures and X-Ray Diffraction Patterns in Nematic Phases Occurring Above Smectic C Phases. Molecular Crystals and Liquid Crystals 145:1, pages 1-15.
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Nguyen Huu Tinh, C. Salleneuve, A. Babeau, A. Roubineau & C. Destrade. (1987) Chiral SCM* Phase in some Thiobenzoates Series. Molecular Crystals and Liquid Crystals Letters 4:3-4, pages 93-98.
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MaryE. Neubert, FrankC. Herlinger, MichaelR. Jirouskek & Adriaan De Vries. (1986) The Effect of Carbonyl Containing Groups in the Terminal Chains on Mesomorphic Properties in Aromatic Esters and Thioesters. l. α-keto Groups on the Phenolic End. Molecular Crystals and Liquid Crystals 139:3-4, pages 299-320.
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MaryE. Neubert, MichaelR. Jirousek & CarolA. Hanlon. (1986) Mesomorphic Properties of Some 4, 4′- Alkyl and Alkoxy Disubstituted Phenylbenzoates. Molecular Crystals and Liquid Crystals 133:3-4, pages 223-233.
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J Chruściel, S. Wróbel, H. Kresse, S. Urban & W. Otowski. (1985) Dielectric Studies of 4-n-Pentylphenyl-4-Octyloxythiobenzoate. Molecular Crystals and Liquid Crystals 127:1, pages 57-65.
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Aj Leadbetter, Pa Tucker, Gw Gray & Ar Tajbakhsh. (1985) The Phase Behaviour of 4-n-Hexylphenyl 4-n-Tetra-Decyloxybenzthiolate () and 4-n-Pentylphenyl 4-n-Decyloxybenzthiolate (). Molecular Crystals and Liquid Crystals Letters 1:1-2, pages 19-24.
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MaryE. Neubert. (1985) Synthesis of Some Deuterated Aromatic Mesomorphic Compounds Used in Broad-Line 2H-NMR Studies. Molecular Crystals and Liquid Crystals 129:4, pages 327-373.
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A.N. Kalkura, S.Krishna Prasad & R. Shashidhar. (1983) Pressure Studies on 7 S5, 8 S5 and Their Mixtures. Molecular Crystals and Liquid Crystals 99:1, pages 193-202.
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MaryE. Neubert, M.E. Stahl & R.E. Cline. (1982) Synthesis and Mesomorphic Properties of the Homologous Series of Di-(4′- n-alkylphenyl)- trans-cyclohexane-1,4-dicarboxylates. Molecular Crystals and Liquid Crystals 89:1-4, pages 93-117.
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P. S. Clegg, R. J. Birgeneau, S. Park, C. W. Garland, G. S. Iannacchione, R. L. Leheny & M. E. Neubert. (2003) High-resolution x-ray study of the nematic–smectic- and smectic- –smectic- transitions in liquid-crystal–aerosil gels . Physical Review E 68:3.
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V. Vill. 1992. Transition Temperatures and Related Properties of Two-Ring Systems with Bridging Group. Transition Temperatures and Related Properties of Two-Ring Systems with Bridging Group 175 199 .
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J. D. Miller, P. R. Battle, P. J. Collings, D. K. Yang & P. P. Crooker. (1987) Temperature-concentration phase diagram for the blue phases of a highly chiral liquid crystal. Physical Review A 35:9, pages 3959-3960.
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B. M. Ocko, R. J. Birgeneau, J. D. Litster & M. E. Neubert. (1984) Critical and Tricritical Behavior at the Nematic to Smectic- Transition . Physical Review Letters 52:3, pages 208-211.
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P. A. C. Gane, A. J. Leadbetter, P. A. Tucker, G. W. Gray & A. R. Tajbakhsh. (1982) The phase behavior of two thiol esters (1̄2̄ S5 and 1̄4̄ S5). The Journal of Chemical Physics 77:12, pages 6215-6217.
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Thomas E. Lockhart, Edward Gelerinter & Mary E. Neubert. (1982) Measurement of refractive indices and their relation to orientational order at smectic- —smectic- transitions . Physical Review A 25:4, pages 2262-2271.
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